Organic electroluminescent materials and devices

ABSTRACT

is disclosed.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority under 35 U.S.C. § 119(e) to U.S. Provisional Application No. 62/680,283, filed Jun. 4, 2018, and U.S. Provisional Application No. 62/683,797, filed Jun. 12, 2018, the entire contents of which are incorporated herein by reference.

FIELD

The present invention relates to compounds for use as emitters, and devices, such as organic light emitting diodes, including the same.

BACKGROUND

Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.

OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.

One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Alternatively the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs. The white OLED can be either a single EML device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.

One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)₃, which has the following structure:

In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.

As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.

As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.

As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.

As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.

More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.

SUMMARY

Disclosed herein is a novel transition metal compound having a first ligand with a unique configuration of fused rings that makes the compound useful as emitters in OLEDs. A compound comprising a first ligand L_(A) of Formula I

is disclosed. In Formula I, X¹ to X⁸ are each independently C or N, where no more than two N atoms are bonded to each other. At least one pair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and is joined to a structure G of Formula II

where A is selected from the group consisting of O, S, Se, and NR′. In the compound, R^(A), R^(B), R^(C), and R^(D) each independently represents mono to the maximum number of allowable substitutions, or no substitution. Each R^(A), R^(B), R^(C), R^(D), and R′ is independently hydrogen or a substituent selected from the group consisting of the general substituents defined above. Any two substituents may be joined or fused together to form a ring. The ligand L_(A) is complexed to a metal M. M is optionally coordinated to other ligands. The ligand L_(A) is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand.

An OLED comprising the compound of the present disclosure in an organic layer therein is also disclosed.

A consumer product comprising the OLED is also disclosed.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.

FIG. 3 shows a plot of the photoluminescence spectrum of an inventive example Compound A in PMMA film.

DETAILED DESCRIPTION

Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.

The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.

More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.

FIG. 1 shows an organic light emitting device 100. The figures are not necessarily drawn to scale. Device 100 may include a substrate 110, an anode 115, a hole injection layer 120, a hole transport layer 125, an electron blocking layer 130, an emissive layer 135, a hole blocking layer 140, an electron transport layer 145, an electron injection layer 150, a protective layer 155, a cathode 160, and a barrier layer 170. Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164. Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.

More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210, a cathode 215, an emissive layer 220, a hole transport layer 225, and an anode 230. Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230, device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200. FIG. 2 provides one example of how some layers may be omitted from the structure of device 100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device 200, hole transport layer 225 transports holes and injects holes into emissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2.

Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2. For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.

Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and organic vapor jet printing (OVJP). Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.

Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. A consumer product comprising an OLED that includes the compound of the present disclosure in the organic layer in the OLED is disclosed. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, curved displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, rollable displays, foldable displays, stretchable displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays (displays that are less than 2 inches diagonal), 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, a light therapy device, and a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.), but could be used outside this temperature range, for example, from −40 degree C. to +80 degree C.

The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.

The terms “halo,” “halogen,” and “halide” are used interchangeably and refer to fluorine, chlorine, bromine, and iodine.

The term “acyl” refers to a substituted carbonyl radical (C(O)—R_(s)).

The term “ester” refers to a substituted oxycarbonyl (—O—C(O)—R_(s) or —C(O)—O—R_(s)) radical.

The term “ether” refers to an —OR_(s) radical.

The terms “sulfanyl” or “thio-ether” are used interchangeably and refer to a —SR_(s) radical.

The term “sulfinyl” refers to a —S(O)—R_(s) radical.

The term “sulfonyl” refers to a —SO₂—R_(s) radical.

The term “phosphino” refers to a —P(R_(s))₃ radical, wherein each R_(s) can be same or different.

The term “silyl” refers to a —Si(R_(s))₃ radical, wherein each R_(s) can be same or different.

In each of the above, R_(s) can be hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combination thereof. Preferred R_(s) is selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and combination thereof.

The term “alkyl” refers to and includes both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group is optionally substituted.

The term “cycloalkyl” refers to and includes monocyclic, polycyclic, and spiro alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl, adamantyl, and the like. Additionally, the cycloalkyl group is optionally substituted.

The terms “heteroalkyl” or “heterocycloalkyl” refer to an alkyl or a cycloalkyl radical, respectively, having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si and Se, preferably, O, S or N. Additionally, the heteroalkyl or heterocycloalkyl group is optionally substituted.

The term “alkenyl” refers to and includes both straight and branched chain alkene radicals. Alkenyl groups are essentially alkyl groups that include at least one carbon-carbon double bond in the alkyl chain. Cycloalkenyl groups are essentially cycloalkyl groups that include at least one carbon-carbon double bond in the cycloalkyl ring. The term “heteroalkenyl” as used herein refers to an alkenyl radical having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Preferred alkenyl, cycloalkenyl, or heteroalkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl, cycloalkenyl, or heteroalkenyl group is optionally substituted.

The term “alkynyl” refers to and includes both straight and branched chain alkyne radicals. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group is optionally substituted.

The terms “aralkyl” or “arylalkyl” are used interchangeably and refer to an alkyl group that is substituted with an aryl group. Additionally, the aralkyl group is optionally substituted.

The term “heterocyclic group” refers to and includes aromatic and non-aromatic cyclic radicals containing at least one heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals may be used interchangeably with heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers, such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and the like. Additionally, the heterocyclic group may be optionally substituted.

The term “aryl” refers to and includes both single-ring aromatic hydrocarbyl groups and polycyclic aromatic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is an aromatic hydrocarbyl group, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group is optionally substituted.

The term “heteroaryl” refers to and includes both single-ring aromatic groups and polycyclic aromatic ring systems that include at least one heteroatom. The heteroatoms include, but are not limited to O, S, N, P, B, Si, and Se. In many instances, O, S, or N are the preferred heteroatoms. Hetero-single ring aromatic systems are preferably single rings with 5 or 6 ring atoms, and the ring can have from one to six heteroatoms. The hetero-polycyclic ring systems can have two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. The hetero-polycyclic aromatic ring systems can have from one to six heteroatoms per ring of the polycyclic aromatic ring system. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group is optionally substituted.

Of the aryl and heteroaryl groups listed above, the groups of triphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, pyrazine, pyrimidine, triazine, and benzimidazole, and the respective aza-analogs of each thereof are of particular interest.

The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl, as used herein, are independently unsubstituted, or independently substituted, with one or more general substituents.

In many instances, the general substituents are selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.

In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, alkoxy, aryloxy, amino, silyl, aryl, heteroaryl, sulfanyl, and combinations thereof.

In yet other instances, the more preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.

The terms “substituted” and “substitution” refer to a substituent other than H that is bonded to the relevant position, e.g., a carbon or nitrogen. For example, when R¹ represents mono-substitution, then one R¹ must be other than H (i.e., a substitution). Similarly, when R¹ represents di-substitution, then two of R¹ must be other than H. Similarly, when R¹ represents no substitution, R¹, for example, can be a hydrogen for available valencies of ring atoms, as in carbon atoms for benzene and the nitrogen atom in pyrrole, or simply represents nothing for ring atoms with fully filled valencies, e.g., the nitrogen atom in pyridine. The maximum number of substitutions possible in a ring structure will depend on the total number of available valencies in the ring atoms.

As used herein, “combinations thereof” indicates that one or more members of the applicable list are combined to form a known or chemically stable arrangement that one of ordinary skill in the art can envision from the applicable list. For example, an alkyl and deuterium can be combined to form a partial or fully deuterated alkyl group; a halogen and alkyl can be combined to form a halogenated alkyl substituent; and a halogen, alkyl, and aryl can be combined to form a halogenated arylalkyl. In one instance, the term substitution includes a combination of two to four of the listed groups. In another instance, the term substitution includes a combination of two to three groups. In yet another instance, the term substitution includes a combination of two groups. Preferred combinations of substituent groups are those that contain up to fifty atoms that are not hydrogen or deuterium, or those which include up to forty atoms that are not hydrogen or deuterium, or those that include up to thirty atoms that are not hydrogen or deuterium. In many instances, a preferred combination of substituent groups will include up to twenty atoms that are not hydrogen or deuterium.

The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective aromatic ring can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.

As used herein, “deuterium” refers to an isotope of hydrogen. Deuterated compounds can be readily prepared using methods known in the art. For example, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, and U.S. Pat. Application Pub. No. US 2011/0037057, which are hereby incorporated by reference in their entireties, describe the making of deuterium-substituted organometallic complexes. Further reference is made to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt et al., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which are incorporated by reference in their entireties, describe the deuteration of the methylene hydrogens in benzyl amines and efficient pathways to replace aromatic ring hydrogens with deuterium, respectively.

It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.

In some instance, a pair of adjacent substituents can be optionally joined or fused into a ring. The preferred ring is a five, six, or seven-membered carbocyclic or heterocyclic ring, includes both instances where the portion of the ring formed by the pair of substituents is saturated and where the portion of the ring formed by the pair of substituents is unsaturated. As used herein, “adjacent” means that the two substituents involved can be on the same ring next to each other, or on two neighboring rings having the two closest available substitutable positions, such as 2, 2′ positions in a biphenyl, or 1, 8 position in a naphthalene, as long as they can form a stable fused ring system.

According to an embodiment, a compound comprising a first ligand L_(A) of Formula I

is disclosed. In Formula I, X¹ to X⁸ are each independently C or N, where no more than two N atoms are bonded to each other. At least one pair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and is joined to a structure G of Formula II

where A is selected from the group consisting of O, S, Se, and NR′. In the compound, R^(A), R^(B), R^(C), and R^(D) each independently represents mono to the maximum number of allowable substitutions, or no substitution. Each R^(A), R^(B), R^(C), R^(D), and R′ is independently hydrogen or a substituent selected from the group consisting of the general substituents defined above. Any two substituents may be joined or fused together to form a ring. The ligand L_(A) is complexed to a metal M. M is optionally coordinated to other ligands. The ligand L_(A) is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand.

In some embodiments, each R^(A), R^(B), R^(C), and R^(D) is independently selected from the group consisting of the preferred general substituents defined above.

In some embodiments, X¹ to X⁸ are each C. In some embodiments, at least one of X¹ to X⁸ is N.

In some embodiments, A in Formula II is O or S.

In some embodiments, M is selected from the group consisting of Ru, Os, Pd, Pt, Ir, Cu, and Au. In some embodiments, M is Ir or Pt. Preferably, Ir is Ir(III) and Pt is Pt(I).

In some embodiments where M is selected from the group consisting of Ru, Os, Pd, Pt, Ir, Cu, and Au, the compound further comprises a substituted or unsubstituted acetylacetonate ligand.

In some embodiments, Formula II is substituted or unsubstituted

In some embodiments, only one pair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and is joined to the structure G.

In some embodiments, the first ligand L_(A) is of the formula

In some embodiments, the first ligand L_(A) is selected from the group consisting of:

where X⁹ to X¹² are each independently C or N; and where no more than two N atoms are bonded to each other.

In some embodiments of the compound, the first ligand L_(A) is selected from the group consisting of ligands L_(A1-O) to L_(A384-O), L_(A1-S) to L_(A384-S), L_(A1-C) to L_(A383-C), and L_(A384-C) that are based on the structure

where the asterisks with an Arabic numeral indicate the points of attachment to the corresponding points of attachment in the structure G,

where for ligands L_(A1-O) to L_(A384-O), A in the structure G is O,

where for ligands L_(A1-S) to L_(A384-S), A in the structure G is S,

where for ligands L_(A1-C) to L_(A384-C), A in the structure G is C(CH₃)₂, where X³, R⁶, R⁸, and G are defined for A1 to A384 as shown below:

X³ R⁶ R⁸ G A1 CH H H G¹ A2 CH H H G³ A3 CH H H G⁵ A4 CH H H G⁷ A5 CH H H G⁹ A6 CH H H G¹¹ A7 N H H G¹ A8 N H H G³ A9 N H H G⁵ A10 N H H G⁷ A11 N H H G⁹ A12 N H H G¹¹ A13 CR^(B1) H H G¹ A14 CR^(B3) H H G¹ A15 CR^(B5) H H G¹ A16 CR^(B7) H H G¹ A17 CR^(B9) H H G¹ A18 CR^(B11) H H G¹ A19 CR^(B13) H H G¹ A20 CR^(B15) H H G¹ A21 CR^(B17) H H G¹ A22 CR^(B19) H H G¹ A23 CR^(B21) H H G¹ A24 CR^(B23) H H G¹ A25 CR^(B25) H H G¹ A26 CR^(B27) H H G¹ A27 CR^(B29) H H G¹ A28 CR^(B31) H H G¹ A29 CR^(B33) H H G¹ A30 CR^(B35) H H G¹ A31 CR^(B37) H H G¹ A32 CR^(B39) H H G¹ A33 CR^(B41) H H G¹ A34 CR^(B43) H H G¹ A35 CR^(B45) H H G¹ A36 CR^(B47) H H G¹ A37 CR^(B49) H H G¹ A38 CR^(B51) H H G¹ A39 CR^(B53) H H G¹ A40 CR^(B55) H H G¹ A41 CR^(B57) H H G¹ A42 CR^(B59) H H G¹ A43 CR^(B1) H H G² A44 CR^(B3) H H G² A45 CR^(B5) H H G² A46 CR^(B7) H H G² A47 CR^(B9) H H G² A48 CR^(B11) H H G² A49 CR^(B13) H H G² A50 CR^(B15) H H G² A51 CR^(B17) H H G² A52 CR^(B19) H H G² A53 CR^(B21) H H G² A54 CR^(B23) H H G² A55 CR^(B25) H H G² A56 CR^(B27) H H G² A57 CR^(B29) H H G² A58 CR^(B31) H H G² A59 CR^(B33) H H G² A60 CR^(B35) H H G² A61 CR^(B37) H H G² A62 CR^(B39) H H G² A63 CR^(B41) H H G² A64 CR^(B43) H H G² A65 CR^(B45) H H G² A66 CR^(B47) H H G² A67 CR^(B49) H H G² A68 CR^(B51) H H G² A69 CR^(B53) H H G² A70 CR^(B55) H H G² A71 CR^(B57) H H G² A72 CR^(B59) H H G² A73 CR^(B1) H H G³ A74 CR^(B3) H H G³ A75 CR^(B5) H H G³ A76 CR^(B7) H H G³ A77 CR^(B9) H H G³ A78 CR^(B11) H H G³ A79 CR^(B13) H H G³ A80 CR^(B15) H H G³ A81 CR^(B17) H H G³ A82 CR^(B19) H H G³ A83 CR^(B21) H H G³ A84 CR^(B23) H H G³ A85 CR^(B25) H H G³ A86 CR^(B27) H H G³ A87 CR^(B29) H H G³ A88 CR^(B31) H H G³ A89 CR^(B33) H H G³ A90 CR^(B35) H H G³ A91 CR^(B37) H H G³ A92 CR^(B39) H H G³ A93 CR^(B41) H H G³ A94 CR^(B43) H H G³ A95 CR^(B45) H H G³ A96 CR^(B47) H H G³ A97 CR^(B49) H H G³ A98 CR^(B51) H H G³ A99 CR^(B53) H H G³ A100 CR^(B55) H H G³ A101 CR^(B57) H H G³ A102 CR^(B59) H H G³ A103 CR^(B1) H H G⁴ A104 CR^(B3) H H G⁴ A105 CR^(B5) H H G⁴ A106 CR^(B7) H H G⁴ A107 CR^(B9) H H G⁴ A108 CR^(B11) H H G⁴ A109 CR^(B13) H H G⁴ A110 CR^(B15) H H G⁴ A111 CR^(B17) H H G⁴ A112 CR^(B19) H H G⁴ A113 CR^(B21) H H G⁴ A114 CR^(B23) H H G⁴ A115 CR^(B25) H H G⁴ A116 CR^(B27) H H G⁴ A117 CR^(B29) H H G⁴ A118 CR^(B31) H H G⁴ A119 CR^(B33) H H G⁴ A120 CR^(B35) H H G⁴ A121 CR^(B37) H H G⁴ A122 CR^(B39) H H G⁴ A123 CR^(B41) H H G⁴ A124 CR^(B43) H H G⁴ A125 CR^(B45) H H G⁴ A126 CR^(B47) H H G⁴ A127 CR^(B49) H H G⁴ A128 CR^(B51) H H G⁴ A129 CH H H G² A130 CH H H G⁴ A131 CH H H G⁶ A132 CH H H G⁸ A133 CH H H G¹⁰ A134 CH H H G¹² A135 N H H G² A136 N H H G⁴ A137 N H H G⁶ A138 N H H G⁸ A139 N H H G¹⁰ A140 N H H G¹² A141 CR^(B2) H H G¹ A142 CR^(B4) H H G¹ A143 CR^(B6) H H G¹ A144 CR^(B8) H H G¹ A145 CR^(B10) H H G¹ A146 CR^(B12) H H G¹ A147 CR^(B14) H H G¹ A148 CR^(B16) H H G¹ A149 CR^(B18) H H G¹ A150 CR^(B20) H H G¹ A151 CR^(B22) H H G¹ A152 CR^(B24) H H G¹ A153 CR^(B26) H H G¹ A154 CR^(B28) H H G¹ A155 CR^(B30) H H G¹ A156 CR^(B32) H H G¹ A157 CR^(B34) H H G¹ A158 CR^(B36) H H G¹ A159 CR^(B38) H H G¹ A160 CR^(B40) H H G¹ A161 CR^(B42) H H G¹ A162 CR^(B44) H H G¹ A163 CR^(B46) H H G¹ A164 CR^(B48) H H G¹ A165 CR^(B50) H H G¹ A166 CR^(B52) H H G¹ A167 CR^(B54) H H G¹ A168 CR^(B56) H H G¹ A169 CR^(B58) H H G¹ A170 CR^(B60) H H G¹ A171 CR^(B2) H H G² A172 CR^(B4) H H G² A173 CR^(B6) H H G² A174 CR^(B8) H H G² A175 CR^(B10) H H G² A176 CR^(B12) H H G² A177 CR^(B14) H H G² A178 CR^(B16) H H G² A179 CR^(B18) H H G² A180 CR^(B20) H H G² A181 CR^(B22) H H G² A182 CR^(B24) H H G² A183 CR^(B26) H H G² A184 CR^(B28) H H G² A185 CR^(B30) H H G² A186 CR^(B32) H H G² A187 CR^(B34) H H G² A188 CR^(B36) H H G² A189 CR^(B38) H H G² A190 CR^(B40) H H G² A191 CR^(B42) H H G² A192 CR^(B44) H H G² A193 CR^(B46) H H G² A194 CR^(B48) H H G² A195 CR^(B50) H H G² A196 CR^(B52) H H G² A197 CR^(B54) H H G² A198 CR^(B56) H H G² A199 CR^(B58) H H G² A200 CR^(B60) H H G² A201 CR^(B2) H H G³ A202 CR^(B4) H H G³ A203 CR^(B6) H H G³ A204 CR^(B8) H H G³ A205 CR^(B10) H H G³ A206 CR^(B12) H H G³ A207 CR^(B14) H H G³ A208 CR^(B16) H H G³ A209 CR^(B18) H H G³ A210 CR^(B20) H H G³ A211 CR^(B22) H H G³ A212 CR^(B24) H H G³ A213 CR^(B26) H H G³ A214 CR^(B28) H H G³ A215 CR^(B30) H H G³ A216 CR^(B32) H H G³ A217 CR^(B34) H H G³ A218 CR^(B36) H H G³ A219 CR^(B38) H H G³ A220 CR^(B40) H H G³ A221 CR^(B42) H H G³ A222 CR^(B44) H H G³ A223 CR^(B46) H H G³ 224 CR^(B48) H H G³ A225 CR^(B50) H H G³ A226 CR^(B52) H H G³ A227 CR^(B54) H H G³ A228 CR^(B56) H H G³ A229 CR^(B58) H H G³ A230 CR^(B60) H H G³ A231 CR^(B2) H H G⁴ A232 CR^(B4) H H G⁴ A233 CR^(B6) H H G⁴ A234 CR^(B8) H H G⁴ A235 CR^(B10) H H G⁴ A236 CR^(B12) H H G⁴ A237 CR^(B14) H H G⁴ A238 CR^(B16) H H G⁴ A239 CR^(B18) H H G⁴ A240 CR^(B20) H H G⁴ A241 CR^(B22) H H G⁴ A242 CR^(B24) H H G⁴ A243 CR^(B26) H H G⁴ A244 CR^(B28) H H G⁴ A245 CR^(B30) H H G⁴ A246 CR^(B32) H H G⁴ A247 CR^(B34) H H G⁴ A248 CR^(B36) H H G⁴ A249 CR^(B38) H H G⁴ A250 CR^(B40) H H G⁴ A251 CR^(B42) H H G⁴ A252 CR^(B44) H H G⁴ A253 CR^(B46) H H G⁴ A254 CR^(B48) H H G⁴ A255 CR^(B50) H H G⁴ A256 CR^(B52) H H G⁴ A257 CR^(B55) H H G⁴ A258 CR^(B57) H H G⁴ A259 CR^(B59) H H G⁴ A260 CR^(B1) H H G⁵ A261 CR^(B3) H H G⁵ A262 CR^(B5) H H G⁵ A263 CR^(B7) H H G⁵ A264 CR^(B9) H H G⁵ A265 CR^(B11) H H G⁵ A266 CR^(B13) H H G⁵ A267 CR^(B15) H H G⁵ A268 CR^(B17) H H G⁵ A269 CR^(B19) H H G⁵ A270 CR^(B21) H H G⁵ A271 CR^(B23) H H G⁵ A272 CR^(B25) H H G⁵ A273 CR^(B27) H H G⁵ A274 CR^(B29) H H G⁵ A275 CR^(B31) H H G⁵ A276 CR^(B33) H H G⁵ A277 CR^(B35) H H G⁵ A278 CR^(B37) H H G⁵ A279 CR^(B39) H H G⁵ A280 CR^(B41) H H G⁵ A281 CR^(B43) H H G⁵ A282 CR^(B45) H H G⁵ A283 CR^(B47) H H G⁵ A284 CR^(B49) H H G⁵ A285 CR^(B51) H H G⁵ A286 CR^(B53) H H G⁵ A287 CR^(B55) H H G⁵ A288 CR^(B57) H H G⁵ A289 CR^(B59) H H G⁵ A290 CR^(B1) H H G⁶ A291 CR^(B3) H H G⁶ A292 CR^(B5) H H G⁶ A293 CR^(B7) H H G⁶ A294 CR^(B9) H H G⁶ A295 CR^(B11) H H G⁶ A296 CR^(B13) H H G⁶ A297 CR^(B15) H H G⁶ A298 CR^(B17) H H G⁶ A299 CR^(B19) H H G⁶ A300 CR^(B21) H H G⁶ A301 CR^(B23) H H G⁶ A302 CR^(B25) H H G⁶ A303 CR^(B27) H H G⁶ A304 CR^(B29) H H G⁶ A305 CR^(B31) H H G⁶ A306 CR^(B33) H H G⁶ A307 CR^(B35) H H G⁶ A308 CR^(B37) H H G⁶ A309 CR^(B39) H H G⁶ A310 CR^(B41) H H G⁶ A311 CR^(B43) H H G⁶ A312 CR^(B45) H H G⁶ A313 CR^(B47) H H G⁶ A314 CR^(B49) H H G⁶ A315 CR^(B51) H H G⁶ A316 CR^(B53) H H G⁶ A317 CR^(B55) H H G⁶ A318 CR^(B57) H H G⁶ A319 CR^(B59) H H G⁶ A320 CR^(B56) H H G⁴ A321 CR^(B58) H H G⁴ A322 CR^(B60) H H G⁴ A323 CR^(B2) H H G⁵ A324 CR^(B4) H H G⁵ A325 CR^(B6) H H G⁵ A326 CR^(B8) H H G⁵ A327 CR^(B10) H H G⁵ A328 CR^(B12) H H G⁵ A329 CR^(B14) H H G⁵ A330 CR^(B16) H H G⁵ A331 CR^(B18) H H G⁵ A332 CR^(B20) H H G⁵ A333 CR^(B22) H H G⁵ A334 CR^(B24) H H G⁵ A335 CR^(B26) H H G⁵ A336 CR^(B28) H H G⁵ A337 CR^(B30) H H G⁵ A338 CR^(B32) H H G⁵ A339 CR^(B34) H H G⁵ A340 CR^(B36) H H G⁵ A341 CR^(B38) H H G⁵ A342 CR^(B40) H H G⁵ A343 CR^(B42) H H G⁵ A344 CR^(B44) H H G⁵ A345 CR^(B46) H H G⁵ A346 CR^(B48) H H G⁵ A347 CR^(B50) H H G⁵ A348 CR^(B52) H H G⁵ A349 CR^(B54) H H G⁵ A350 CR^(B56) H H G⁵ A351 CR^(B58) H H G⁵ A352 CR^(B60) H H G⁵ A353 CR^(B1) H H G⁶ A354 CR^(B4) H H G⁶ A355 CR^(B7) H H G⁶ A356 CR^(B10) H H G⁶ A357 CR^(B13) H H G⁶ A358 CR^(B16) H H G⁶ A359 CR^(B19) H H G⁶ A360 CR^(B22) H H G⁶ A361 CR^(B25) H H G⁶ A362 CR^(B28) H H G⁶ A363 CR^(B31) H H G⁶ A364 CR^(B34) H H G⁶ A365 CR^(B37) H H G⁶ A366 CR^(B40) H H G⁶ A367 CR^(B43) H H G⁶ A368 CR^(B46) H H G⁶ A369 CR^(B49) H H G⁶ A370 CR^(B52) H H G⁶ A371 CR^(B55) H H G⁶ A372 CR^(B58) H H G⁶ A373 CR^(B61) H H G⁶ A374 CR^(B64) H H G⁶ A375 CR^(B67) H H G⁶ A376 CR^(B70) H H G⁶ A377 CR^(B73) H H G⁶ A378 CR^(B76) H H G⁶ A379 CR^(B79) H H G⁶ A380 CR^(B82) H H G⁶ A381 CR^(B85) H H G⁶ A382 CR^(B88) H H G⁶ A383 CR^(B53) H H G⁴ A384 CR^(B54) H H G⁴ ligands L_(A385-O) to L_(A420-O), L_(A385-S) to L_(A420-S), and L_(A385-C) to L_(A419-C), and L_(A420-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points of attachment to the corresponding points of attachment in the structure G,

wherein for ligands L_(A385-O) to L_(A420-O), A in the structure G is O,

wherein for ligands L_(A385-S) to L_(A420-S), A in the structure G is S,

wherein for ligands L_(A385-C) to L_(A420-C), A in the structure G is C(CH₃)₂, wherein R⁶, R⁸, and G are defined for A385 to A420 as shown below:

R⁶ R⁸ G A385 H H G¹³ A386 H H G¹⁵ A387 H H G¹⁷ A388 H H G¹⁹ A389 H H G²¹ A390 H H G²³ A391 CH₃ CH₃ G¹³ A392 CH₃ CH₃ G¹⁵ A393 CH₃ CH₃ G¹⁷ A394 CH₃ CH₃ G¹⁹ A395 CH₃ CH₃ G²¹ A396 CH₃ CH₃ G²³ A397 CH₃ CH₃ G¹³ A398 CH₃ CH₃ G¹⁵ A399 CH₃ CH₃ G¹⁷ A400 CH₃ CH₃ G¹⁹ A401 CH₃ CH₃ G²¹ A402 CH₃ CH₃ G²³ A403 H H G¹⁴ A404 H H G¹⁶ A405 H H G¹⁸ A406 H H G²⁰ A407 H H G²² A408 H H G²⁴ A409 CH₃ CH₃ G¹⁴ A410 CH₃ CH₃ G¹⁶ A411 CH₃ CH₃ G¹⁸ A412 CH₃ CH₃ G²⁰ A413 CH₃ CH₃ G²² A414 CH₃ CH₃ G²⁴ A415 CH₃ CH₃ G¹⁴ A416 CH₃ CH₃ G¹⁶ A417 CH₃ CH₃ G¹⁸ A418 CH₃ CH₃ G²⁰ A419 CH₃ CH₃ G²² A420 CH₃ CH₃ G²⁴ ligands L_(A421-O) to L_(A1152-O), L_(A421-S) to L_(A1152-S), L_(A421-C) to L_(A1151-C), and L_(A1152-C) that are based on the structure

where the asterisks with an Arabic numeral indicate the points of attachment to the corresponding points of attachment in the structure G,

where for ligands L_(A421-O) to L_(A1152-O), A in the structure G is O,

where for ligands L_(A421-S) to L_(A1152-S), A in the structure G is S, and

where for ligands L_(A421-C) to L_(A1152-C), A in the structure G is C(CH₃)₂, where R², R³, and G are defined for A421 to A1152 as shown below:

R² R³ G A421 H H G³⁷ A422 H H G³⁹ A423 H H G⁴¹ A424 H H G⁴³ A425 H H G⁴⁵ A426 H H G⁴⁷ A427 CH₃ R^(B1) G³⁷ A428 CH₃ R^(B3) G³⁷ A429 CH₃ R^(B5) G³⁷ A430 CH₃ R^(B7) G³⁷ A431 CH₃ R^(B9) G³⁷ A432 CH₃ R^(B11) G³⁷ A433 CH₃ R^(B13) G³⁷ A434 CH₃ R^(B15) G³⁷ A435 CH₃ R^(B17) G³⁷ A436 CH₃ R^(B19) G³⁷ A437 CH₃ R^(B21) G³⁷ A438 CH₃ R^(B23) G³⁷ A439 CH₃ R^(B25) G³⁷ A440 CH₃ R^(B27) G³⁷ A441 CH₃ R^(B29) G³⁷ A442 CH₃ R^(B31) G³⁷ A443 CH₃ R^(B33) G³⁷ A444 CH₃ R^(B35) G³⁷ A445 CH₃ R^(B37) G³⁷ A446 CH₃ R^(B39) G³⁷ A447 CH₃ R^(B41) G³⁷ A448 CH₃ R^(B43) G³⁷ A449 CH₃ R^(B45) G³⁷ A450 CH₃ R^(B47) G³⁷ A451 CH₃ R^(B49) G³⁷ A452 CH₃ R^(B51) G³⁷ A453 CH₃ R^(B53) G³⁷ A454 CH₃ R^(B55) G³⁷ A455 CH₃ R^(B57) G³⁷ A456 CH₃ R^(B59) G³⁷ A457 R^(B1) CH₃ G³⁷ A458 R^(B3) CH₃ G³⁷ A459 R^(B5) CH₃ G³⁷ A460 R^(B7) CH₃ G³⁷ A461 R^(B9) CH₃ G³⁷ A462 R^(B11) CH₃ G³⁷ A463 R^(B13) CH₃ G³⁷ A464 R^(B15) CH₃ G³⁷ A465 R^(B17) CH₃ G³⁷ A466 R^(B19) CH₃ G³⁷ A467 R^(B21) CH₃ G³⁷ A468 R^(B23) CH₃ G³⁷ A469 R^(B25) CH₃ G³⁷ A470 R^(B27) CH₃ G³⁷ A471 R^(B29) CH₃ G³⁷ A472 R^(B31) CH₃ G³⁷ A473 R^(B33) CH₃ G³⁷ A474 R^(B35) CH₃ G³⁷ A475 R^(B37) CH₃ G³⁷ A476 R^(B39) CH₃ G³⁷ A477 R^(B41) CH₃ G³⁷ A478 R^(B43) CH₃ G³⁷ A479 R^(B45) CH₃ G³⁷ A480 R^(B47) CH₃ G³⁷ A481 R^(B49) CH₃ G³⁷ A482 R^(B51) CH₃ G³⁷ A483 R^(B53) CH₃ G³⁷ A484 R^(B55) CH₃ G³⁷ A485 R^(B57) CH₃ G³⁷ A486 R^(B59) CH₃ G³⁷ A487 CH₃ R^(B1) G³⁸ A488 CH₃ R^(B3) G³⁸ A489 CH₃ R^(B5) G³⁸ A490 CH₃ R^(B7) G³⁸ A491 CH₃ R^(B9) G³⁸ A492 CH₃ R^(B11) G³⁸ A493 CH₃ R^(B13) G³⁸ A494 CH₃ R^(B15) G³⁸ A495 CH₃ R^(B17) G³⁸ A496 CH₃ R^(B19) G³⁸ A497 CH₃ R^(B21) G³⁸ A498 CH₃ R^(B23) G³⁸ A499 CH₃ R^(B25) G³⁸ A500 CH₃ R^(B27) G³⁸ A501 CH₃ R^(B29) G³⁸ A502 CH₃ R^(B31) G³⁸ A503 CH₃ R^(B33) G³⁸ A504 CH₃ R^(B35) G³⁸ A505 CH₃ R^(B37) G³⁸ A506 CH₃ R^(B39) G³⁸ A507 CH₃ R^(B41) G³⁸ A508 CH₃ R^(B43) G³⁸ A509 CH₃ R^(B45) G³⁸ A510 CH₃ R^(B47) G³⁸ A511 CH₃ R^(B49) G³⁸ A512 CH₃ R^(B51) G³⁸ A513 CH₃ R^(B53) G³⁸ A514 CH₃ R^(B55) G³⁸ A515 CH₃ R^(B57) G³⁸ A516 CH₃ R^(B59) G³⁸ A517 R^(B1) CH₃ G³⁸ A518 R^(B3) CH₃ G³⁸ A519 R^(B5) CH₃ G³⁸ A520 R^(B7) CH₃ G³⁸ A521 R^(B9) CH₃ G³⁸ A522 R^(B11) CH₃ G³⁸ A523 R^(B13) CH₃ G³⁸ A524 R^(B15) CH₃ G³⁸ A525 R^(B17) CH₃ G³⁸ A526 R^(B19) CH₃ G³⁸ A527 R^(B21) CH₃ G³⁸ A528 R^(B23) CH₃ G³⁸ A529 R^(B25) CH₃ G³⁸ A530 R^(B27) CH₃ G³⁸ A531 R^(B29) CH₃ G³⁸ A532 R^(B31) CH₃ G³⁸ A533 R^(B33) CH₃ G³⁸ A534 R^(B35) CH₃ G³⁸ A535 R^(B37) CH₃ G³⁸ A536 R^(B39) CH₃ G³⁸ A537 R^(B41) CH₃ G³⁸ A538 R^(B43) CH₃ G³⁸ A539 R^(B45) CH₃ G³⁸ A540 R^(B47) CH₃ G³⁸ A541 R^(B49) CH₃ G³⁸ A542 R^(B51) CH₃ G³⁸ A543 R^(B53) CH₃ G³⁸ A544 R^(B55) CH₃ G³⁸ A545 R^(B57) CH₃ G³⁸ A546 R^(B59) CH₃ G³⁸ A547 CH₃ R^(B1) G³⁹ A548 CH₃ R^(B3) G³⁹ A549 CH₃ R^(B5) G³⁹ A550 CH₃ R^(B7) G³⁹ A551 CH₃ R^(B9) G³⁹ A552 CH₃ R^(B11) G³⁹ A553 CH₃ R^(B13) G³⁹ A554 CH₃ R^(B15) G³⁹ A555 CH₃ R^(B17) G³⁹ A556 CH₃ R^(B19) G³⁹ A557 CH₃ R^(B21) G³⁹ A558 CH₃ R^(B23) G³⁹ A559 CH₃ R^(B25) G³⁹ A560 CH₃ R^(B27) G³⁹ A561 CH₃ R^(B29) G³⁹ A562 CH₃ R^(B31) G³⁹ A563 CH₃ R^(B33) G³⁹ A564 CH₃ R^(B35) G³⁹ A565 CH₃ R^(B37) G³⁹ A566 CH₃ R^(B39) G³⁹ A567 CH₃ R^(B41) G³⁹ A568 CH₃ R^(B43) G³⁹ A569 CH₃ R^(B45) G³⁹ A570 CH₃ R^(B47) G³⁹ A571 CH₃ R^(B49) G³⁹ A572 CH₃ R^(B51) G³⁹ A573 CH₃ R^(B53) G³⁹ A574 CH₃ R^(B55) G³⁹ A575 CH₃ R^(B57) G³⁹ A576 CH₃ R^(B59) G³⁹ A577 R^(B1) CH₃ G³⁹ A578 R^(B3) CH₃ G³⁹ A579 R^(B5) CH₃ G³⁹ A580 R^(B7) CH₃ G³⁹ A581 R^(B9) CH₃ G³⁹ A582 R^(B11) CH₃ G³⁹ A583 R^(B13) CH₃ G³⁹ A584 R^(B15) CH₃ G³⁹ A585 R^(B17) CH₃ G³⁹ A586 R^(B19) CH₃ G³⁹ A587 R^(B21) CH₃ G³⁹ A588 R^(B23) CH₃ G³⁹ A589 R^(B25) CH₃ G³⁹ A590 R^(B27) CH₃ G³⁹ A591 R^(B29) CH₃ G³⁹ A592 R^(B31) CH₃ G³⁹ A593 R^(B33) CH₃ G³⁹ A594 R^(B35) CH₃ G³⁹ A595 R^(B37) CH₃ G³⁹ A596 R^(B39) CH₃ G³⁹ A597 R^(B41) CH₃ G³⁹ A598 R^(B43) CH₃ G³⁹ A599 R^(B45) CH₃ G³⁹ A600 R^(B47) CH₃ G³⁹ A601 R^(B49) CH₃ G³⁹ A602 R^(B51) CH₃ G³⁹ A603 R^(B53) CH₃ G³⁹ A604 R^(B55) CH₃ G³⁹ A605 R^(B57) CH₃ G³⁹ A606 R^(B59) CH₃ G³⁹ A607 CH₃ R^(B1) G⁴⁰ A608 CH₃ R^(B3) G⁴⁰ A609 CH₃ R^(B5) G⁴⁰ A610 CH₃ R^(B7) G⁴⁰ A611 CH₃ R^(B9) G⁴⁰ A612 CH₃ R^(B11) G⁴⁰ A613 CH₃ R^(B13) G⁴⁰ A614 CH₃ R^(B15) G⁴⁰ A615 CH₃ R^(B17) G⁴⁰ A616 CH₃ R^(B19) G⁴⁰ A617 CH₃ R^(B21) G⁴⁰ A618 CH₃ R^(B23) G⁴⁰ A619 CH₃ R^(B25) G⁴⁰ A620 CH₃ R^(B27) G⁴⁰ A621 CH₃ R^(B29) G⁴⁰ A622 CH₃ R^(B31) G⁴⁰ A623 CH₃ R^(B33) G⁴⁰ A624 CH₃ R^(B35) G⁴⁰ A625 CH₃ R^(B37) G⁴⁰ A626 CH₃ R^(B39) G⁴⁰ A627 CH₃ R^(B41) G⁴⁰ A628 CH₃ R^(B43) G⁴⁰ A629 CH₃ R^(B45) G⁴⁰ A630 CH₃ R^(B47) G⁴⁰ A631 CH₃ R^(B49) G⁴⁰ A632 CH₃ R^(B51) G⁴⁰ A633 CH₃ R^(B53) G⁴⁰ A634 CH₃ R^(B55) G⁴⁰ A635 CH₃ R^(B57) G⁴⁰ A636 CH₃ R^(B59) G⁴⁰ A637 R^(B1) CH₃ G⁴⁰ A638 R^(B3) CH₃ G⁴⁰ A639 R^(B5) CH₃ G⁴⁰ A640 R^(B7) CH₃ G⁴⁰ A641 R^(B9) CH₃ G⁴⁰ A642 R^(B11) CH₃ G⁴⁰ A643 R^(B13) CH₃ G⁴⁰ A644 R^(B15) CH₃ G⁴⁰ A645 R^(B17) CH₃ G⁴⁰ A646 R^(B19) CH₃ G⁴⁰ A647 R^(B21) CH₃ G⁴⁰ A648 R^(B23) CH₃ G⁴⁰ A649 R^(B25) CH₃ G⁴⁰ A650 R^(B27) CH₃ G⁴⁰ A651 R^(B29) CH₃ G⁴⁰ A652 R^(B31) CH₃ G⁴⁰ A653 R^(B33) CH₃ G⁴⁰ A654 R^(B35) CH₃ G⁴⁰ A655 R^(B37) CH₃ G⁴⁰ A656 R^(B39) CH₃ G⁴⁰ A657 R^(B41) CH₃ G⁴⁰ A658 R^(B43) CH₃ G⁴⁰ A659 R^(B45) CH₃ G⁴⁰ A660 R^(B47) CH₃ G⁴⁰ A661 R^(B49) CH₃ G⁴⁰ A662 R^(B51) CH₃ G⁴⁰ A663 R^(B53) CH₃ G⁴⁰ A664 R^(B55) CH₃ G⁴⁰ A665 H H G³⁸ A666 H H G⁴⁰ A667 H H G⁴² A668 H H G⁴⁴ A669 H H G⁴⁶ A670 H H G⁴⁸ A671 CH₃ R^(B2) G³⁷ A672 CH₃ R^(B4) G³⁷ A673 CH₃ R^(B6) G³⁷ A674 CH₃ R^(B8) G³⁷ A675 CH₃ R^(B10) G³⁷ A676 CH₃ R^(B12) G³⁷ A677 CH₃ R^(B14) G³⁷ A678 CH₃ R^(B16) G³⁷ A679 CH₃ R^(B18) G³⁷ A680 CH₃ R^(B20) G³⁷ A681 CH₃ R^(B22) G³⁷ A682 CH₃ R^(B24) G³⁷ A683 CH₃ R^(B26) G³⁷ A684 CH₃ R^(B28) G³⁷ A685 CH₃ R^(B30) G³⁷ A686 CH₃ R^(B32) G³⁷ A687 CH₃ R^(B34) G³⁷ A688 CH₃ R^(B36) G³⁷ A689 CH₃ R^(B38) G³⁷ A690 CH₃ R^(B40) G³⁷ A691 CH₃ R^(B42) G³⁷ A692 CH₃ R^(B44) G³⁷ A693 CH₃ R^(B46) G³⁷ A694 CH₃ R^(B48) G³⁷ A695 CH₃ R^(B50) G³⁷ A696 CH₃ R^(B52) G³⁷ A697 CH₃ R^(B54) G³⁷ A698 CH₃ R^(B56) G³⁷ A699 CH₃ R^(B58) G³⁷ A700 CH₃ R^(B60) G³⁷ A701 R^(B2) CH₃ G³⁷ A702 R^(B4) CH₃ G³⁷ A703 R^(B6) CH₃ G³⁷ A704 R^(B8) CH₃ G³⁷ A705 R^(B10) CH₃ G³⁷ A706 R^(B12) CH₃ G³⁷ A707 R^(B14) CH₃ G³⁷ A708 R^(B16) CH₃ G³⁷ A709 R^(B18) CH₃ G³⁷ A710 R^(B20) CH₃ G³⁷ A711 R^(B22) CH₃ G³⁷ A712 R^(B24) CH₃ G³⁷ A713 R^(B26) CH₃ G³⁷ A714 R^(B28) CH₃ G³⁷ A715 R^(B30) CH₃ G³⁷ A716 R^(B32) CH₃ G³⁷ A717 R^(B34) CH₃ G³⁷ A718 R^(B36) CH₃ G³⁷ A719 R^(B38) CH₃ G³⁷ A720 R^(B40) CH₃ G³⁷ A721 R^(B42) CH₃ G³⁷ A722 R^(B44) CH₃ G³⁷ A723 R^(B46) CH₃ G³⁷ A724 R^(B48) CH₃ G³⁷ A725 R^(B50) CH₃ G³⁷ A726 R^(B52) CH₃ G³⁷ A727 R^(B54) CH₃ G³⁷ A728 R^(B56) CH₃ G³⁷ A729 R^(B58) CH₃ G³⁷ A730 R^(B60) CH₃ G³⁷ A731 CH₃ R^(B2) G³⁸ A732 CH₃ R^(B4) G³⁸ A733 CH₃ R^(B6) G³⁸ A734 CH₃ R^(B8) G³⁸ A735 CH₃ R^(B10) G³⁸ A736 CH₃ R^(B12) G³⁸ A737 CH₃ R^(B14) G³⁸ A738 CH₃ R^(B16) G³⁸ A739 CH₃ R^(B18) G³⁸ A740 CH₃ R^(B20) G³⁸ A741 CH₃ R^(B22) G³⁸ A742 CH₃ R^(B24) G³⁸ A743 CH₃ R^(B26) G³⁸ A744 CH₃ R^(B28) G³⁸ A745 CH₃ R^(B30) G³⁸ A746 CH₃ R^(B32) G³⁸ A747 CH₃ R^(B34) G³⁸ A748 CH₃ R^(B36) G³⁸ A749 CH₃ R^(B38) G³⁸ A750 CH₃ R^(B40) G³⁸ A751 CH₃ R^(B42) G³⁸ A752 CH₃ R^(B44) G³⁸ A753 CH₃ R^(B46) G³⁸ A754 CH₃ R^(B48) G³⁸ A755 CH₃ R^(B50) G³⁸ A756 CH₃ R^(B52) G³⁸ A757 CH₃ R^(B54) G³⁸ A758 CH₃ R^(B56) G³⁸ A759 CH₃ R^(B58) G³⁸ A760 CH₃ R^(B60) G³⁸ A761 R^(B2) CH₃ G³⁸ A762 R^(B4) CH₃ G³⁸ A763 R^(B6) CH₃ G³⁸ A764 R^(B8) CH₃ G³⁸ A765 R^(B10) CH₃ G³⁸ A766 R^(B12) CH₃ G³⁸ A767 R^(B14) CH₃ G³⁸ A768 R^(B16) CH₃ G³⁸ A769 R^(B18) CH₃ G³⁸ A770 R^(B20) CH₃ G³⁸ A771 R^(B22) CH₃ G³⁸ A772 R^(B24) CH₃ G³⁸ A773 R^(B26) CH₃ G³⁸ A774 R^(B28) CH₃ G³⁸ A775 R^(B30) CH₃ G³⁸ A776 R^(B32) CH₃ G³⁸ A777 R^(B34) CH₃ G³⁸ A778 R^(B36) CH₃ G³⁸ A779 R^(B38) CH₃ G³⁸ A780 R^(B40) CH₃ G³⁸ A781 R^(B42) CH₃ G³⁸ A782 R^(B44) CH₃ G³⁸ A783 R^(B46) CH₃ G³⁸ A784 R^(B48) CH₃ G³⁸ A785 R^(B50) CH₃ G³⁸ A786 R^(B52) CH₃ G³⁸ A787 R^(B54) CH₃ G³⁸ A788 R^(B56) CH₃ G³⁸ A789 R^(B58) CH₃ G³⁸ A790 R^(B60) CH₃ G³⁸ A791 CH₃ R^(B2) G³⁹ A792 CH₃ R^(B4) G³⁹ A793 CH₃ R^(B6) G³⁹ A794 CH₃ R^(B8) G³⁹ A795 CH₃ R^(B10) G³⁹ A796 CH₃ R^(B12) G³⁹ A797 CH₃ R^(B14) G³⁹ A798 CH₃ R^(B16) G³⁹ A799 CH₃ R^(B18) G³⁹ A800 CH₃ R^(B20) G³⁹ A801 CH₃ R^(B22) G³⁹ A802 CH₃ R^(B24) G³⁹ A803 CH₃ R^(B26) G³⁹ A804 CH₃ R^(B28) G³⁹ A805 CH₃ R^(B30) G³⁹ A806 CH₃ R^(B32) G³⁹ A807 CH₃ R^(B34) G³⁹ A808 CH₃ R^(B36) G³⁹ A809 CH₃ R^(B38) G³⁹ A810 CH₃ R^(B40) G³⁹ A811 CH₃ R^(B42) G³⁹ A812 CH₃ R^(B44) G³⁹ A813 CH₃ R^(B46) G³⁹ A814 CH₃ R^(B48) G³⁹ A815 CH₃ R^(B50) G³⁹ A816 CH₃ R^(B52) G³⁹ A817 CH₃ R^(B54) G³⁹ A818 CH₃ R^(B56) G³⁹ A819 CH₃ R^(B58) G³⁹ A820 CH₃ R^(B60) G³⁹ A821 R^(B2) CH₃ G³⁹ A822 R^(B4) CH₃ G³⁹ A823 R^(B6) CH₃ G³⁹ A824 R^(B8) CH₃ G³⁹ A825 R^(B10) CH₃ G³⁹ A826 R^(B12) CH₃ G³⁹ A827 R^(B14) CH₃ G³⁹ A828 R^(B16) CH₃ G³⁹ A829 R^(B18) CH₃ G³⁹ A830 R^(B20) CH₃ G³⁹ A831 R^(B22) CH₃ G³⁹ A832 R^(B24) CH₃ G³⁹ A833 R^(B26) CH₃ G³⁹ A834 R^(B28) CH₃ G³⁹ A835 R^(B30) CH₃ G³⁹ A836 R^(B32) CH₃ G³⁹ A837 R^(B34) CH₃ G³⁹ A838 R^(B36) CH₃ G³⁹ A839 R^(B38) CH₃ G³⁹ A840 R^(B40) CH₃ G³⁹ A841 R^(B42) CH₃ G³⁹ A842 R^(B44) CH₃ G³⁹ A843 R^(B46) CH₃ G³⁹ A844 R^(B48) CH₃ G³⁹ A845 R^(B50) CH₃ G³⁹ A846 R^(B52) CH₃ G³⁹ A847 R^(B54) CH₃ G³⁹ A848 R^(B56) CH₃ G³⁹ A849 R^(B58) CH₃ G³⁹ A850 R^(B60) CH₃ G³⁹ A851 CH₃ R^(B2) G⁴⁰ A852 CH₃ R^(B4) G⁴⁰ A853 CH₃ R^(B6) G⁴⁰ A854 CH₃ R^(B8) G⁴⁰ A855 CH₃ R^(B10) G⁴⁰ A856 CH₃ R^(B12) G⁴⁰ A857 CH₃ R^(B14) G⁴⁰ A858 CH₃ R^(B16) G⁴⁰ A859 CH₃ R^(B18) G⁴⁰ A860 CH₃ R^(B20) G⁴⁰ A861 CH₃ R^(B22) G⁴⁰ A862 CH₃ R^(B24) G⁴⁰ A863 CH₃ R^(B26) G⁴⁰ A864 CH₃ R^(B28) G⁴⁰ A865 CH₃ R^(B30) G⁴⁰ A866 CH₃ R^(B32) G⁴⁰ A867 CH₃ R^(B34) G⁴⁰ A868 CH₃ R^(B36) G⁴⁰ A869 CH₃ R^(B38) G⁴⁰ A870 CH₃ R^(B40) G⁴⁰ A871 CH₃ R^(B42) G⁴⁰ A872 CH₃ R^(B44) G⁴⁰ A873 CH₃ R^(B46) G⁴⁰ A874 CH₃ R^(B48) G⁴⁰ A875 CH₃ R^(B50) G⁴⁰ A876 CH₃ R^(B52) G⁴⁰ A877 CH₃ R^(B54) G⁴⁰ A878 CH₃ R^(B56) G⁴⁰ A879 CH₃ R^(B58) G⁴⁰ A880 CH₃ R^(B60) G⁴⁰ A881 R^(B2) CH₃ G⁴⁰ A882 R^(B4) CH₃ G⁴⁰ A883 R^(B6) CH₃ G⁴⁰ A884 R^(B8) CH₃ G⁴⁰ A885 R^(B10) CH₃ G⁴⁰ A886 R^(B12) CH₃ G⁴⁰ A887 R^(B14) CH₃ G⁴⁰ A888 R^(B16) CH₃ G⁴⁰ A889 R^(B18) CH₃ G⁴⁰ A890 R^(B20) CH₃ G⁴⁰ A891 R^(B22) CH₃ G⁴⁰ A892 R^(B24) CH₃ G⁴⁰ A893 R^(B26) CH₃ G⁴⁰ A894 R^(B28) CH₃ G⁴⁰ A895 R^(B30) CH₃ G⁴⁰ A896 R^(B32) CH₃ G⁴⁰ A897 R^(B34) CH₃ G⁴⁰ A898 R^(B36) CH₃ G⁴⁰ A899 R^(B38) CH₃ G⁴⁰ A900 R^(B40) CH₃ G⁴⁰ A901 R^(B42) CH₃ G⁴⁰ A902 R^(B44) CH₃ G⁴⁰ A903 R^(B46) CH₃ G⁴⁰ A904 R^(B48) CH₃ G⁴⁰ A905 R^(B50) CH₃ G⁴⁰ A906 R^(B52) CH₃ G⁴⁰ A907 R^(B54) CH₃ G⁴⁰ A908 R^(B56) CH₃ G⁴⁰ A909 R^(B57) CH₃ G⁴⁰ A910 R^(B59) CH₃ G⁴⁰ A911 CH₃ R^(B1) G⁴¹ A912 CH₃ R^(B3) G⁴¹ A913 CH₃ R^(B5) G⁴¹ A914 CH₃ R^(B7) G⁴¹ A915 CH₃ R^(B9) G⁴¹ A916 CH₃ R^(B11) G⁴¹ A917 CH₃ R^(B13) G⁴¹ A918 CH₃ R^(B15) G⁴¹ A919 CH₃ R^(B17) G⁴¹ A920 CH₃ R^(B19) G⁴¹ A921 CH₃ R^(B21) G⁴¹ A922 CH₃ R^(B23) G⁴¹ A923 CH₃ R^(B25) G⁴¹ A924 CH₃ R^(B27) G⁴¹ A925 CH₃ R^(B29) G⁴¹ A926 CH₃ R^(B31) G⁴¹ A927 CH₃ R^(B33) G⁴¹ A928 CH₃ R^(B35) G⁴¹ A929 CH₃ R^(B37) G⁴¹ A930 CH₃ R^(B39) G⁴¹ A931 CH₃ R^(B41) G⁴¹ A932 CH₃ R^(B43) G⁴¹ A933 CH₃ R^(B45) G⁴¹ A934 CH₃ R^(B47) G⁴¹ A935 CH₃ R^(B49) G⁴¹ A936 CH₃ R^(B51) G⁴¹ A937 CH₃ R^(B53) G⁴¹ A938 CH₃ R^(B55) G⁴¹ A939 CH₃ R^(B57) G⁴¹ A940 CH₃ R^(B59) G⁴¹ A941 R^(B1) CH₃ G⁴¹ A942 R^(B3) CH₃ G⁴¹ A943 R^(B5) CH₃ G⁴¹ A944 R^(B7) CH₃ G⁴¹ A945 R^(B9) CH₃ G⁴¹ A946 R^(B11) CH₃ G⁴¹ A947 R^(B13) CH₃ G⁴¹ A948 R^(B15) CH₃ G⁴¹ A949 R^(B17) CH₃ G⁴¹ A950 R^(B19) CH₃ G⁴¹ A951 R^(B21) CH₃ G⁴¹ A952 R^(B23) CH₃ G⁴¹ A953 R^(B25) CH₃ G⁴¹ A954 R^(B27) CH₃ G⁴¹ A955 R^(B29) CH₃ G⁴¹ A956 R^(B31) CH₃ G⁴¹ A957 R^(B33) CH₃ G⁴¹ A958 R^(B35) CH₃ G⁴¹ A959 R^(B37) CH₃ G⁴¹ A960 R^(B39) CH₃ G⁴¹ A961 R^(B41) CH₃ G⁴¹ A962 R^(B43) CH₃ G⁴¹ A963 R^(B45) CH₃ G⁴¹ A964 R^(B47) CH₃ G⁴¹ A965 R^(B49) CH₃ G⁴¹ A966 R^(B51) CH₃ G⁴¹ A967 R^(B53) CH₃ G⁴¹ A968 R^(B55) CH₃ G⁴¹ A969 R^(B57) CH₃ G⁴¹ A970 R^(B59) CH₃ G⁴¹ A971 CH₃ R^(B1) G⁴² A972 CH₃ R^(B3) G⁴² A973 CH₃ R^(B5) G⁴² A974 CH₃ R^(B7) G⁴² A975 CH₃ R^(B9) G⁴² A976 CH₃ R^(B11) G⁴² A977 CH₃ R^(B13) G⁴² A978 CH₃ R^(B15) G⁴² A979 CH₃ R^(B17) G⁴² A980 CH₃ R^(B19) G⁴² A981 CH₃ R^(B21) G⁴² A982 CH₃ R^(B23) G⁴² A983 CH₃ R^(B25) G⁴² A984 CH₃ R^(B27) G⁴² A985 CH₃ R^(B29) G⁴² A986 CH₃ R^(B31) G⁴² A987 CH₃ R^(B33) G⁴² A988 CH₃ R^(B35) G⁴² A989 CH₃ R^(B37) G⁴² A990 CH₃ R^(B39) G⁴² A991 CH₃ R^(B41) G⁴² A992 CH₃ R^(B43) G⁴² A993 CH₃ R^(B45) G⁴² A994 CH₃ R^(B47) G⁴² A995 CH₃ R^(B49) G⁴² A996 CH₃ R^(B51) G⁴² A997 CH₃ R^(B53) G⁴² A998 CH₃ R^(B55) G⁴² A999 CH₃ R^(B57) G⁴² A1000 CH₃ R^(B59) G⁴² A1001 R^(B1) CH₃ G⁴² A1002 R^(B3) CH₃ G⁴² A1003 R^(B5) CH₃ G⁴² A1004 R^(B7) CH₃ G⁴² A1005 R^(B9) CH₃ G⁴² A1006 R^(B11) CH₃ G⁴² A1007 R^(B13) CH₃ G⁴² A1008 R^(B15) CH₃ G⁴² A1009 R^(B17) CH₃ G⁴² A1010 R^(B19) CH₃ G⁴² A1011 R^(B21) CH₃ G⁴² A1012 R^(B23) CH₃ G⁴² A1013 R^(B25) CH₃ G⁴² A1014 R^(B27) CH₃ G⁴² A1015 R^(B29) CH₃ G⁴² A1016 R^(B31) CH₃ G⁴² A1017 R^(B33) CH₃ G⁴² A1018 R^(B35) CH₃ G⁴² A1019 R^(B37) CH₃ G⁴² A1020 R^(B39) CH₃ G⁴² A1021 R^(B41) CH₃ G⁴² A1022 R^(B43) CH₃ G⁴² A1023 R^(B45) CH₃ G⁴² A1024 R^(B47) CH₃ G⁴² A1025 R^(B49) CH₃ G⁴² A1026 R^(B51) CH₃ G⁴² A1027 R^(B53) CH₃ G⁴² A1028 R^(B55) CH₃ G⁴² A1029 R^(B57) CH₃ G⁴² A1030 R^(B59) CH₃ G⁴² A1031 R^(B58) CH₃ G⁴⁰ A1032 R^(B60) CH₃ G⁴⁰ A1033 CH₃ R^(B2) G⁴¹ A1034 CH₃ R^(B4) G⁴¹ A1035 CH₃ R^(B6) G⁴¹ A1036 CH₃ R^(B8) G⁴¹ A1037 CH₃ R^(B10) G⁴¹ A1038 CH₃ R^(B12) G⁴¹ A1039 CH₃ R^(B14) G⁴¹ A1040 CH₃ R^(B16) G⁴¹ A1041 CH₃ R^(B18) G⁴¹ A1042 CH₃ R^(B20) G⁴¹ A1043 CH₃ R^(B22) G⁴¹ A1044 CH₃ R^(B24) G⁴¹ A1045 CH₃ R^(B26) G⁴¹ A1046 CH₃ R^(B28) G⁴¹ A1047 CH₃ R^(B30) G⁴¹ A1048 CH₃ R^(B32) G⁴¹ A1049 CH₃ R^(B34) G⁴¹ A1050 CH₃ R^(B36) G⁴¹ A1051 CH₃ R^(B38) G⁴¹ A1052 CH₃ R^(B40) G⁴¹ A1053 CH₃ R^(B42) G⁴¹ A1054 CH₃ R^(B44) G⁴¹ A1055 CH₃ R^(B46) G⁴¹ A1056 CH₃ R^(B48) G⁴¹ A1057 CH₃ R^(B50) G⁴¹ A1058 CH₃ R^(B52) G⁴¹ A1059 CH₃ R^(B54) G⁴¹ A1060 CH₃ R^(B56) G⁴¹ A1061 CH₃ R^(B58) G⁴¹ A1062 CH₃ R^(B60) G⁴¹ A1063 R^(B2) CH₃ G⁴¹ A1064 R^(B4) CH₃ G⁴¹ A1065 R^(B6) CH₃ G⁴¹ A1066 R^(B8) CH₃ G⁴¹ A1067 R^(B10) CH₃ G⁴¹ A1068 R^(B12) CH₃ G⁴¹ A1069 R^(B14) CH₃ G⁴¹ A1070 R^(B16) CH₃ G⁴¹ A1071 R^(B18) CH₃ G⁴¹ A1072 R^(B20) CH₃ G⁴¹ A1073 R^(B22) CH₃ G⁴¹ A1074 R^(B24) CH₃ G⁴¹ A1075 R^(B26) CH₃ G⁴¹ A1076 R^(B28) CH₃ G⁴¹ A1077 R^(B30) CH₃ G⁴¹ A1078 R^(B32) CH₃ G⁴¹ A1079 R^(B34) CH₃ G⁴¹ A1080 R^(B36) CH₃ G⁴¹ A1081 R^(B38) CH₃ G⁴¹ A1082 R^(B40) CH₃ G⁴¹ A1083 R^(B42) CH₃ G⁴¹ A1084 R^(B44) CH₃ G⁴¹ A1085 R^(B46) CH₃ G⁴¹ A1086 R^(B48) CH₃ G⁴¹ A1087 R^(B50) CH₃ G⁴¹ A1088 R^(B52) CH₃ G⁴¹ A1089 R^(B54) CH₃ G⁴¹ A1090 R^(B56) CH₃ G⁴¹ A1091 R^(B58) CH₃ G⁴¹ A1092 R^(B60) CH₃ G⁴¹ A1093 CH₃ R^(B2) G⁴² A1094 CH₃ R^(B4) G⁴² A1095 CH₃ R^(B6) G⁴² A1096 CH₃ R^(B8) G⁴² A1097 CH₃ R^(B10) G⁴² A1098 CH₃ R^(B12) G⁴² A1099 CH₃ R^(B14) G⁴² A1100 CH₃ R^(B16) G⁴² A1101 CH₃ R^(B18) G⁴² A1102 CH₃ R^(B20) G⁴² A1103 CH₃ R^(B22) G⁴² A1104 CH₃ R^(B24) G⁴² A1105 CH₃ R^(B26) G⁴² A1106 CH₃ R^(B28) G⁴² A1107 CH₃ R^(B30) G⁴² A1108 CH₃ R^(B32) G⁴² A1109 CH₃ R^(B34) G⁴² A1110 CH₃ R^(B36) G⁴² A1111 CH₃ R^(B38) G⁴² A1112 CH₃ R^(B40) G⁴² A1113 CH₃ R^(B42) G⁴² A1114 CH₃ R^(B44) G⁴² A1115 CH₃ R^(B46) G⁴² A1116 CH₃ R^(B48) G⁴² A1117 CH₃ R^(B50) G⁴² A1118 CH₃ R^(B52) G⁴² A1119 CH₃ R^(B54) G⁴² A1120 CH₃ R^(B56) G⁴² A1121 CH₃ R^(B58) G⁴² A1122 CH₃ R^(B60) G⁴² A1123 R^(B2) CH₃ G⁴² A1124 R^(B4) CH₃ G⁴² A1125 R^(B6) CH₃ G⁴² A1126 R^(B8) CH₃ G⁴² A1127 R^(B10) CH₃ G⁴² A1128 R^(B12) CH₃ G⁴² A1129 R^(B14) CH₃ G⁴² A1130 R^(B16) CH₃ G⁴² A1131 R^(B18) CH₃ G⁴² A1132 R^(B20) CH₃ G⁴² A1133 R^(B22) CH₃ G⁴² A1134 R^(B24) CH₃ G⁴² A1135 R^(B26) CH₃ G⁴² A1136 R^(B28) CH₃ G⁴² A1137 R^(B30) CH₃ G⁴² A1138 R^(B32) CH₃ G⁴² A1139 R^(B34) CH₃ G⁴² A1140 R^(B36) CH₃ G⁴² A1141 R^(B38) CH₃ G⁴² A1142 R^(B40) CH₃ G⁴² A1143 R^(B42) CH₃ G⁴² A1144 R^(B44) CH₃ G⁴² A1145 R^(B46) CH₃ G⁴² A1146 R^(B48) CH₃ G⁴² A1147 R^(B50) CH₃ G⁴² A1148 R^(B52) CH₃ G⁴² A1149 R^(B54) CH₃ G⁴² A1150 R^(B56) CH₃ G⁴² A1151 R^(B58) CH₃ G⁴² A1152 R^(B60) CH₃ G⁴², ligands L_(A1153-O) to L_(A1764-O), L_(A1153-S) to L_(A1764-S), L_(A1153-C) to L_(A1763-C), and L_(A1764-C) that are based on the structure

where the asterisks with an Arabic numeral indicate the points of attachment to the corresponding points of attachment in the structure G,

where for ligands L_(A1153-O) to L_(A1764-O), A in the structure G is O,

where for ligands L_(A1153-S) to L_(A1764-S), A in the structure G is S, and

where for ligands L_(A1153-C) to L_(A1764-C), A in the structure G is C(CH₃)₂, where R², R³, and G are defined for A1153 to A1764 as shown below:

R² R³ G A1153 H H G³⁷ A1154 H H G³⁹ A1155 H H G⁴¹ A1156 H H G⁴³ A1157 H H G⁴⁵ A1158 H H G⁴⁷ A1159 CH₃ R^(B1) G³⁷ A1160 CH₃ R^(B3) G³⁷ A1161 CH₃ R^(B5) G³⁷ A1162 CH₃ R^(B7) G³⁷ A1163 CH₃ R^(B9) G³⁷ A1164 CH₃ R^(B11) G³⁷ A1165 CH₃ R^(B13) G³⁷ A1166 CH₃ R^(B15) G³⁷ A1167 CH₃ R^(B17) G³⁷ A1168 CH₃ R^(B19) G³⁷ A1169 CH₃ R^(B21) G³⁷ A1170 CH₃ R^(B23) G³⁷ A1171 CH₃ R^(B25) G³⁷ A1172 CH₃ R^(B27) G³⁷ A1173 CH₃ R^(B29) G³⁷ A1174 CH₃ R^(B31) G³⁷ A1175 CH₃ R^(B33) G³⁷ A1176 CH₃ R^(B35) G³⁷ A1177 CH₃ R^(B37) G³⁷ A1178 CH₃ R^(B39) G³⁷ A1179 CH₃ R^(B41) G³⁷ A1180 CH₃ R^(B43) G³⁷ A1181 CH₃ R^(B45) G³⁷ A1182 CH₃ R^(B47) G³⁷ A1183 CH₃ R^(B49) G³⁷ A1184 CH₃ R^(B51) G³⁷ A1185 CH₃ R^(B53) G³⁷ A1186 CH₃ R^(B55) G³⁷ A1187 CH₃ R^(B57) G³⁷ A1188 CH₃ R^(B59) G³⁷ A1189 R^(B1) CH₃ G³⁷ A1190 R^(B3) CH₃ G³⁷ A1191 R^(B5) CH₃ G³⁷ A1192 R^(B7) CH₃ G³⁷ A1193 R^(B9) CH₃ G³⁷ A1194 R^(B11) CH₃ G³⁷ A1195 R^(B13) CH₃ G³⁷ A1196 R^(B15) CH₃ G³⁷ A1197 R^(B17) CH₃ G³⁷ A1198 R^(B19) CH₃ G³⁷ A1199 R^(B21) CH₃ G³⁷ A1200 R^(B23) CH₃ G³⁷ A1201 R^(B25) CH₃ G³⁷ A1202 R^(B27) CH₃ G³⁷ A1203 R^(B29) CH₃ G³⁷ A1204 R^(B31) CH₃ G³⁷ A1205 R^(B33) CH₃ G³⁷ A1206 R^(B35) CH₃ G³⁷ A1207 R^(B37) CH₃ G³⁷ A1208 R^(B39) CH₃ G³⁷ A1209 R^(B41) CH₃ G³⁷ A1210 R^(B43) CH₃ G³⁷ A1211 R^(B45) CH₃ G³⁷ A1212 R^(B47) CH₃ G³⁷ A1213 R^(B49) CH₃ G³⁷ A1214 R^(B51) CH₃ G³⁷ A1215 R^(B53) CH₃ G³⁷ A1216 R^(B55) CH₃ G³⁷ A1217 R^(B57) CH₃ G³⁷ A1218 R^(B59) CH₃ G³⁷ A1219 CH₃ R^(B1) G³⁹ A1220 CH₃ R^(B3) G³⁹ A1221 CH₃ R^(B5) G³⁹ A1222 CH₃ R^(B7) G³⁹ A1223 CH₃ R^(B9) G³⁹ A1224 CH₃ R^(B11) G³⁹ A1225 CH₃ R^(B13) G³⁹ A1226 CH₃ R^(B15) G³⁹ A1227 CH₃ R^(B17) G³⁹ A1228 CH₃ R^(B19) G³⁹ A1229 CH₃ R^(B21) G³⁹ A1230 CH₃ R^(B23) G³⁹ A1231 CH₃ R^(B25) G³⁹ A1232 CH₃ R^(B27) G³⁹ A1233 CH₃ R^(B29) G³⁹ A1234 CH₃ R^(B31) G³⁹ A1235 CH₃ R^(B33) G³⁹ A1236 CH₃ R^(B35) G³⁹ A1237 CH₃ R^(B37) G³⁹ A1238 CH₃ R^(B39) G³⁹ A1239 CH₃ R^(B41) G³⁹ A1240 CH₃ R^(B43) G³⁹ A1241 CH₃ R^(B45) G³⁹ A1242 CH₃ R^(B47) G³⁹ A1243 CH₃ R^(B49) G³⁹ A1244 CH₃ R^(B51) G³⁹ A1245 CH₃ R^(B53) G³⁹ A1246 CH₃ R^(B55) G³⁹ A1247 CH₃ R^(B57) G³⁹ A1248 CH₃ R^(B59) G³⁹ A1249 R^(B1) CH₃ G³⁹ A1250 R^(B3) CH₃ G³⁹ A1251 R^(B5) CH₃ G³⁹ A1252 R^(B7) CH₃ G³⁹ A1253 R^(B9) CH₃ G³⁹ A1254 R^(B11) CH₃ G³⁹ A1255 R^(B13) CH₃ G³⁹ A1256 R^(B15) CH₃ G³⁹ A1257 R^(B17) CH₃ G³⁹ A1258 R^(B19) CH₃ G³⁹ A1259 R^(B21) CH₃ G³⁹ A1260 R^(B23) CH₃ G³⁹ A1261 R^(B25) CH₃ G³⁹ A1262 R^(B27) CH₃ G³⁹ A1263 R^(B29) CH₃ G³⁹ A1264 R^(B31) CH₃ G³⁹ A1265 R^(B33) CH₃ G³⁹ A1266 R^(B35) CH₃ G³⁹ A1267 R^(B37) CH₃ G³⁹ A1268 R^(B39) CH₃ G³⁹ A1269 R^(B41) CH₃ G³⁹ A1270 R^(B43) CH₃ G³⁹ A1271 R^(B45) CH₃ G³⁹ A1272 R^(B47) CH₃ G³⁹ A1273 R^(B49) CH₃ G³⁹ A1274 R^(B51) CH₃ G³⁹ A1275 R^(B53) CH₃ G³⁹ A1276 R^(B55) CH₃ G³⁹ A1277 R^(B57) CH₃ G³⁹ A1278 R^(B59) CH₃ G³⁹ A1279 CH₃ R^(B1) G⁴⁰ A1280 CH₃ R^(B3) G⁴⁰ A1281 CH₃ R^(B5) G⁴⁰ A1282 CH₃ R^(B7) G⁴⁰ A1283 CH₃ R^(B9) G⁴⁰ A1284 CH₃ R^(B11) G⁴⁰ A1285 CH₃ R^(B13) G⁴⁰ A1286 CH₃ R^(B15) G⁴⁰ A1287 CH₃ R^(B17) G⁴⁰ A1288 CH₃ R^(B19) G⁴⁰ A1289 CH₃ R^(B21) G⁴⁰ A1290 CH₃ R^(B23) G⁴⁰ A1291 CH₃ R^(B25) G⁴⁰ A1292 CH₃ R^(B27) G⁴⁰ A1293 CH₃ R^(B29) G⁴⁰ A1294 CH₃ R^(B31) G⁴⁰ A1295 CH₃ R^(B33) G⁴⁰ A1296 CH₃ R^(B35) G⁴⁰ A1297 CH₃ R^(B37) G⁴⁰ A1298 CH₃ R^(B39) G⁴⁰ A1299 CH₃ R^(B41) G⁴⁰ A1300 CH₃ R^(B43) G⁴⁰ A1301 CH₃ R^(B45) G⁴⁰ A1302 CH₃ R^(B47) G⁴⁰ A1303 CH₃ R^(B49) G⁴⁰ A1304 CH₃ R^(B51) G⁴⁰ A1305 CH₃ R^(B53) G⁴⁰ A1306 CH₃ R^(B55) G⁴⁰ A1307 CH₃ R^(B57) G⁴⁰ A1308 CH₃ R^(B59) G⁴⁰ A1309 R^(B1) CH₃ G⁴⁰ A1310 R^(B3) CH₃ G⁴⁰ A1311 R^(B5) CH₃ G⁴⁰ A1312 R^(B7) CH₃ G⁴⁰ A1313 R^(B9) CH₃ G⁴⁰ A1314 R^(B11) CH₃ G⁴⁰ A1315 R^(B13) CH₃ G⁴⁰ A1316 R^(B15) CH₃ G⁴⁰ A1317 R^(B17) CH₃ G⁴⁰ A1318 R^(B19) CH₃ G⁴⁰ A1319 R^(B21) CH₃ G⁴⁰ A1320 R^(B23) CH₃ G⁴⁰ A1321 R^(B25) CH₃ G⁴⁰ A1322 R^(B27) CH₃ G⁴⁰ A1323 R^(B29) CH₃ G⁴⁰ A1324 R^(B31) CH₃ G⁴⁰ A1325 R^(B33) CH₃ G⁴⁰ A1326 R^(B35) CH₃ G⁴⁰ A1327 R^(B37) CH₃ G⁴⁰ A1328 R^(B39) CH₃ G⁴⁰ A1329 R^(B41) CH₃ G⁴⁰ A1330 R^(B43) CH₃ G⁴⁰ A1331 R^(B45) CH₃ G⁴⁰ A1332 R^(B47) CH₃ G⁴⁰ A1333 R^(B49) CH₃ G⁴⁰ A1334 R^(B51) CH₃ G⁴⁰ A1335 R^(B53) CH₃ G⁴⁰ A1336 R^(B55) CH₃ G⁴⁰ A1337 R^(B57) CH₃ G⁴⁰ A1338 R^(B59) CH₃ G⁴⁰ A1339 CH₃ R^(B1) G⁴¹ A1340 CH₃ R^(B3) G⁴¹ A1341 CH₃ R^(B5) G⁴¹ A1342 CH₃ R^(B7) G⁴¹ A1343 CH₃ R^(B9) G⁴¹ A1344 CH₃ R^(B11) G⁴¹ A1345 CH₃ R^(B13) G⁴¹ A1346 CH₃ R^(B15) G⁴¹ A1347 CH₃ R^(B17) G⁴¹ A1348 CH₃ R^(B19) G⁴¹ A1349 CH₃ R^(B21) G⁴¹ A1350 CH₃ R^(B23) G⁴¹ A1351 CH₃ R^(B25) G⁴¹ A1352 CH₃ R^(B27) G⁴¹ A1353 CH₃ R^(B29) G⁴¹ A1354 CH₃ R^(B31) G⁴¹ A1355 CH₃ R^(B33) G⁴¹ A1356 CH₃ R^(B35) G⁴¹ A1357 H H G³⁸ A1358 H H G⁴⁰ A1359 H H G⁴² A1360 H H G⁴⁴ A1361 H H G⁴⁶ A1362 H H G⁴⁸ A1363 CH₃ R^(B2) G³⁷ A1364 CH₃ R^(B4) G³⁷ A1365 CH₃ R^(B6) G³⁷ A1366 CH₃ R^(B8) G³⁷ A1367 CH₃ R^(B10) G³⁷ A1368 CH₃ R^(B12) G³⁷ A1369 CH₃ R^(B14) G³⁷ A1370 CH₃ R^(B16) G³⁷ A1371 CH₃ R^(B18) G³⁷ A1372 CH₃ R^(B20) G³⁷ A1373 CH₃ R^(B22) G³⁷ A1374 CH₃ R^(B24) G³⁷ A1375 CH₃ R^(B26) G³⁷ A1376 CH₃ R^(B28) G³⁷ A1377 CH₃ R^(B30) G³⁷ A1378 CH₃ R^(B32) G³⁷ A1379 CH₃ R^(B34) G³⁷ A1380 CH₃ R^(B36) G³⁷ A1381 CH₃ R^(B38) G³⁷ A1382 CH₃ R^(B40) G³⁷ A1383 CH₃ R^(B42) G³⁷ A1384 CH₃ R^(B44) G³⁷ A1385 CH₃ R^(B46) G³⁷ A1386 CH₃ R^(B48) G³⁷ A1387 CH₃ R^(B50) G³⁷ A1388 CH₃ R^(B52) G³⁷ A1389 CH₃ R^(B54) G³⁷ A1390 CH₃ R^(B56) G³⁷ A1391 CH₃ R^(B58) G³⁷ A1392 CH₃ R^(B60) G³⁷ A1393 R^(B2) CH₃ G³⁷ A1394 R^(B4) CH₃ G³⁷ A1395 R^(B6) CH₃ G³⁷ A1396 R^(B8) CH₃ G³⁷ A1397 R^(B10) CH₃ G³⁷ A1398 R^(B12) CH₃ G³⁷ A1399 R^(B14) CH₃ G³⁷ A1400 R^(B16) CH₃ G³⁷ A1401 R^(B18) CH₃ G³⁷ A1402 R^(B20) CH₃ G³⁷ A1403 R^(B22) CH₃ G³⁷ A1404 R^(B24) CH₃ G³⁷ A1405 R^(B26) CH₃ G³⁷ A1406 R^(B28) CH₃ G³⁷ A1407 R^(B30) CH₃ G³⁷ A1408 R^(B32) CH₃ G³⁷ A1409 R^(B34) CH₃ G³⁷ A1410 R^(B36) CH₃ G³⁷ A1411 R^(B38) CH₃ G³⁷ A1412 R^(B40) CH₃ G³⁷ A1413 R^(B42) CH₃ G³⁷ A1414 R^(B44) CH₃ G³⁷ A1415 R^(B46) CH₃ G³⁷ A1416 R^(B48) CH₃ G³⁷ A1417 R^(B50) CH₃ G³⁷ A1418 R^(B52) CH₃ G³⁷ A1419 R^(B54) CH₃ G³⁷ A1420 R^(B56) CH₃ G³⁷ A1421 R^(B58) CH₃ G³⁷ A1422 R^(B60) CH₃ G³⁷ A1423 CH₃ R^(B2) G³⁹ A1424 CH₃ R^(B4) G³⁹ A1425 CH₃ R^(B6) G³⁹ A1426 CH₃ R^(B8) G³⁹ A1427 CH₃ R^(B10) G³⁹ A1428 CH₃ R^(B12) G³⁹ A1429 CH₃ R^(B14) G³⁹ A1430 CH₃ R^(B16) G³⁹ A1431 CH₃ R^(B18) G³⁹ A1432 CH₃ R^(B20) G³⁹ A1433 CH₃ R^(B22) G³⁹ A1434 CH₃ R^(B24) G³⁹ A1435 CH₃ R^(B26) G³⁹ A1436 CH₃ R^(B28) G³⁹ A1437 CH₃ R^(B30) G³⁹ A1438 CH₃ R^(B32) G³⁹ A1439 CH₃ R^(B34) G³⁹ A1440 CH₃ R^(B36) G³⁹ A1441 CH₃ R^(B38) G³⁹ A1442 CH₃ R^(B40) G³⁹ A1443 CH₃ R^(B42) G³⁹ A1444 CH₃ R^(B44) G³⁹ A1445 CH₃ R^(B46) G³⁹ A1446 CH₃ R^(B48) G³⁹ A1447 CH₃ R^(B50) G³⁹ A1448 CH₃ R^(B52) G³⁹ A1449 CH₃ R^(B54) G³⁹ A1450 CH₃ R^(B56) G³⁹ A1451 CH₃ R^(B58) G³⁹ A1452 CH₃ R^(B60) G³⁹ A1453 R^(B2) CH₃ G³⁹ A1454 R^(B4) CH₃ G³⁹ A1455 R^(B6) CH₃ G³⁹ A1456 R^(B8) CH₃ G³⁹ A1457 R^(B10) CH₃ G³⁹ A1458 R^(B12) CH₃ G³⁹ A1459 R^(B14) CH₃ G³⁹ A1460 R^(B16) CH₃ G³⁹ A1461 R^(B18) CH₃ G³⁹ A1462 R^(B20) CH₃ G³⁹ A1463 R^(B22) CH₃ G³⁹ A1464 R^(B24) CH₃ G³⁹ A1465 R^(B26) CH₃ G³⁹ A1466 R^(B28) CH₃ G³⁹ A1467 R^(B30) CH₃ G³⁹ A1468 R^(B32) CH₃ G³⁹ A1469 R^(B34) CH₃ G³⁹ A1470 R^(B36) CH₃ G³⁹ A1471 R^(B38) CH₃ G³⁹ A1472 R^(B40) CH₃ G³⁹ A1473 R^(B42) CH₃ G³⁹ A1474 R^(B44) CH₃ G³⁹ A1475 R^(B46) CH₃ G³⁹ A1476 R^(B48) CH₃ G³⁹ A1477 R^(B50) CH₃ G³⁹ A1478 R^(B52) CH₃ G³⁹ A1479 R^(B54) CH₃ G³⁹ A1480 R^(B56) CH₃ G³⁹ A1481 R^(B58) CH₃ G³⁹ A1482 R^(B60) CH₃ G³⁹ A1483 CH₃ R^(B2) G⁴⁰ A1484 CH₃ R^(B4) G⁴⁰ A1485 CH₃ R^(B6) G⁴⁰ A1486 CH₃ R^(B8) G⁴⁰ A1487 CH₃ R^(B10) G⁴⁰ A1488 CH₃ R^(B12) G⁴⁰ A1489 CH₃ R^(B14) G⁴⁰ A1490 CH₃ R^(B16) G⁴⁰ A1491 CH₃ R^(B18) G⁴⁰ A1492 CH₃ R^(B20) G⁴⁰ A1493 CH₃ R^(B22) G⁴⁰ A1494 CH₃ R^(B24) G⁴⁰ A1495 CH₃ R^(B26) G⁴⁰ A1496 CH₃ R^(B28) G⁴⁰ A1497 CH₃ R^(B30) G⁴⁰ A1498 CH₃ R^(B32) G⁴⁰ A1499 CH₃ R^(B34) G⁴⁰ A1500 CH₃ R^(B36) G⁴⁰ A1501 CH₃ R^(B38) G⁴⁰ A1502 CH₃ R^(B40) G⁴⁰ A1503 CH₃ R^(B42) G⁴⁰ A1504 CH₃ R^(B44) G⁴⁰ A1505 CH₃ R^(B46) G⁴⁰ A1506 CH₃ R^(B48) G⁴⁰ A1507 CH₃ R^(B50) G⁴⁰ A1508 CH₃ R^(B52) G⁴⁰ A1509 CH₃ R^(B54) G⁴⁰ A1510 CH₃ R^(B56) G⁴⁰ A1511 CH₃ R^(B58) G⁴⁰ A1512 CH₃ R^(B60) G⁴⁰ A1513 R^(B2) CH₃ G⁴⁰ A1514 R^(B4) CH₃ G⁴⁰ A1515 R^(B6) CH₃ G⁴⁰ A1516 R^(B8) CH₃ G⁴⁰ A1517 R^(B10) CH₃ G⁴⁰ A1518 R^(B12) CH₃ G⁴⁰ A1519 R^(B14) CH₃ G⁴⁰ A1520 R^(B16) CH₃ G⁴⁰ A1521 R^(B18) CH₃ G⁴⁰ A1522 R^(B20) CH₃ G⁴⁰ A1523 R^(B22) CH₃ G⁴⁰ A1524 R^(B24) CH₃ G⁴⁰ A1525 R^(B26) CH₃ G⁴⁰ A1526 R^(B28) CH₃ G⁴⁰ A1527 R^(B30) CH₃ G⁴⁰ A1528 R^(B32) CH₃ G⁴⁰ A1529 R^(B34) CH₃ G⁴⁰ A1530 R^(B36) CH₃ G⁴⁰ A1531 R^(B38) CH₃ G⁴⁰ A1532 R^(B40) CH₃ G⁴⁰ A1533 R^(B42) CH₃ G⁴⁰ A1534 R^(B44) CH₃ G⁴⁰ A1535 R^(B46) CH₃ G⁴⁰ A1536 R^(B48) CH₃ G⁴⁰ A1537 R^(B50) CH₃ G⁴⁰ A1538 R^(B52) CH₃ G⁴⁰ A1539 R^(B54) CH₃ G⁴⁰ A1540 R^(B56) CH₃ G⁴⁰ A1541 R^(B58) CH₃ G⁴⁰ A1542 R^(B60) CH₃ G⁴⁰ A1543 CH₃ R^(B2) G⁴¹ A1544 CH₃ R^(B4) G⁴¹ A1545 CH₃ R^(B6) G⁴¹ A1546 CH₃ R^(B8) G⁴¹ A1547 CH₃ R^(B10) G⁴¹ A1548 CH₃ R^(B12) G⁴¹ A1549 CH₃ R^(B14) G⁴¹ A1550 CH₃ R^(B16) G⁴¹ A1551 CH₃ R^(B18) G⁴¹ A1552 CH₃ R^(B20) G⁴¹ A1553 CH₃ R^(B22) G⁴¹ A1554 CH₃ R^(B24) G⁴¹ A1555 CH₃ R^(B26) G⁴¹ A1556 CH₃ R^(B28) G⁴¹ A1557 CH₃ R^(B30) G⁴¹ A1558 CH₃ R^(B32) G⁴¹ A1559 CH₃ R^(B34) G⁴¹ A1560 CH₃ R^(B36) G⁴¹ A1561 CH₃ R^(B37) G⁴¹ A1562 CH₃ R^(B39) G⁴¹ A1563 CH₃ R^(B41) G⁴¹ A1564 CH₃ R^(B43) G⁴¹ A1565 CH₃ R^(B45) G⁴¹ A1566 CH₃ R^(B47) G⁴¹ A1567 CH₃ R^(B49) G⁴¹ A1568 CH₃ R^(B51) G⁴¹ A1569 CH₃ R^(B53) G⁴¹ A1570 CH₃ R^(B55) G⁴¹ A1571 CH₃ R^(B57) G⁴¹ A1572 CH₃ R^(B59) G⁴¹ A1573 R^(B1) CH₃ G⁴¹ A1574 R^(B3) CH₃ G⁴¹ A1575 R^(B5) CH₃ G⁴¹ A1576 R^(B7) CH₃ G⁴¹ A1577 R^(B9) CH₃ G⁴¹ A1578 R^(B11) CH₃ G⁴¹ A1579 R^(B13) CH₃ G⁴¹ A1580 R^(B15) CH₃ G⁴¹ A1581 R^(B17) CH₃ G⁴¹ A1582 R^(B19) CH₃ G⁴¹ A1583 R^(B21) CH₃ G⁴¹ A1584 R^(B23) CH₃ G⁴¹ A1585 R^(B25) CH₃ G⁴¹ A1586 R^(B27) CH₃ G⁴¹ A1587 R^(B29) CH₃ G⁴¹ A1588 R^(B31) CH₃ G⁴¹ A1589 R^(B33) CH₃ G⁴¹ A1590 R^(B35) CH₃ G⁴¹ A1591 R^(B37) CH₃ G⁴¹ A1592 R^(B39) CH₃ G⁴¹ A1593 R^(B41) CH₃ G⁴¹ A1594 R^(B43) CH₃ G⁴¹ A1595 R^(B45) CH₃ G⁴¹ A1596 R^(B47) CH₃ G⁴¹ A1597 R^(B49) CH₃ G⁴¹ A1598 R^(B51) CH₃ G⁴¹ A1599 R^(B53) CH₃ G⁴¹ A1600 R^(B55) CH₃ G⁴¹ A1601 R^(B57) CH₃ G⁴¹ A1602 R^(B59) CH₃ G⁴¹ A1603 CH₃ R^(B1) G⁴² A1604 CH₃ R^(B3) G⁴² A1605 CH₃ R^(B5) G⁴² A1606 CH₃ R^(B7) G⁴² A1607 CH₃ R^(B9) G⁴² A1608 CH₃ R^(B11) G⁴² A1609 CH₃ R^(B13) G⁴² A1610 CH₃ R^(B15) G⁴² A1611 CH₃ R^(B17) G⁴² A1612 CH₃ R^(B19) G⁴² A1613 CH₃ R^(B21) G⁴² A1614 CH₃ R^(B23) G⁴² A1615 CH₃ R^(B25) G⁴² A1616 CH₃ R^(B27) G⁴² A1617 CH₃ R^(B29) G⁴² A1618 CH₃ R^(B31) G⁴² A1619 CH₃ R^(B33) G⁴² A1620 CH₃ R^(B35) G⁴² A1621 CH₃ R^(B37) G⁴² A1622 CH₃ R^(B39) G⁴² A1623 CH₃ R^(B41) G⁴² A1624 CH₃ R^(B43) G⁴² A1625 CH₃ R^(B45) G⁴² A1626 CH₃ R^(B47) G⁴² A1627 CH₃ R^(B49) G⁴² A1628 CH₃ R^(B51) G⁴² A1629 CH₃ R^(B53) G⁴² A1630 CH₃ R^(B55) G⁴² A1631 CH₃ R^(B57) G⁴² A1632 CH₃ R^(B59) G⁴² A1633 R^(B1) CH₃ G⁴² A1634 R^(B3) CH₃ G⁴² A1635 R^(B5) CH₃ G⁴² A1636 R^(B7) CH₃ G⁴² A1637 R^(B9) CH₃ G⁴² A1638 R^(B11) CH₃ G⁴² A1639 R^(B13) CH₃ G⁴² A1640 R^(B15) CH₃ G⁴² A1641 R^(B17) CH₃ G⁴² A1642 R^(B19) CH₃ G⁴² A1643 R^(B21) CH₃ G⁴² A1644 R^(B23) CH₃ G⁴² A1645 R^(B25) CH₃ G⁴² A1646 R^(B27) CH₃ G⁴² A1647 R^(B29) CH₃ G⁴² A1648 R^(B31) CH₃ G⁴² A1649 R^(B33) CH₃ G⁴² A1650 R^(B35) CH₃ G⁴² A1651 R^(B37) CH₃ G⁴² A1652 R^(B39) CH₃ G⁴² A1653 R^(B41) CH₃ G⁴² A1654 R^(B43) CH₃ G⁴² A1655 R^(B45) CH₃ G⁴² A1656 R^(B47) CH₃ G⁴² A1657 R^(B49) CH₃ G⁴² A1658 R^(B51) CH₃ G⁴² A1659 R^(B53) CH₃ G⁴² A1660 R^(B55) CH₃ G⁴² A1661 R^(B57) CH₃ G⁴² A1662 R^(B59) CH₃ G⁴² A1663 CH₃ R^(B38) G⁴¹ A1664 CH₃ R^(B40) G⁴¹ A1665 CH₃ R^(B42) G⁴¹ A1666 CH₃ R^(B44) G⁴¹ A1667 CH₃ R^(B46) G⁴¹ A1668 CH₃ R^(B48) G⁴¹ A1669 CH₃ R^(B50) G⁴¹ A1670 CH₃ R^(B52) G⁴¹ A1671 CH₃ R^(B54) G⁴¹ A1672 CH₃ R^(B56) G⁴¹ A1673 CH₃ R^(B58) G⁴¹ A1674 CH₃ R^(B60) G⁴¹ A1675 R^(B2) CH₃ G⁴¹ A1676 R^(B4) CH₃ G⁴¹ A1677 R^(B6) CH₃ G⁴¹ A1678 R^(B8) CH₃ G⁴¹ A1679 R^(B10) CH₃ G⁴¹ A1680 R^(B12) CH₃ G⁴¹ A1681 R^(B14) CH₃ G⁴¹ A1682 R^(B16) CH₃ G⁴¹ A1683 R^(B18) CH₃ G⁴¹ A1684 R^(B20) CH₃ G⁴¹ A1685 R^(B22) CH₃ G⁴¹ A1686 R^(B24) CH₃ G⁴¹ A1687 R^(B26) CH₃ G⁴¹ A1688 R^(B28) CH₃ G⁴¹ A1689 R^(B30) CH₃ G⁴¹ A1690 R^(B32) CH₃ G⁴¹ A1691 R^(B34) CH₃ G⁴¹ A1692 R^(B36) CH₃ G⁴¹ A1693 R^(B38) CH₃ G⁴¹ A1694 R^(B40) CH₃ G⁴¹ A1695 R^(B42) CH₃ G⁴¹ A1696 R^(B44) CH₃ G⁴¹ A1697 R^(B46) CH₃ G⁴¹ A1698 R^(B48) CH₃ G⁴¹ A1699 R^(B50) CH₃ G⁴¹ A1700 R^(B52) CH₃ G⁴¹ A1701 R^(B54) CH₃ G⁴¹ A1702 R^(B56) CH₃ G⁴¹ A1703 R^(B58) CH₃ G⁴¹ A1704 R^(B60) CH₃ G⁴¹ A1705 CH₃ R^(B2) G⁴² A1706 CH₃ R^(B4) G⁴² A1707 CH₃ R^(B6) G⁴² A1708 CH₃ R^(B8) G⁴² A1709 CH₃ R^(B10) G⁴² A1710 CH₃ R^(B12) G⁴² A1711 CH₃ R^(B14) G⁴² A1712 CH₃ R^(B16) G⁴² A1713 CH₃ R^(B18) G⁴² A1714 CH₃ R^(B20) G⁴² A1715 CH₃ R^(B22) G⁴² A1716 CH₃ R^(B24) G⁴² A1717 CH₃ R^(B26) G⁴² A1718 CH₃ R^(B28) G⁴² A1719 CH₃ R^(B30) G⁴² A1720 CH₃ R^(B32) G⁴² A1721 CH₃ R^(B34) G⁴² A1722 CH₃ R^(B36) G⁴² A1723 CH₃ R^(B38) G⁴² A1724 CH₃ R^(B40) G⁴² A1725 CH₃ R^(B42) G⁴² A1726 CH₃ R^(B44) G⁴² A1727 CH₃ R^(B46) G⁴² A1728 CH₃ R^(B48) G⁴² A1729 CH₃ R^(B50) G⁴² A1730 CH₃ R^(B52) G⁴² A1731 CH₃ R^(B54) G⁴² A1732 CH₃ R^(B56) G⁴² A1733 CH₃ R^(B58) G⁴² A1734 CH₃ R^(B60) G⁴² A1735 R^(B2) CH₃ G⁴² A1736 R^(B4) CH₃ G⁴² A1737 R^(B6) CH₃ G⁴² A1738 R^(B8) CH₃ G⁴² A1739 R^(B10) CH₃ G⁴² A1740 R^(B12) CH₃ G⁴² A1741 R^(B14) CH₃ G⁴² A1742 R^(B16) CH₃ G⁴² A1743 R^(B18) CH₃ G⁴² A1744 R^(B20) CH₃ G⁴² A1745 R^(B22) CH₃ G⁴² A1746 R^(B24) CH₃ G⁴² A1747 R^(B26) CH₃ G⁴² A1748 R^(B28) CH₃ G⁴² A1749 R^(B30) CH₃ G⁴² A1750 R^(B32) CH₃ G⁴² A1751 R^(B34) CH₃ G⁴² A1752 R^(B36) CH₃ G⁴² A1753 R^(B38) CH₃ G⁴² A1754 R^(B40) CH₃ G⁴² A1755 R^(B42) CH₃ G⁴² A1756 R^(B44) CH₃ G⁴² A1757 R^(B46) CH₃ G⁴² A1758 R^(B48) CH₃ G⁴² A1759 R^(B50) CH₃ G⁴² A1760 R^(B52) CH₃ G⁴² A1761 R^(B54) CH₃ G⁴² A1762 R^(B56) CH₃ G⁴² A1763 R^(B58) CH₃ G⁴² A1764 R^(B60) CH₃ G⁴², where R^(B1) to R^(B60) have the following structures:

wherein G¹ to G⁴⁸ have the following structures:

and where the Arabic Numerals indicate the points of attachment to the corresponding points of attachment in ligand L_(A).

In some embodiments, the compound has a formula of M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), where L_(B) and L_(C) are each a bidentate ligand; and x is 1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2; and x+y+z is the oxidation state of the metal M. In some embodiments where the compound has a formula of M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), the compound is selected from the group of formulas consisting of Ir(L_(A))₃, Ir(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)), Ir(L_(A))₂(L_(C)), and Ir(L_(A))(L_(B))(L_(C)), where L_(A), L_(B), and L_(C) are different from each other. In some embodiments, the compound has a formula of Pt(L_(A))(L_(B)), and L_(A) and L_(B) can be same or different. In some embodiments, L_(A) and L_(B) are connected to form a tetradentate ligand. In some embodiments, L_(A) and L_(B) are connected at two places to form a macrocyclic tetradentate ligand. In some embodiments, L_(B) and L_(C) are each independently selected from the group consisting of:

where each Y¹ to Y¹³ are independently selected from the group consisting of carbon and nitrogen; Y′ is selected from the group consisting of BR_(e), NR_(e), PR_(e), O, S, Se, C═O, S═O, SO₂, CR_(e)R_(f), SiR_(e)R_(f), and GeR_(e)R_(f); R_(e) and R_(f) are optionally fused or joined to form a ring; each R_(e) and R_(f) is independently selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; each R_(a), R_(b), R_(e), and R_(d) may independently represent from mono substitution to the maximum possible number of substitutions, or no substitution; each R_(a), R_(b), R_(e), and R_(d) is independently hydrogen or a substituent selected from the group consisting of the general substituents defined herein; and any two adjacent substituents of R_(a), R_(b), R_(e), and R_(d) can be optionally fused or joined to form a ring or form a multidentate ligand.

In some embodiments, the compound has a formula of M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z), where L_(B) and L_(C) are each a bidentate ligand; and x is 1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2; and x+y+z is the oxidation state of the metal M, L_(B) and L_(C) are each independently selected from the group consisting of:

In some embodiments of the compound where the first ligand L_(A) is selected from the group consisting of ligands L_(A1-O) to L_(A384-O), L_(A1-S) to L_(A384-S), L_(A1-C) to L_(A384-C), L_(A385-O) to L_(A420-O), L_(A385-S) to L_(A420-S), and L_(A385-C) to L_(A420-C), L_(A421-O) to L_(A1152-O), L_(A421-S) to L_(A1152-S), L_(A421-C) to L_(A1152-C), L_(A1153-O) to L_(A1764-O), L_(A1153-S) to L_(A1764-S), L_(A1153-C) to L_(A1763-C), and L_(A1764-C) as defined above, the compound is Compound Ai-F having the formula Ir(L_(Ai-F))₃, the Compound By-F having the formula Ir(L_(Ai-F))(L_(Bk))₂, or the Compound Cz-F having the formula Ir(L_(Ai-F))₂(L_(Cj));

where i is an integer from 1 to 1764, and k is an integer from 1 to 490, and j is an integer from 1 to 1260, y=490i+k−4908, z=1764i+j−1764, and F is O, S, or C;

where L_(Bk) is selected from the group consisting of the following structures:

where L_(C1) through L_(C1260) are based on a structure of Formula X

in which R¹, R², and R³ are defined as:

Ligand R¹ R² R³ L_(C1) R^(D1) R^(D1) H L_(C2) R^(D2) R^(D2) H L_(C3) R^(D3) R^(D3) H L_(C4) R^(D4) R^(D4) H L_(C5) R^(D5) R^(D5) H L_(C6) R^(D6) R^(D6) H L_(C7) R^(D7) R^(D7) H L_(C8) R^(D8) R^(D8) H L_(C9) R^(D9) R^(D9) H L_(C10) R^(D10) R^(D10) H L_(C11) R^(D11) R^(D11) H L_(C12) R^(D12) R^(D12) H L_(C13) R^(D13) R^(D13) H L_(C14) R^(D14) R^(D14) H L_(C15) R^(D15) R^(D15) H L_(C16) R^(D16) R^(D16) H L_(C17) R^(D17) R^(D17) H L_(C18) R^(D18) R^(D18) H L_(C19) R^(D19) R^(D19) H L_(C20) R^(D20) R^(D20) H L_(C21) R^(D21) R^(D21) H L_(C22) R^(D22) R^(D22) H L_(C23) R^(D23) R^(D23) H L_(C24) R^(D24) R^(D24) H L_(C25) R^(D25) R^(D25) H L_(C26) R^(D26) R^(D26) H L_(C27) R^(D27) R^(D27) H L_(C28) R^(D28) R^(D28) H L_(C29) R^(D29) R^(D29) H L_(C30) R^(D30) R^(D30) H L_(C31) R^(D31) R^(D31) H L_(C32) R^(D32) R^(D32) H L_(C33) R^(D33) R^(D33) H L_(C34) R^(D34) R^(D34) H L_(C35) R^(D35) R^(D35) H L_(C36) R^(D40) R^(D40) H L_(C37) R^(D41) R^(D41) H L_(C38) R^(D42) R^(D42) H L_(C39) R^(D64) R^(D64) H L_(C40) R^(D66) R^(D66) H L_(C41) R^(D68) R^(D68) H L_(C42) R^(D76) R^(D76) H L_(C43) R^(D1) R^(D2) H L_(C44) R^(D1) R^(D3) H L_(C45) R^(D1) R^(D4) H L_(C46) R^(D1) R^(D5) H L_(C47) R^(D1) R^(D6) H L_(C48) R^(D1) R^(D7) H L_(C49) R^(D1) R^(D8) H L_(C50) R^(D1) R^(D9) H L_(C51) R^(D1) R^(D10) H L_(C52) R^(D1) R^(D11) H L_(C53) R^(D1) R^(D12) H L_(C54) R^(D1) R^(D13) H L_(C55) R^(D1) R^(D14) H L_(C56) R^(D1) R^(D15) H L_(C57) R^(D1) R^(D16) H L_(C58) R^(D1) R^(D17) H L_(C59) R^(D1) R^(D18) H L_(C60) R^(D1) R^(D19) H L_(C61) R^(D1) R^(D20) H L_(C62) R^(D1) R^(D21) H L_(C63) R^(D1) R^(D22) H L_(C64) R^(D1) R^(D23) H L_(C65) R^(D1) R^(D24) H L_(C66) R^(D1) R^(D25) H L_(C67) R^(D1) R^(D26) H L_(C68) R^(D1) R^(D27) H L_(C69) R^(D1) R^(D28) H L_(C70) R^(D1) R^(D29) H L_(C71) R^(D1) R^(D30) H L_(C72) R^(D1) R^(D31) H L_(C73) R^(D1) R^(D32) H L_(C74) R^(D1) R^(D33) H L_(C75) R^(D1) R^(D34) H L_(C76) R^(D1) R^(D35) H L_(C77) R^(D1) R^(D40) H L_(C78) R^(D1) R^(D41) H L_(C79) R^(D1) R^(D42) H L_(C80) R^(D1) R^(D64) H L_(C81) R^(D1) R^(D66) H L_(C82) R^(D1) R^(D68) H L_(C83) R^(D1) R^(D76) H L_(C84) R^(D2) R^(D1) H L_(C85) R^(D2) R^(D3) H L_(C86) R^(D2) R^(D4) H L_(C87) R^(D2) R^(D5) H L_(C88) R^(D2) R^(D6) H L_(C89) R^(D2) R^(D7) H L_(C90) R^(D2) R^(D8) H L_(C91) R^(D2) R^(D9) H L_(C92) R^(D2) R^(D10) H L_(C93) R^(D2) R^(D11) H L_(C94) R^(D2) R^(D12) H L_(C95) R^(D2) R^(D13) H L_(C96) R^(D2) R^(D14) H L_(C97) R^(D2) R^(D15) H L_(C98) R^(D2) R^(D16) H L_(C99) R^(D2) R^(D17) H L_(C100) R^(D2) R^(D18) H L_(C101) R^(D2) R^(D19) H L_(C102) R^(D2) R^(D20) H L_(C103) R^(D2) R^(D21) H L_(C104) R^(D2) R^(D22) H L_(C105) R^(D2) R^(D23) H L_(C106) R^(D2) R^(D24) H L_(C107) R^(D2) R^(D25) H L_(C108) R^(D2) R^(D26) H L_(C109) R^(D2) R^(D27) H L_(C110) R^(D2) R^(D28) H L_(C111) R^(D2) R^(D29) H L_(C112) R^(D2) R^(D30) H L_(C113) R^(D2) R^(D31) H L_(C114) R^(D2) R^(D32) H L_(C115) R^(D2) R^(D33) H L_(C116) R^(D2) R^(D34) H L_(C117) R^(D2) R^(D35) H L_(C118) R^(D2) R^(D40) H L_(C119) R^(D2) R^(D41) H L_(C120) R^(D2) R^(D42) H L_(C121) R^(D2) R^(D64) H L_(C122) R^(D2) R^(D66) H L_(C123) R^(D2) R^(D68) H L_(C124) R^(D2) R^(D76) H L_(C125) R^(D3) R^(D4) H L_(C126) R^(D3) R^(D5) H L_(C127) R^(D3) R^(D6) H L_(C128) R^(D3) R^(D7) H L_(C129) R^(D3) R^(D8) H L_(C130) R^(D3) R^(D9) H L_(C131) R^(D3) R^(D10) H L_(C132) R^(D3) R^(D11) H L_(C133) R^(D3) R^(D12) H L_(C134) R^(D3) R^(D13) H L_(C135) R^(D3) R^(D14) H L_(C136) R^(D3) R^(D15) H L_(C137) R^(D3) R^(D16) H L_(C138) R^(D3) R^(D17) H L_(C139) R^(D3) R^(D18) H L_(C140) R^(D3) R^(D19) H L_(C141) R^(D3) R^(D20) H L_(C142) R^(D3) R^(D21) H L_(C143) R^(D3) R^(D22) H L_(C144) R^(D3) R^(D23) H L_(C145) R^(D3) R^(D24) H L_(C146) R^(D3) R^(D25) H L_(C147) R^(D3) R^(D26) H L_(C148) R^(D3) R^(D27) H L_(C149) R^(D3) R^(D28) H L_(C150) R^(D3) R^(D29) H L_(C151) R^(D3) R^(D30) H L_(C152) R^(D3) R^(D31) H L_(C153) R^(D3) R^(D32) H L_(C154) R^(D3) R^(D33) H L_(C155) R^(D3) R^(D34) H L_(C156) R^(D3) R^(D35) H L_(C157) R^(D3) R^(D40) H L_(C158) R^(D3) R^(D41) H L_(C159) R^(D3) R^(D42) H L_(C160) R^(D3) R^(D64) H L_(C161) R^(D3) R^(D66) H L_(C162) R^(D3) R^(D68) H L_(C163) R^(D3) R^(D76) H L_(C164) R^(D4) R^(D5) H L_(C165) R^(D4) R^(D6) H L_(C166) R^(D4) R^(D7) H L_(C167) R^(D4) R^(D8) H L_(C168) R^(D4) R^(D9) H L_(C169) R^(D4) R^(D10) H L_(C170) R^(D4) R^(D11) H L_(C171) R^(D4) R^(D12) H L_(C172) R^(D4) R^(D13) H L_(C173) R^(D4) R^(D14) H L_(C174) R^(D4) R^(D15) H L_(C175) R^(D4) R^(D16) H L_(C176) R^(D4) R^(D17) H L_(C177) R^(D4) R^(D18) H L_(C178) R^(D4) R^(D19) H L_(C179) R^(D4) R^(D20) H L_(C180) R^(D4) R^(D21) H L_(C181) R^(D4) R^(D22) H L_(C182) R^(D4) R^(D23) H L_(C183) R^(D4) R^(D24) H L_(C184) R^(D4) R^(D25) H L_(C185) R^(D4) R^(D26) H L_(C186) R^(D4) R^(D27) H L_(C187) R^(D4) R^(D28) H L_(C188) R^(D4) R^(D29) H L_(C189) R^(D4) R^(D30) H L_(C190) R^(D4) R^(D31) H L_(C191) R^(D4) R^(D32) H L_(C192) R^(D4) R^(D33) H L_(C193) R^(D4) R^(D34) H L_(C194) R^(D4) R^(D35) H L_(C195) R^(D4) R^(D40) H L_(C196) R^(D4) R^(D41) H L_(C197) R^(D4) R^(D42) H L_(C198) R^(D4) R^(D64) H L_(C199) R^(D4) R^(D66) H L_(C200) R^(D4) R^(D68) H L_(C201) R^(D4) R^(D76) H L_(C202) R^(D4) R^(D1) H L_(C203) R^(D7) R^(D5) H L_(C204) R^(D7) R^(D6) H L_(C205) R^(D7) R^(D8) H L_(C206) R^(D7) R^(D9) H L_(C207) R^(D7) R^(D10) H L_(C208) R^(D7) R^(D11) H L_(C209) R^(D7) R^(D12) H L_(C210) R^(D7) R^(D13) H L_(C211) R^(D7) R^(D14) H L_(C212) R^(D7) R^(D15) H L_(C213) R^(D7) R^(D16) H L_(C214) R^(D7) R^(D17) H L_(C215) R^(D7) R^(D18) H L_(C216) R^(D7) R^(D19) H L_(C217) R^(D7) R^(D20) H L_(C218) R^(D7) R^(D21) H L_(C219) R^(D7) R^(D22) H L_(C220) R^(D7) R^(D23) H L_(C221) R^(D7) R^(D24) H L_(C222) R^(D7) R^(D25) H L_(C223) R^(D7) R^(D26) H L_(C224) R^(D7) R^(D27) H L_(C225) R^(D7) R^(D28) H L_(C226) R^(D7) R^(D29) H L_(C227) R^(D7) R^(D30) H L_(C228) R^(D7) R^(D31) H L_(C229) R^(D7) R^(D32) H L_(C230) R^(D7) R^(D33) H L_(C231) R^(D7) R^(D34) H L_(C232) R^(D7) R^(D35) H L_(C233) R^(D7) R^(D40) H L_(C234) R^(D7) R^(D41) H L_(C235) R^(D7) R^(D42) H L_(C236) R^(D7) R^(D64) H L_(C237) R^(D7) R^(D66) H L_(C238) R^(D7) R^(D68) H L_(C239) R^(D7) R^(D76) H L_(C240) R^(D8) R^(D5) H L_(C241) R^(D8) R^(D6) H L_(C242) R^(D8) R^(D9) H L_(C243) R^(D8) R^(D10) H L_(C244) R^(D8) R^(D11) H L_(C245) R^(D8) R^(D12) H L_(C246) R^(D8) R^(D13) H L_(C247) R^(D8) R^(D14) H L_(C248) R^(D8) R^(D15) H L_(C249) R^(D8) R^(D16) H L_(C250) R^(D8) R^(D17) H L_(C251) R^(D8) R^(D18) H L_(C252) R^(D8) R^(D19) H L_(C253) R^(D8) R^(D20) H L_(C254) R^(D8) R^(D21) H L_(C255) R^(D8) R^(D22) H L_(C256) R^(D8) R^(D23) H L_(C257) R^(D8) R^(D24) H L_(C258) R^(D8) R^(D25) H L_(C259) R^(D8) R^(D26) H L_(C260) R^(D8) R^(D27) H L_(C261) R^(D8) R^(D28) H L_(C262) R^(D8) R^(D29) H L_(C263) R^(D8) R^(D30) H L_(C264) R^(D8) R^(D31) H L_(C265) R^(D8) R^(D32) H L_(C266) R^(D8) R^(D33) H L_(C267) R^(D8) R^(D34) H L_(C268) R^(D8) R^(D35) H L_(C269) R^(D8) R^(D40) H L_(C270) R^(D8) R^(D41) H L_(C271) R^(D8) R^(D42) H L_(C272) R^(D8) R^(D64) H L_(C273) R^(D8) R^(D66) H L_(C274) R^(D8) R^(D68) H L_(C275) R^(D8) R^(D76) H L_(C276) R^(D11) R^(D5) H L_(C277) R^(D11) R^(D6) H L_(C278) R^(D11) R^(D9) H L_(C279) R^(D11) R^(D10) H L_(C280) R^(D11) R^(D12) H L_(C281) R^(D11) R^(D13) H L_(C282) R^(D11) R^(D14) H L_(C283) R^(D11) R^(D15) H L_(C284) R^(D11) R^(D16) H L_(C285) R^(D11) R^(D17) H L_(C286) R^(D11) R^(D18) H L_(C287) R^(D11) R^(D19) H L_(C288) R^(D11) R^(D20) H L_(C289) R^(D11) R^(D21) H L_(C290) R^(D11) R^(D22) H L_(C291) R^(D11) R^(D23) H L_(C292) R^(D11) R^(D24) H L_(C293) R^(D11) R^(D25) H L_(C294) R^(D11) R^(D26) H L_(C295) R^(D11) R^(D27) H L_(C296) R^(D11) R^(D28) H L_(C297) R^(D11) R^(D29) H L_(C298) R^(D11) R^(D30) H L_(C299) R^(D11) R^(D31) H L_(C300) R^(D11) R^(D32) H L_(C301) R^(D11) R^(D33) H L_(C302) R^(D11) R^(D34) H L_(C303) R^(D11) R^(D35) H L_(C304) R^(D11) R^(D40) H L_(C305) R^(D11) R^(D41) H L_(C306) R^(D11) R^(D42) H L_(C307) R^(D11) R^(D64) H L_(C308) R^(D11) R^(D66) H L_(C309) R^(D11) R^(D68) H L_(C310) R^(D11) R^(D76) H L_(C311) R^(D13) R^(D5) H L_(C312) R^(D13) R^(D6) H L_(C313) R^(D13) R^(D9) H L_(C314) R^(D13) R^(D10) H L_(C315) R^(D13) R^(D12) H L_(C316) R^(D13) R^(D14) H L_(C317) R^(D13) R^(D15) H L_(C318) R^(D13) R^(D16) H L_(C319) R^(D13) R^(D17) H L_(C320) R^(D13) R^(D18) H L_(C321) R^(D13) R^(D19) H L_(C322) R^(D13) R^(D20) H L_(C323) R^(D13) R^(D21) H L_(C324) R^(D13) R^(D22) H L_(C325) R^(D13) R^(D23) H L_(C326) R^(D13) R^(D24) H L_(C327) R^(D13) R^(D25) H L_(C328) R^(D13) R^(D26) H L_(C329) R^(D13) R^(D27) H L_(C330) R^(D13) R^(D28) H L_(C331) R^(D13) R^(D29) H L_(C332) R^(D13) R^(D30) H L_(C333) R^(D13) R^(D31) H L_(C334) R^(D13) R^(D32) H L_(C335) R^(D13) R^(D33) H L_(C336) R^(D13) R^(D34) H L_(C337) R^(D13) R^(D35) H L_(C338) R^(D13) R^(D40) H L_(C339) R^(D13) R^(D41) H L_(C340) R^(D13) R^(D42) H L_(C341) R^(D13) R^(D64) H L_(C342) R^(D13) R^(D66) H L_(C343) R^(D13) R^(D68) H L_(C344) R^(D13) R^(D76) H L_(C345) R^(D14) R^(D5) H L_(C346) R^(D14) R^(D6) H L_(C347) R^(D14) R^(D9) H L_(C348) R^(D14) R^(D10) H L_(C349) R^(D14) R^(D12) H L_(C350) R^(D14) R^(D15) H L_(C351) R^(D14) R^(D16) H L_(C352) R^(D14) R^(D17) H L_(C353) R^(D14) R^(D18) H L_(C354) R^(D14) R^(D19) H L_(C355) R^(D14) R^(D20) H L_(C356) R^(D14) R^(D21) H L_(C357) R^(D14) R^(D22) H L_(C358) R^(D14) R^(D23) H L_(C359) R^(D14) R^(D24) H L_(C360) R^(D14) R^(D25) H L_(C361) R^(D14) R^(D26) H L_(C362) R^(D14) R^(D27) H L_(C363) R^(D14) R^(D28) H L_(C364) R^(D14) R^(D29) H L_(C365) R^(D14) R^(D30) H L_(C366) R^(D14) R^(D31) H L_(C367) R^(D14) R^(D32) H L_(C368) R^(D14) R^(D33) H L_(C369) R^(D14) R^(D34) H L_(C370) R^(D14) R^(D35) H L_(C371) R^(D14) R^(D40) H L_(C372) R^(D14) R^(D41) H L_(C373) R^(D14) R^(D42) H L_(C374) R^(D14) R^(D64) H L_(C375) R^(D14) R^(D66) H L_(C376) R^(D14) R^(D68) H L_(C377) R^(D14) R^(D76) H L_(C378) R^(D22) R^(D5) H L_(C379) R^(D22) R^(D6) H L_(C380) R^(D22) R^(D9) H L_(C381) R^(D22) R^(D10) H L_(C382) R^(D22) R^(D12) H L_(C383) R^(D22) R^(D15) H L_(C384) R^(D22) R^(D16) H L_(C385) R^(D22) R^(D17) H L_(C386) R^(D22) R^(D18) H L_(C387) R^(D22) R^(D19) H L_(C388) R^(D22) R^(D20) H L_(C389) R^(D22) R^(D21) H L_(C390) R^(D22) R^(D23) H L_(C391) R^(D22) R^(D24) H L_(C392) R^(D22) R^(D25) H L_(C393) R^(D22) R^(D26) H L_(C394) R^(D22) R^(D27) H L_(C395) R^(D22) R^(D28) H L_(C396) R^(D22) R^(D29) H L_(C397) R^(D22) R^(D30) H L_(C398) R^(D22) R^(D31) H L_(C399) R^(D22) R^(D32) H L_(C400) R^(D22) R^(D33) H L_(C401) R^(D22) R^(D34) H L_(C402) R^(D22) R^(D35) H L_(C403) R^(D22) R^(D40) H L_(C404) R^(D22) R^(D41) H L_(C405) R^(D22) R^(D42) H L_(C406) R^(D22) R^(D64) H L_(C407) R^(D22) R^(D66) H L_(C408) R^(D22) R^(D68) H L_(C409) R^(D22) R^(D76) H L_(C410) R^(D26) R^(D5) H L_(C411) R^(D26) R^(D6) H L_(C412) R^(D26) R^(D9) H L_(C413) R^(D26) R^(D10) H L_(C414) R^(D26) R^(D12) H L_(C415) R^(D26) R^(D15) H L_(C416) R^(D26) R^(D16) H L_(C417) R^(D26) R^(D17) H L_(C418) R^(D26) R^(D18) H L_(C419) R^(D26) R^(D19) H L_(C420) R^(D26) R^(D20) H L_(C421) R^(D26) R^(D21) H L_(C422) R^(D26) R^(D23) H L_(C423) R^(D26) R^(D24) H L_(C424) R^(D26) R^(D25) H L_(C425) R^(D26) R^(D27) H L_(C426) R^(D26) R^(D28) H L_(C427) R^(D26) R^(D29) H L_(C428) R^(D26) R^(D30) H L_(C429) R^(D26) R^(D31) H L_(C430) R^(D26) R^(D32) H L_(C431) R^(D26) R^(D33) H L_(C432) R^(D26) R^(D34) H L_(C433) R^(D26) R^(D35) H L_(C434) R^(D26) R^(D40) H L_(C435) R^(D26) R^(D41) H L_(C436) R^(D26) R^(D42) H L_(C437) R^(D26) R^(D64) H L_(C438) R^(D26) R^(D66) H L_(C439) R^(D26) R^(D68) H L_(C440) R^(D26) R^(D76) H L_(C441) R^(D35) R^(D5) H L_(C442) R^(D35) R^(D6) H L_(C443) R^(D35) R^(D9) H L_(C444) R^(D35) R^(D10) H L_(C445) R^(D35) R^(D12) H L_(C446) R^(D35) R^(D15) H L_(C447) R^(D35) R^(D16) H L_(C448) R^(D35) R^(D17) H L_(C449) R^(D35) R^(D18) H L_(C450) R^(D35) R^(D19) H L_(C451) R^(D35) R^(D20) H L_(C452) R^(D35) R^(D21) H L_(C453) R^(D35) R^(D23) H L_(C454) R^(D35) R^(D24) H L_(C455) R^(D35) R^(D25) H L_(C456) R^(D35) R^(D27) H L_(C457) R^(D35) R^(D28) H L_(C458) R^(D35) R^(D29) H L_(C459) R^(D35) R^(D30) H L_(C460) R^(D35) R^(D31) H L_(C461) R^(D35) R^(D32) H L_(C462) R^(D35) R^(D33) H L_(C463) R^(D35) R^(D34) H L_(C464) R^(D35) R^(D40) H L_(C465) R^(D35) R^(D41) H L_(C466) R^(D35) R^(D42) H L_(C467) R^(D35) R^(D64) H L_(C468) R^(D35) R^(D66) H L_(C469) R^(D35) R^(D68) H L_(C470) R^(D35) R^(D76) H L_(C471) R^(D40) R^(D5) H L_(C472) R^(D40) R^(D6) H L_(C473) R^(D40) R^(D9) H L_(C474) R^(D40) R^(D10) H L_(C475) R^(D40) R^(D12) H L_(C476) R^(D40) R^(D15) H L_(C477) R^(D40) R^(D16) H L_(C478) R^(D40) R^(D17) H L_(C479) R^(D40) R^(D18) H L_(C480) R^(D40) R^(D19) H L_(C481) R^(D40) R^(D20) H L_(C482) R^(D40) R^(D21) H L_(C483) R^(D40) R^(D23) H L_(C484) R^(D40) R^(D24) H L_(C485) R^(D40) R^(D25) H L_(C486) R^(D40) R^(D27) H L_(C487) R^(D40) R^(D28) H L_(C488) R^(D40) R^(D29) H L_(C489) R^(D40) R^(D30) H L_(C490) R^(D40) R^(D31) H L_(C491) R^(D40) R^(D32) H L_(C492) R^(D40) R^(D33) H L_(C493) R^(D40) R^(D34) H L_(C494) R^(D40) R^(D41) H L_(C495) R^(D40) R^(D42) H L_(C496) R^(D40) R^(D64) H L_(C497) R^(D40) R^(D66) H L_(C498) R^(D40) R^(D68) H L_(C499) R^(D40) R^(D76) H L_(C500) R^(D41) R^(D5) H L_(C501) R^(D41) R^(D6) H L_(C502) R^(D41) R^(D9) H L_(C503) R^(D41) R^(D10) H L_(C504) R^(D41) R^(D12) H L_(C505) R^(D41) R^(D15) H L_(C506) R^(D41) R^(D16) H L_(C507) R^(D41) R^(D17) H L_(C508) R^(D41) R^(D18) H L_(C509) R^(D41) R^(D19) H L_(C510) R^(D41) R^(D20) H L_(C511) R^(D41) R^(D21) H L_(C512) R^(D41) R^(D23) H L_(C513) R^(D41) R^(D24) H L_(C514) R^(D41) R^(D25) H L_(C515) R^(D41) R^(D27) H L_(C516) R^(D41) R^(D28) H L_(C517) R^(D41) R^(D29) H L_(C518) R^(D41) R^(D30) H L_(C519) R^(D41) R^(D31) H L_(C520) R^(D41) R^(D32) H L_(C521) R^(D41) R^(D33) H L_(C522) R^(D41) R^(D34) H L_(C523) R^(D41) R^(D42) H L_(C524) R^(D41) R^(D64) H L_(C525) R^(D41) R^(D66) H L_(C526) R^(D41) R^(D68) H L_(C527) R^(D41) R^(D76) H L_(C528) R^(D64) R^(D5) H L_(C529) R^(D64) R^(D6) H L_(C530) R^(D64) R^(D9) H L_(C531) R^(D64) R^(D10) H L_(C532) R^(D64) R^(D12) H L_(C533) R^(D64) R^(D15) H L_(C534) R^(D64) R^(D16) H L_(C535) R^(D64) R^(D17) H L_(C536) R^(D64) R^(D18) H L_(C537) R^(D64) R^(D19) H L_(C538) R^(D64) R^(D20) H L_(C539) R^(D64) R^(D21) H L_(C540) R^(D64) R^(D23) H L_(C541) R^(D64) R^(D24) H L_(C542) R^(D64) R^(D25) H L_(C543) R^(D64) R^(D27) H L_(C544) R^(D64) R^(D28) H L_(C545) R^(D64) R^(D29) H L_(C546) R^(D64) R^(D30) H L_(C547) R^(D64) R^(D31) H L_(C548) R^(D64) R^(D32) H L_(C549) R^(D64) R^(D33) H L_(C550) R^(D64) R^(D34) H L_(C551) R^(D64) R^(D42) H L_(C552) R^(D64) R^(D64) H L_(C553) R^(D64) R^(D66) H L_(C554) R^(D64) R^(D68) H L_(C555) R^(D64) R^(D76) H L_(C556) R^(D66) R^(D5) H L_(C557) R^(D66) R^(D6) H L_(C558) R^(D66) R^(D9) H L_(C559) R^(D66) R^(D10) H L_(C560) R^(D66) R^(D12) H L_(C561) R^(D66) R^(D15) H L_(C562) R^(D66) R^(D16) H L_(C563) R^(D66) R^(D17) H L_(C564) R^(D66) R^(D18) H L_(C565) R^(D66) R^(D19) H L_(C566) R^(D66) R^(D20) H L_(C567) R^(D66) R^(D21) H L_(C568) R^(D66) R^(D23) H L_(C569) R^(D66) R^(D24) H L_(C570) R^(D66) R^(D25) H L_(C571) R^(D66) R^(D27) H L_(C572) R^(D66) R^(D28) H L_(C573) R^(D66) R^(D29) H L_(C574) R^(D66) R^(D30) H L_(C575) R^(D66) R^(D31) H L_(C576) R^(D66) R^(D32) H L_(C577) R^(D66) R^(D33) H L_(C578) R^(D66) R^(D34) H L_(C579) R^(D66) R^(D42) H L_(C580) R^(D66) R^(D68) H L_(C581) R^(D66) R^(D76) H L_(C582) R^(D68) R^(D5) H L_(C583) R^(D68) R^(D6) H L_(C584) R^(D68) R^(D9) H L_(C585) R^(D68) R^(D10) H L_(C586) R^(D68) R^(D12) H L_(C587) R^(D68) R^(D15) H L_(C588) R^(D68) R^(D16) H L_(C589) R^(D68) R^(D17) H L_(C590) R^(D68) R^(D18) H L_(C591) R^(D68) R^(D19) H L_(C592) R^(D68) R^(D20) H L_(C593) R^(D68) R^(D21) H L_(C594) R^(D68) R^(D23) H L_(C595) R^(D68) R^(D24) H L_(C596) R^(D68) R^(D25) H L_(C597) R^(D68) R^(D27) H L_(C598) R^(D68) R^(D28) H L_(C599) R^(D68) R^(D29) H L_(C600) R^(D68) R^(D30) H L_(C601) R^(D68) R^(D31) H L_(C602) R^(D68) R^(D32) H L_(C603) R^(D68) R^(D33) H L_(C604) R^(D68) R^(D34) H L_(C605) R^(D68) R^(D42) H L_(C606) R^(D68) R^(D76) H L_(C607) R^(D76) R^(D5) H L_(C608) R^(D76) R^(D6) H L_(C609) R^(D76) R^(D9) H L_(C610) R^(D76) R^(D10) H L_(C611) R^(D76) R^(D12) H L_(C612) R^(D76) R^(D15) H L_(C613) R^(D76) R^(D16) H L_(C614) R^(D76) R^(D17) H L_(C615) R^(D76) R^(D18) H L_(C616) R^(D76) R^(D19) H L_(C617) R^(D76) R^(D20) H L_(C618) R^(D76) R^(D21) H L_(C619) R^(D76) R^(D23) H L_(C620) R^(D76) R^(D24) H L_(C621) R^(D76) R^(D25) H L_(C622) R^(D76) R^(D27) H L_(C623) R^(D76) R^(D28) H L_(C624) R^(D76) R^(D29) H L_(C625) R^(D76) R^(D30) H L_(C626) R^(D76) R^(D31) H L_(C627) R^(D76) R^(D32) H L_(C628) R^(D76) R^(D33) H L_(C629) R^(D76) R^(D34) H L_(C630) R^(D76) R^(D42) H L_(C631) R^(D1) R^(D1) R^(D1) L_(C632) R^(D2) R^(D2) R^(D1) L_(C633) R^(D3) R^(D3) R^(D1) L_(C634) R^(D4) R^(D4) R^(D1) L_(C635) R^(D5) R^(D5) R^(D1) L_(C636) R^(D6) R^(D6) R^(D1) L_(C637) R^(D7) R^(D7) R^(D1) L_(C638) R^(D8) R^(D8) R^(D1) L_(C639) R^(D9) R^(D9) R^(D1) L_(C640) R^(D10) R^(D10) R^(D1) L_(C641) R^(D11) R^(D11) R^(D1) L_(C642) R^(D12) R^(D12) R^(D1) L_(C643) R^(D13) R^(D13) R^(D1) L_(C644) R^(D14) R^(D14) R^(D1) L_(C645) R^(D15) R^(D15) R^(D1) L_(C646) R^(D16) R^(D16) R^(D1) L_(C647) R^(D17) R^(D17) R^(D1) L_(C648) R^(D18) R^(D18) R^(D1) L_(C649) R^(D19) R^(D19) R^(D1) L_(C650) R^(D20) R^(D20) R^(D1) L_(C651) R^(D21) R^(D21) R^(D1) L_(C652) R^(D22) R^(D22) R^(D1) L_(C653) R^(D23) R^(D23) R^(D1) L_(C654) R^(D24) R^(D24) R^(D1) L_(C655) R^(D25) R^(D25) R^(D1) L_(C656) R^(D26) R^(D26) R^(D1) L_(C657) R^(D27) R^(D27) R^(D1) L_(C658) R^(D28) R^(D28) R^(D1) L_(C659) R^(D29) R^(D29) R^(D1) L_(C660) R^(D30) R^(D30) R^(D1) L_(C661) R^(D31) R^(D31) R^(D1) L_(C662) R^(D32) R^(D32) R^(D1) L_(C663) R^(D33) R^(D33) R^(D1) L_(C664) R^(D34) R^(D34) R^(D1) L_(C665) R^(D35) R^(D35) R^(D1) L_(C666) R^(D40) R^(D40) R^(D1) L_(C667) R^(D41) R^(D41) R^(D1) L_(C668) R^(D42) R^(D42) R^(D1) L_(C669) R^(D64) R^(D64) R^(D1) L_(C670) R^(D66) R^(D66) R^(D1) L_(C671) R^(D68) R^(D68) R^(D1) L_(C672) R^(D76) R^(D76) R^(D1) L_(C673) R^(D1) R^(D2) R^(D1) L_(C674) R^(D1) R^(D3) R^(D1) L_(C675) R^(D1) R^(D4) R^(D1) L_(C676) R^(D1) R^(D5) R^(D1) L_(C677) R^(D1) R^(D6) R^(D1) L_(C678) R^(D1) R^(D7) R^(D1) L_(C679) R^(D1) R^(D8) R^(D1) L_(C680) R^(D1) R^(D9) R^(D1) L_(C681) R^(D1) R^(D10) R^(D1) L_(C682) R^(D1) R^(D11) R^(D1) L_(C683) R^(D1) R^(D12) R^(D1) L_(C684) R^(D1) R^(D13) R^(D1) L_(C685) R^(D1) R^(D14) R^(D1) L_(C686) R^(D1) R^(D15) R^(D1) L_(C687) R^(D1) R^(D16) R^(D1) L_(C688) R^(D1) R^(D17) R^(D1) L_(C689) R^(D1) R^(D18) R^(D1) L_(C690) R^(D1) R^(D19) R^(D1) L_(C691) R^(D1) R^(D20) R^(D1) L_(C692) R^(D1) R^(D21) R^(D1) L_(C693) R^(D1) R^(D22) R^(D1) L_(C694) R^(D1) R^(D23) R^(D1) L_(C695) R^(D1) R^(D24) R^(D1) L_(C696) R^(D1) R^(D25) R^(D1) L_(C697) R^(D1) R^(D26) R^(D1) L_(C698) R^(D1) R^(D27) R^(D1) L_(C699) R^(D1) R^(D28) R^(D1) L_(C700) R^(D1) R^(D29) R^(D1) L_(C701) R^(D1) R^(D30) R^(D1) L_(C702) R^(D1) R^(D31) R^(D1) L_(C703) R^(D1) R^(D32) R^(D1) L_(C704) R^(D1) R^(D33) R^(D1) L_(C705) R^(D1) R^(D34) R^(D1) L_(C706) R^(D1) R^(D35) R^(D1) L_(C707) R^(D1) R^(D40) R^(D1) L_(C708) R^(D1) R^(D41) R^(D1) L_(C709) R^(D1) R^(D42) R^(D1) L_(C710) R^(D1) R^(D64) R^(D1) L_(C711) R^(D1) R^(D66) R^(D1) L_(C712) R^(D1) R^(D68) R^(D1) L_(C713) R^(D1) R^(D76) R^(D1) L_(C714) R^(D2) R^(D1) R^(D1) L_(C715) R^(D2) R^(D3) R^(D1) L_(C716) R^(D2) R^(D4) R^(D1) L_(C717) R^(D2) R^(D5) R^(D1) L_(C718) R^(D2) R^(D6) R^(D1) L_(C719) R^(D2) R^(D7) R^(D1) L_(C720) R^(D2) R^(D8) R^(D1) L_(C721) R^(D2) R^(D9) R^(D1) L_(C722) R^(D2) R^(D10) R^(D1) L_(C723) R^(D2) R^(D11) R^(D1) L_(C724) R^(D2) R^(D12) R^(D1) L_(C725) R^(D2) R^(D13) R^(D1) L_(C726) R^(D2) R^(D14) R^(D1) L_(C727) R^(D2) R^(D15) R^(D1) L_(C728) R^(D2) R^(D16) R^(D1) L_(C729) R^(D2) R^(D17) R^(D1) L_(C730) R^(D2) R^(D18) R^(D1) L_(C731) R^(D2) R^(D19) R^(D1) L_(C732) R^(D2) R^(D20) R^(D1) L_(C733) R^(D2) R^(D21) R^(D1) L_(C734) R^(D2) R^(D22) R^(D1) L_(C735) R^(D2) R^(D23) R^(D1) L_(C736) R^(D2) R^(D24) R^(D1) L_(C737) R^(D2) R^(D25) R^(D1) L_(C738) R^(D2) R^(D26) R^(D1) L_(C739) R^(D2) R^(D27) R^(D1) L_(C740) R^(D2) R^(D28) R^(D1) L_(C741) R^(D2) R^(D29) R^(D1) L_(C742) R^(D2) R^(D30) R^(D1) L_(C743) R^(D2) R^(D31) R^(D1) L_(C744) R^(D2) R^(D32) R^(D1) L_(C745) R^(D2) R^(D33) R^(D1) L_(C746) R^(D2) R^(D34) R^(D1) L_(C747) R^(D2) R^(D35) R^(D1) L_(C748) R^(D2) R^(D40) R^(D1) L_(C749) R^(D2) R^(D41) R^(D1) L_(C750) R^(D2) R^(D42) R^(D1) L_(C751) R^(D2) R^(D64) R^(D1) L_(C752) R^(D2) R^(D66) R^(D1) L_(C753) R^(D2) R^(D68) R^(D1) L_(C754) R^(D2) R^(D76) R^(D1) L_(C755) R^(D3) R^(D4) R^(D1) L_(C756) R^(D3) R^(D5) R^(D1) L_(C757) R^(D3) R^(D6) R^(D1) L_(C758) R^(D3) R^(D7) R^(D1) L_(C759) R^(D3) R^(D8) R^(D1) L_(C760) R^(D3) R^(D9) R^(D1) L_(C761) R^(D3) R^(D10) R^(D1) L_(C762) R^(D3) R^(D11) R^(D1) L_(C763) R^(D3) R^(D12) R^(D1) L_(C764) R^(D3) R^(D13) R^(D1) L_(C765) R^(D3) R^(D14) R^(D1) L_(C766) R^(D3) R^(D15) R^(D1) L_(C767) R^(D3) R^(D16) R^(D1) L_(C768) R^(D3) R^(D17) R^(D1) L_(C769) R^(D3) R^(D18) R^(D1) L_(C770) R^(D3) R^(D19) R^(D1) L_(C771) R^(D3) R^(D20) R^(D1) L_(C772) R^(D3) R^(D21) R^(D1) L_(C773) R^(D3) R^(D22) R^(D1) L_(C774) R^(D3) R^(D23) R^(D1) L_(C775) R^(D3) R^(D24) R^(D1) L_(C776) R^(D3) R^(D25) R^(D1) L_(C777) R^(D3) R^(D26) R^(D1) L_(C778) R^(D3) R^(D27) R^(D1) L_(C779) R^(D3) R^(D28) R^(D1) L_(C780) R^(D3) R^(D29) R^(D1) L_(C781) R^(D3) R^(D30) R^(D1) L_(C782) R^(D3) R^(D31) R^(D1) L_(C783) R^(D3) R^(D32) R^(D1) L_(C784) R^(D3) R^(D33) R^(D1) L_(C785) R^(D3) R^(D34) R^(D1) L_(C786) R^(D3) R^(D35) R^(D1) L_(C787) R^(D3) R^(D40) R^(D1) L_(C788) R^(D3) R^(D41) R^(D1) L_(C789) R^(D3) R^(D42) R^(D1) L_(C790) R^(D3) R^(D64) R^(D1) L_(C791) R^(D3) R^(D66) R^(D1) L_(C792) R^(D3) R^(D68) R^(D1) L_(C793) R^(D3) R^(D76) R^(D1) L_(C794) R^(D4) R^(D5) R^(D1) L_(C795) R^(D4) R^(D6) R^(D1) L_(C796) R^(D4) R^(D7) R^(D1) L_(C797) R^(D4) R^(D8) R^(D1) L_(C798) R^(D4) R^(D9) R^(D1) L_(C799) R^(D4) R^(D10) R^(D1) L_(C800) R^(D4) R^(D11) R^(D1) L_(C801) R^(D4) R^(D12) R^(D1) L_(C802) R^(D4) R^(D13) R^(D1) L_(C803) R^(D4) R^(D14) R^(D1) L_(C804) R^(D4) R^(D15) R^(D1) L_(C805) R^(D4) R^(D16) R^(D1) L_(C806) R^(D4) R^(D17) R^(D1) L_(C807) R^(D4) R^(D18) R^(D1) L_(C808) R^(D4) R^(D19) R^(D1) L_(C809) R^(D4) R^(D20) R^(D1) L_(C810) R^(D4) R^(D21) R^(D1) L_(C811) R^(D4) R^(D22) R^(D1) L_(C812) R^(D4) R^(D23) R^(D1) L_(C813) R^(D4) R^(D24) R^(D1) L_(C814) R^(D4) R^(D25) R^(D1) L_(C815) R^(D4) R^(D26) R^(D1) L_(C816) R^(D4) R^(D27) R^(D1) L_(C817) R^(D4) R^(D28) R^(D1) L_(C818) R^(D4) R^(D29) R^(D1) L_(C819) R^(D4) R^(D30) R^(D1) L_(C820) R^(D4) R^(D31) R^(D1) L_(C821) R^(D4) R^(D32) R^(D1) L_(C822) R^(D4) R^(D33) R^(D1) L_(C823) R^(D4) R^(D34) R^(D1) L_(C824) R^(D4) R^(D35) R^(D1) L_(C825) R^(D4) R^(D40) R^(D1) L_(C826) R^(D4) R^(D41) R^(D1) L_(C827) R^(D4) R^(D42) R^(D1) L_(C828) R^(D4) R^(D64) R^(D1) L_(C829) R^(D4) R^(D66) R^(D1) L_(C830) R^(D4) R^(D68) R^(D1) L_(C831) R^(D4) R^(D76) R^(D1) L_(C832) R^(D4) R^(D1) R^(D1) L_(C833) R^(D7) R^(D5) R^(D1) L_(C834) R^(D7) R^(D6) R^(D1) L_(C835) R^(D7) R^(D8) R^(D1) L_(C836) R^(D7) R^(D9) R^(D1) L_(C837) R^(D7) R^(D10) R^(D1) L_(C838) R^(D7) R^(D11) R^(D1) L_(C839) R^(D7) R^(D12) R^(D1) L_(C840) R^(D7) R^(D13) R^(D1) L_(C841) R^(D7) R^(D14) R^(D1) L_(C842) R^(D7) R^(D15) R^(D1) L_(C843) R^(D7) R^(D16) R^(D1) L_(C844) R^(D7) R^(D11) R^(D1) L_(C845) R^(D7) R^(D18) R^(D1) L_(C846) R^(D7) R^(D19) R^(D1) L_(C847) R^(D7) R^(D20) R^(D1) L_(C848) R^(D7) R^(D21) R^(D1) L_(C849) R^(D7) R^(D22) R^(D1) L_(C850) R^(D7) R^(D23) R^(D1) L_(C851) R^(D7) R^(D24) R^(D1) L_(C852) R^(D7) R^(D25) R^(D1) L_(C853) R^(D7) R^(D26) R^(D1) L_(C854) R^(D7) R^(D27) R^(D1) L_(C855) R^(D7) R^(D28) R^(D1) L_(C856) R^(D7) R^(D29) R^(D1) L_(C857) R^(D7) R^(D30) R^(D1) L_(C858) R^(D7) R^(D31) R^(D1) L_(C859) R^(D7) R^(D32) R^(D1) L_(C860) R^(D7) R^(D33) R^(D1) L_(C861) R^(D7) R^(D34) R^(D1) L_(C862) R^(D7) R^(D35) R^(D1) L_(C863) R^(D7) R^(D40) R^(D1) L_(C864) R^(D7) R^(D41) R^(D1) L_(C865) R^(D7) R^(D42) R^(D1) L_(C866) R^(D7) R^(D64) R^(D1) L_(C867) R^(D7) R^(D66) R^(D1) L_(C868) R^(D7) R^(D68) R^(D1) L_(C869) R^(D7) R^(D76) R^(D1) L_(C870) R^(D8) R^(D5) R^(D1) L_(C871) R^(D8) R^(D6) R^(D1) L_(C872) R^(D8) R^(D9) R^(D1) L_(C873) R^(D8) R^(D10) R^(D1) L_(C874) R^(D8) R^(D11) R^(D1) L_(C875) R^(D8) R^(D12) R^(D1) L_(C876) R^(D8) R^(D11) R^(D1) L_(C877) R^(D8) R^(D14) R^(D1) L_(C878) R^(D8) R^(D15) R^(D1) L_(C879) R^(D8) R^(D16) R^(D1) L_(C880) R^(D8) R^(D17) R^(D1) L_(C881) R^(D8) R^(D18) R^(D1) L_(C882) R^(D8) R^(D19) R^(D1) L_(C883) R^(D8) R^(D20) R^(D1) L_(C884) R^(D8) R^(D21) R^(D1) L_(C885) R^(D8) R^(D22) R^(D1) L_(C886) R^(D8) R^(D23) R^(D1) L_(C887) R^(D8) R^(D24) R^(D1) L_(C888) R^(D8) R^(D25) R^(D1) L_(C889) R^(D8) R^(D26) R^(D1) L_(C890) R^(D8) R^(D27) R^(D1) L_(C891) R^(D8) R^(D28) R^(D1) L_(C892) R^(D8) R^(D29) R^(D1) L_(C893) R^(D8) R^(D30) R^(D1) L_(C894) R^(D8) R^(D31) R^(D1) L_(C895) R^(D8) R^(D32) R^(D1) L_(C896) R^(D8) R^(D33) R^(D1) L_(C897) R^(D8) R^(D34) R^(D1) L_(C898) R^(D8) R^(D35) R^(D1) L_(C899) R^(D8) R^(D40) R^(D1) L_(C900) R^(D8) R^(D41) R^(D1) L_(C901) R^(D8) R^(D42) R^(D1) L_(C902) R^(D8) R^(D64) R^(D1) L_(C903) R^(D8) R^(D66) R^(D1) L_(C904) R^(D8) R^(D68) R^(D1) L_(C905) R^(D8) R^(D76) R^(D1) L_(C906) R^(D11) R^(D5) R^(D1) L_(C907) R^(D11) R^(D6) R^(D1) L_(C908) R^(D11) R^(D9) R^(D1) L_(C909) R^(D11) R^(D10) R^(D1) L_(C910) R^(D11) R^(D12) R^(D1) L_(C911) R^(D11) R^(D13) R^(D1) L_(C912) R^(D11) R^(D14) R^(D1) L_(C913) R^(D11) R^(D15) R^(D1) L_(C914) R^(D11) R^(D16) R^(D1) L_(C915) R^(D11) R^(D17) R^(D1) L_(C916) R^(D11) R^(D18) R^(D1) L_(C917) R^(D11) R^(D19) R^(D1) L_(C918) R^(D11) R^(D20) R^(D1) L_(C919) R^(D11) R^(D21) R^(D1) L_(C920) R^(D11) R^(D22) R^(D1) L_(C921) R^(D11) R^(D23) R^(D1) L_(C922) R^(D11) R^(D24) R^(D1) L_(C923) R^(D11) R^(D25) R^(D1) L_(C924) R^(D11) R^(D26) R^(D1) L_(C925) R^(D11) R^(D27) R^(D1) L_(C926) R^(D11) R^(D28) R^(D1) L_(C927) R^(D11) R^(D29) R^(D1) L_(C928) R^(D11) R^(D30) R^(D1) L_(C929) R^(D11) R^(D31) R^(D1) L_(C930) R^(D11) R^(D32) R^(D1) L_(C931) R^(D11) R^(D33) R^(D1) L_(C932) R^(D11) R^(D34) R^(D1) L_(C933) R^(D11) R^(D35) R^(D1) L_(C934) R^(D11) R^(D40) R^(D1) L_(C935) R^(D11) R^(D41) R^(D1) L_(C936) R^(D11) R^(D42) R^(D1) L_(C937) R^(D11) R^(D64) R^(D1) L_(C938) R^(D11) R^(D66) R^(D1) L_(C939) R^(D11) R^(D68) R^(D1) L_(C940) R^(D11) R^(D76) R^(D1) L_(C941) R^(D11) R^(D5) R^(D1) L_(C942) R^(D13) R^(D6) R^(D1) L_(C943) R^(D11) R^(D9) R^(D1) L_(C944) R^(D13) R^(D10) R^(D1) L_(C945) R^(D13) R^(D12) R^(D1) L_(C946) R^(D13) R^(D14) R^(D1) L_(C947) R^(D11) R^(D15) R^(D1) L_(C948) R^(D13) R^(D16) R^(D1) L_(C949) R^(D13) R^(D17) R^(D1) L_(C950) R^(D13) R^(D18) R^(D1) L_(C951) R^(D11) R^(D19) R^(D1) L_(C952) R^(D13) R^(D20) R^(D1) L_(C953) R^(D13) R^(D21) R^(D1) L_(C954) R^(D13) R^(D22) R^(D1) L_(C955) R^(D13) R^(D23) R^(D1) L_(C956) R^(D13) R^(D24) R^(D1) L_(C957) R^(D13) R^(D25) R^(D1) L_(C958) R^(D13) R^(D26) R^(D1) L_(C959) R^(D13) R^(D27) R^(D1) L_(C960) R^(D13) R^(D28) R^(D1) L_(C961) R^(D13) R^(D29) R^(D1) L_(C962) R^(D13) R^(D30) R^(D1) L_(C963) R^(D13) R^(D31) R^(D1) L_(C964) R^(D13) R^(D32) R^(D1) L_(C965) R^(D13) R^(D33) R^(D1) L_(C966) R^(D13) R^(D34) R^(D1) L_(C967) R^(D13) R^(D35) R^(D1) L_(C968) R^(D13) R^(D40) R^(D1) L_(C969) R^(D13) R^(D41) R^(D1) L_(C970) R^(D13) R^(D42) R^(D1) L_(C971) R^(D13) R^(D64) R^(D1) L_(C972) R^(D13) R^(D66) R^(D1) L_(C973) R^(D13) R^(D68) R^(D1) L_(C974) R^(D13) R^(D76) R^(D1) L_(C975) R^(D14) R^(D5) R^(D1) L_(C976) R^(D14) R^(D6) R^(D1) L_(C977) R^(D14) R^(D9) R^(D1) L_(C978) R^(D14) R^(D10) R^(D1) L_(C979) R^(D14) R^(D12) R^(D1) L_(C980) R^(D14) R^(D15) R^(D1) L_(C981) R^(D14) R^(D10) R^(D1) L_(C982) R^(D14) R^(D17) R^(D1) L_(C983) R^(D14) R^(D18) R^(D1) L_(C984) R^(D14) R^(D19) R^(D1) L_(C985) R^(D14) R^(D20) R^(D1) L_(C986) R^(D14) R^(D21) R^(D1) L_(C987) R^(D14) R^(D22) R^(D1) L_(C988) R^(D14) R^(D23) R^(D1) L_(C989) R^(D14) R^(D24) R^(D1) L_(C990) R^(D14) R^(D25) R^(D1) L_(C991) R^(D14) R^(D26) R^(D1) L_(C992) R^(D14) R^(D27) R^(D1) L_(C993) R^(D14) R^(D28) R^(D1) L_(C994) R^(D14) R^(D29) R^(D1) L_(C995) R^(D14) R^(D30) R^(D1) L_(C996) R^(D14) R^(D31) R^(D1) L_(C997) R^(D14) R^(D32) R^(D1) L_(C998) R^(D14) R^(D33) R^(D1) L_(C999) R^(D14) R^(D34) R^(D1) L_(C1000) R^(D14) R^(D35) R^(D1) L_(C1001) R^(D14) R^(D40) R^(D1) L_(C1002) R^(D14) R^(D41) R^(D1) L_(C1003) R^(D14) R^(D42) R^(D1) L_(C1004) R^(D14) R^(D64) R^(D1) L_(C1005) R^(D14) R^(D66) R^(D1) L_(C1006) R^(D14) R^(D68) R^(D1) L_(C1007) R^(D14) R^(D76) R^(D1) L_(C1008) R^(D22) R^(D5) R^(D1) L_(C1009) R^(D22) R^(D6) R^(D1) L_(C1010) R^(D22) R^(D9) R^(D1) L_(C1011) R^(D22) R^(D10) R^(D1) L_(C1012) R^(D22) R^(D12) R^(D1) L_(C1013) R^(D22) R^(D15) R^(D1) L_(C1014) R^(D22) R^(D16) R^(D1) L_(C1015) R^(D22) R^(D17) R^(D1) L_(C1016) R^(D22) R^(D18) R^(D1) L_(C1017) R^(D22) R^(D19) R^(D1) L_(C1018) R^(D22) R^(D20) R^(D1) L_(C1019) R^(D22) R^(D21) R^(D1) L_(C1020) R^(D22) R^(D23) R^(D1) L_(C1021) R^(D22) R^(D24) R^(D1) L_(C1022) R^(D22) R^(D25) R^(D1) L_(C1023) R^(D22) R^(D26) R^(D1) L_(C1024) R^(D22) R^(D27) R^(D1) L_(C1025) R^(D22) R^(D28) R^(D1) L_(C1026) R^(D22) R^(D29) R^(D1) L_(C1027) R^(D22) R^(D30) R^(D1) L_(C1028) R^(D22) R^(D31) R^(D1) L_(C1029) R^(D22) R^(D32) R^(D1) L_(C1030) R^(D22) R^(D33) R^(D1) L_(C1031) R^(D22) R^(D34) R^(D1) L_(C1032) R^(D22) R^(D35) R^(D1) L_(C1033) R^(D22) R^(D40) R^(D1) L_(C1034) R^(D22) R^(D41) R^(D1) L_(C1035) R^(D22) R^(D42) R^(D1) L_(C1036) R^(D22) R^(D64) R^(D1) L_(C1037) R^(D22) R^(D66) R^(D1) L_(C1038) R^(D22) R^(D68) R^(D1) L_(C1039) R^(D22) R^(D76) R^(D1) L_(C1040) R^(D26) R^(D5) R^(D1) L_(C1041) R^(D26) R^(D6) R^(D1) L_(C1042) R^(D26) R^(D9) R^(D1) L_(C1043) R^(D26) R^(D10) R^(D1) L_(C1044) R^(D26) R^(D12) R^(D1) L_(C1045) R^(D26) R^(D15) R^(D1) L_(C1046) R^(D26) R^(D16) R^(D1) L_(C1047) R^(D26) R^(D17) R^(D1) L_(C1048) R^(D26) R^(D18) R^(D1) L_(C1049) R^(D26) R^(D19) R^(D1) L_(C1050) R^(D26) R^(D20) R^(D1) L_(C1051) R^(D26) R^(D21) R^(D1) L_(C1052) R^(D26) R^(D23) R^(D1) L_(C1053) R^(D26) R^(D24) R^(D1) L_(C1054) R^(D26) R^(D25) R^(D1) L_(C1055) R^(D26) R^(D27) R^(D1) L_(C1056) R^(D26) R^(D28) R^(D1) L_(C1057) R^(D26) R^(D29) R^(D1) L_(C1058) R^(D26) R^(D30) R^(D1) L_(C1059) R^(D26) R^(D31) R^(D1) L_(C1060) R^(D26) R^(D32) R^(D1) L_(C1061) R^(D26) R^(D33) R^(D1) L_(C1062) R^(D26) R^(D34) R^(D1) L_(C1063) R^(D26) R^(D35) R^(D1) L_(C1064) R^(D26) R^(D40) R^(D1) L_(C1065) R^(D26) R^(D41) R^(D1) L_(C1066) R^(D26) R^(D42) R^(D1) L_(C1067) R^(D26) R^(D64) R^(D1) L_(C1068) R^(D26) R^(D66) R^(D1) L_(C1069) R^(D26) R^(D68) R^(D1) L_(C1070) R^(D26) R^(D76) R^(D1) L_(C1071) R^(D35) R^(D5) R^(D1) L_(C1072) R^(D35) R^(D6) R^(D1) L_(C1073) R^(D35) R^(D9) R^(D1) L_(C1074) R^(D35) R^(D10) R^(D1) L_(C1075) R^(D35) R^(D12) R^(D1) L_(C1076) R^(D35) R^(D15) R^(D1) L_(C1077) R^(D35) R^(D16) R^(D1) L_(C1078) R^(D35) R^(D17) R^(D1) L_(C1079) R^(D35) R^(D18) R^(D1) L_(C1080) R^(D35) R^(D19) R^(D1) L_(C1081) R^(D35) R^(D20) R^(D1) L_(C1082) R^(D35) R^(D21) R^(D1) L_(C1083) R^(D35) R^(D23) R^(D1) L_(C1084) R^(D35) R^(D24) R^(D1) L_(C1085) R^(D35) R^(D25) R^(D1) L_(C1086) R^(D35) R^(D27) R^(D1) L_(C1087) R^(D35) R^(D28) R^(D1) L_(C1088) R^(D35) R^(D29) R^(D1) L_(C1089) R^(D35) R^(D30) R^(D1) L_(C1090) R^(D35) R^(D31) R^(D1) L_(C1091) R^(D35) R^(D32) R^(D1) L_(C1092) R^(D35) R^(D33) R^(D1) L_(C1093) R^(D35) R^(D34) R^(D1) L_(C1094) R^(D35) R^(D40) R^(D1) L_(C1095) R^(D35) R^(D41) R^(D1) L_(C1096) R^(D35) R^(D42) R^(D1) L_(C1097) R^(D35) R^(D64) R^(D1) L_(C1098) R^(D35) R^(D66) R^(D1) L_(C1099) R^(D35) R^(D68) R^(D1) L_(C1100) R^(D35) R^(D76) R^(D1) L_(C1101) R^(D40) R^(D5) R^(D1) L_(C1102) R^(D40) R^(D6) R^(D1) L_(C1103) R^(D40) R^(D9) R^(D1) L_(C1104) R^(D40) R^(D10) R^(D1) L_(C1105) R^(D40) R^(D12) R^(D1) L_(C1106) R^(D40) R^(D15) R^(D1) L_(C1107) R^(D40) R^(D16) R^(D1) L_(C1108) R^(D40) R^(D17) R^(D1) L_(C1109) R^(D40) R^(D18) R^(D1) L_(C1110) R^(D40) R^(D19) R^(D1) L_(C1111) R^(D40) R^(D20) R^(D1) L_(C1112) R^(D40) R^(D21) R^(D1) L_(C1113) R^(D40) R^(D23) R^(D1) L_(C1114) R^(D40) R^(D24) R^(D1) L_(C1115) R^(D40) R^(D25) R^(D1) L_(C1116) R^(D40) R^(D27) R^(D1) L_(C1117) R^(D40) R^(D28) R^(D1) L_(C1118) R^(D40) R^(D29) R^(D1) L_(C1119) R^(D40) R^(D30) R^(D1) L_(C1120) R^(D40) R^(D31) R^(D1) L_(C1121) R^(D40) R^(D32) R^(D1) L_(C1122) R^(D40) R^(D33) R^(D1) L_(C1123) R^(D40) R^(D34) R^(D1) L_(C1124) R^(D40) R^(D41) R^(D1) L_(C1125) R^(D40) R^(D42) R^(D1) L_(C1126) R^(D40) R^(D64) R^(D1) L_(C1127) R^(D40) R^(D66) R^(D1) L_(C1128) R^(D40) R^(D68) R^(D1) L_(C1129) R^(D40) R^(D76) R^(D1) L_(C1130) R^(D41) R^(D5) R^(D1) L_(C1131) R^(D41) R^(D6) R^(D1) L_(C1132) R^(D41) R^(D9) R^(D1) L_(C1133) R^(D41) R^(D10) R^(D1) L_(C1134) R^(D41) R^(D12) R^(D1) L_(C1135) R^(D41) R^(D15) R^(D1) L_(C1136) R^(D41) R^(D16) R^(D1) L_(C1137) R^(D41) R^(D17) R^(D1) L_(C1138) R^(D41) R^(D18) R^(D1) L_(C1139) R^(D41) R^(D19) R^(D1) L_(C1140) R^(D41) R^(D20) R^(D1) L_(C1141) R^(D41) R^(D21) R^(D1) L_(C1142) R^(D41) R^(D23) R^(D1) L_(C1143) R^(D41) R^(D24) R^(D1) L_(C1144) R^(D41) R^(D25) R^(D1) L_(C1145) R^(D41) R^(D27) R^(D1) L_(C1146) R^(D41) R^(D28) R^(D1) L_(C1147) R^(D41) R^(D29) R^(D1) L_(C1148) R^(D41) R^(D30) R^(D1) L_(C1149) R^(D41) R^(D31) R^(D1) L_(C1150) R^(D41) R^(D32) R^(D1) L_(C1151) R^(D41) R^(D33) R^(D1) L_(C1152) R^(D41) R^(D34) R^(D1) L_(C1153) R^(D41) R^(D42) R^(D1) L_(C1154) R^(D41) R^(D64) R^(D1) L_(C1155) R^(D41) R^(D66) R^(D1) L_(C1156) R^(D41) R^(D68) R^(D1) L_(C1157) R^(D41) R^(D76) R^(D1) L_(C1158) R^(D64) R^(D5) R^(D1) L_(C1159) R^(D64) R^(D6) R^(D1) L_(C1160) R^(D64) R^(D9) R^(D1) L_(C1161) R^(D64) R^(D10) R^(D1) L_(C1162) R^(D64) R^(D12) R^(D1) L_(C1163) R^(D64) R^(D15) R^(D1) L_(C1164) R^(D64) R^(D16) R^(D1) L_(C1165) R^(D64) R^(D17) R^(D1) L_(C1166) R^(D64) R^(D18) R^(D1) L_(C1167) R^(D64) R^(D19) R^(D1) L_(C1168) R^(D64) R^(D20) R^(D1) L_(C1169) R^(D64) R^(D21) R^(D1) L_(C1170) R^(D64) R^(D23) R^(D1) L_(C1171) R^(D64) R^(D24) R^(D1) L_(C1172) R^(D64) R^(D25) R^(D1) L_(C1173) R^(D64) R^(D27) R^(D1) L_(C1174) R^(D64) R^(D28) R^(D1) L_(C1175) R^(D64) R^(D29) R^(D1) L_(C1176) R^(D64) R^(D30) R^(D1) L_(C1177) R^(D64) R^(D31) R^(D1) L_(C1178) R^(D64) R^(D32) R^(D1) L_(C1179) R^(D64) R^(D33) R^(D1) L_(C1180) R^(D64) R^(D34) R^(D1) L_(C1181) R^(D64) R^(D42) R^(D1) L_(C1182) R^(D64) R^(D64) R^(D1) L_(C1183) R^(D64) R^(D66) R^(D1) L_(C1184) R^(D64) R^(D68) R^(D1) L_(C1185) R^(D64) R^(D76) R^(D1) L_(C1186) R^(D66) R^(D5) R^(D1) L_(C1187) R^(D66) R^(D6) R^(D1) L_(C1188) R^(D66) R^(D9) R^(D1) L_(C1189) R^(D66) R^(D10) R^(D1) L_(C1190) R^(D66) R^(D12) R^(D1) L_(C1191) R^(D66) R^(D15) R^(D1) L_(C1192) R^(D66) R^(D16) R^(D1) L_(C1193) R^(D66) R^(D17) R^(D1) L_(C1194) R^(D66) R^(D18) R^(D1) L_(C1195) R^(D66) R^(D19) R^(D1) L_(C1196) R^(D66) R^(D20) R^(D1) L_(C1197) R^(D66) R^(D21) R^(D1) L_(C1198) R^(D66) R^(D23) R^(D1) L_(C1199) R^(D66) R^(D24) R^(D1) L_(C1200) R^(D66) R^(D25) R^(D1) L_(C1201) R^(D66) R^(D27) R^(D1) L_(C1202) R^(D68) R^(D28) R^(D1) L_(C1203) R^(D68) R^(D29) R^(D1) L_(C1204) R^(D68) R^(D30) R^(D1) L_(C1205) R^(D68) R^(D31) R^(D1) L_(C1206) R^(D68) R^(D32) R^(D1) L_(C1207) R^(D68) R^(D33) R^(D1) L_(C1208) R^(D68) R^(D34) R^(D1) L_(C1209) R^(D68) R^(D42) R^(D1) L_(C1210) R^(D68) R^(D68) R^(D1) L_(C1211) R^(D68) R^(D76) R^(D1) L_(C1212) R^(D68) R^(D5) R^(D1) L_(C1213) R^(D68) R^(D6) R^(D1) L_(C1214) R^(D68) R^(D9) R^(D1) L_(C1215) R^(D68) R^(D10) R^(D1) L_(C1216) R^(D68) R^(D12) R^(D1) L_(C1217) R^(D68) R^(D15) R^(D1) L_(C1218) R^(D68) R^(D16) R^(D1) L_(C1219) R^(D68) R^(D17) R^(D1) L_(C1220) R^(D68) R^(D18) R^(D1) L_(C1221) R^(D68) R^(D19) R^(D1) L_(C1222) R^(D68) R^(D20) R^(D1) L_(C1223) R^(D68) R^(D21) R^(D1) L_(C1224) R^(D68) R^(D23) R^(D1) L_(C1225) R^(D68) R^(D24) R^(D1) L_(C1226) R^(D68) R^(D25) R^(D1) L_(C1227) R^(D68) R^(D27) R^(D1) L_(C1228) R^(D68) R^(D28) R^(D1) L_(C1229) R^(D68) R^(D29) R^(D1) L_(C1230) R^(D68) R^(D30) R^(D1) L_(C1231) R^(D68) R^(D31) R^(D1) L_(C1232) R^(D68) R^(D32) R^(D1) L_(C1233) R^(D68) R^(D33) R^(D1) L_(C1234) R^(D68) R^(D34) R^(D1) L_(C1235) R^(D68) R^(D42) R^(D1) L_(C1236) R^(D68) R^(D76) R^(D1) L_(C1237) R^(D76) R^(D5) R^(D1) L_(C1238) R^(D76) R^(D6) R^(D1) L_(C1239) R^(D76) R^(D9) R^(D1) L_(C1240) R^(D76) R^(D10) R^(D1) L_(C1241) R^(D76) R^(D12) R^(D1) L_(C1242) R^(D76) R^(D15) R^(D1) L_(C1243) R^(D76) R^(D16) R^(D1) L_(C1244) R^(D76) R^(D17) R^(D1) L_(C1245) R^(D76) R^(D18) R^(D1) L_(C1246) R^(D76) R^(D19) R^(D1) L_(C1247) R^(D76) R^(D20) R^(D1) L_(C1248) R^(D76) R^(D21) R^(D1) L_(C1249) R^(D76) R^(D23) R^(D1) L_(C1250) R^(D76) R^(D24) R^(D1) L_(C1251) R^(D76) R^(D25) R^(D1) L_(C1252) R^(D76) R^(D27) R^(D1) L_(C1253) R^(D76) R^(D28) R^(D1) L_(C1254) R^(D76) R^(D29) R^(D1) L_(C1255) R^(D76) R^(D30) R^(D1) L_(C1256) R^(D76) R^(D31) R^(D1) L_(C1257) R^(D76) R^(D32) R^(D1) L_(C1258) R^(D76) R^(D33) R^(D1) L_(C1259) R^(D76) R^(D34) R^(D1) L_(C1260) R^(D76) R^(D42) R^(D1) where R^(D1) to R^(D21) have the following structures:

In some embodiments, the compound has the formula:

where rings E and F each independently represents a 5-membered or 6-membered carbocyclic or heterocyclic ring; R^(E) and R^(F) each independently represents mono to the maximum possible number of substitutions, or no substitution; m₁, m₂, and m₃ are each independently an integer of 0 or 1; when m₂ is 0, both m₁ and m₃ are 1; when m₂ is 1, each of m₁ and m₃ independently can be 0 or 1; when m₁ is 0, L¹ is not present; when m₂ is 0, L² is not present; when m₃ is 0, L³ is not present; where L¹, L², and L³ are each independently selected from the group consisting of a direct bond, BR, NR, PR, O, S, Se, C═O, S═O, SO2, CRR′, SiRR′, GeRR′, alkyl, cycloalkyl, and combinations thereof; where R^(E) and R^(F) are each independently hydrogen or a substituent selected from the group consisting of the general substituents defined above; where R and R′ are each independently selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and where any adjacent R^(E), R^(F), R, and R′ can be joined to form a ring.

In some embodiments where the compound is homoleptic, the compound has the formula:

where R^(G) is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, aryl, heteroaryl, partially or fully deuterated variants thereof, partially or fully fluorinated variants thereof, and combinations thereof.

In some embodiments, the homoleptic compound has the formula selected from the group consisting of:

According to another aspect of the present disclosure, an OLED is disclosed. The OLED comprises: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, where the organic layer comprises a compound comprising a first ligand L_(A) of Formula I

as defined above.

A consumer product comprising the OLED defined above is also disclosed.

In some embodiments, the OLED has one or more characteristics selected from the group consisting of being flexible, being rollable, being foldable, being stretchable, and being curved. In some embodiments, the OLED is transparent or semi-transparent. In some embodiments, the OLED further comprises a layer comprising carbon nanotubes.

In some embodiments, the OLED further comprises a layer comprising a delayed fluorescent emitter. In some embodiments, the OLED comprises a RGB pixel arrangement or white plus color filter pixel arrangement. In some embodiments, the OLED is a mobile device, a hand held device, or a wearable device. In some embodiments, the OLED is a display panel having less than 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a display panel having at least 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a lighting panel.

An emissive region in an OLED is also disclosed. The emissive region comprises a compound comprising a first ligand L_(A) of Formula I

where X¹ to X⁸ are each independently C or N, where no more than two N atoms are bonded to each other. At least one pair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and is joined to a structure G of Formula II

where A is selected from the group consisting of O, S, Se, and NR′. In the compound, R^(A), R^(B), R^(C), and R^(D) each independently represents mono to the maximum number of allowable substitutions, or no substitution. Each R^(A), R^(B), R^(C), R^(D), and R′ is independently hydrogen or a substituent selected from the group consisting of the general substituents defined above. Any two substituents may be joined or fused together to form a ring. The ligand L_(A) is complexed to a metal M. M is optionally coordinated to other ligands. The ligand L_(A) is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand.

In some embodiments of the emissive region, the compound is an emissive dopant or a non-emissive dopant.

In some embodiments, the emissive region further comprises a host, wherein the host contains at least one group selected from the group consisting of metal complex, triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, aza-triphenylene, aza-carbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.

In some embodiments, the emissive region further comprises a host, wherein the host is selected from the group consisting of:

and combinations thereof.

In some embodiments, the compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence; see, e.g., U.S. application Ser. No. 15/700,352, which is hereby incorporated by reference in its entirety), triplet-triplet annihilation, or combinations of these processes. In some embodiments, the emissive dopant can be a racemic mixture, or can be enriched in one enantiomer. In some embodiments, the compound can be homoleptic (each ligand is the same). In some embodiments, the compound can be heteroleptic (at least one ligand is different from others).

When there are more than one ligand coordinated to a metal, the ligands can all be the same in some embodiments. In some other embodiments, at least one ligand is different from the other ligand(s). In some embodiments, every ligand can be different from each other. This is also true in embodiments where a ligand being coordinated to a metal can be linked with other ligands being coordinated to that metal to form a tridentate, tetradentate, pentadentate, or hexadentate ligands. Thus, where the coordinating ligands are being linked together, all of the ligands can be the same in some embodiments, and at least one of the ligands being linked can be different from the other ligand(s) in some other embodiments.

In some embodiments, the compound can be used as a phosphorescent sensitizer in an OLED where one or multiple layers in the OLED contains an acceptor in the form of one or more fluorescent and/or delayed fluorescence emitters. In some embodiments, the compound can be used as one component of an exciplex to be used as a sensitizer. As a phosphorescent sensitizer, the compound must be capable of energy transfer to the acceptor and the acceptor will emit the energy or further transfer energy to a final emitter. The acceptor concentrations can range from 0.001% to 100%. The acceptor could be in either the same layer as the phosphorescent sensitizer or in one or more different layers. In some embodiments, the acceptor is a TADF emitter. In some embodiments, the acceptor is a fluorescent emitter. In some embodiments, the emission can arise from any or all of the sensitizer, acceptor, and final emitter.

According to another aspect, a formulation comprising the compound described herein is also disclosed.

The OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.

The organic layer can also include a host. In some embodiments, two or more hosts are preferred. In some embodiments, the hosts used maybe a) bipolar, b) electron transporting, c) hole transporting or d) wide band gap materials that play little role in charge transport. In some embodiments, the host can include a metal complex. The host can be a triphenylene containing benzo-fused thiophene or benzo-fused furan. Any substituent in the host can be an unfused substituent independently selected from the group consisting of C_(n)H_(2n+1), OC_(n)H_(2n+1), OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂), CH═CH—C_(n)H_(2n+1), C≡C—C_(n)H_(2n+1), Ar₁, Ar₁—Ar₂, and C_(n)H_(2n)—Ar₁, or the host has no substitutions. In the preceding substituents n can range from 1 to 10; and Ar₁ and Ar₂ can be independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof. The host can be an inorganic compound. For example a Zn containing inorganic material e.g. ZnS.

The host can be a compound comprising at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene. The host can include a metal complex. The host can be, but is not limited to, a specific compound selected from the group consisting of:

and combinations thereof. Additional information on possible hosts is provided below.

In yet another aspect of the present disclosure, a formulation that comprises the novel compound disclosed herein is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, electron blocking material, hole blocking material, and an electron transport material, disclosed herein.

The present disclosure encompasses any chemical structure comprising the novel compound of the present disclosure, or a monovalent or polyvalent variant thereof. In other words, the inventive compound, or a monovalent or polyvalent variant thereof, can be a part of a larger chemical structure. Such chemical structure can be selected from the group consisting of a monomer, a polymer, a macromolecule, and a supramolecule (also known as supermolecule). As used herein, a “monovalent variant of a compound” refers to a moiety that is identical to the compound except that one hydrogen has been removed and replaced with a bond to the rest of the chemical structure. As used herein, a “polyvalent variant of a compound” refers to a moiety that is identical to the compound except that more than one hydrogen has been removed and replaced with a bond or bonds to the rest of the chemical structure. In the instance of a supramolecule, the inventive compound can also be incorporated into the supramolecule complex without covalent bonds.

Combination with Other Materials

The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.

Conductivity Dopants:

A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.

Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO006081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804, US20150123047, and US2012146012.

HIL/HTL:

A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoO_(x); a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:

Each of Ar¹ to Ar⁹ is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, Ar¹ to Ar⁹ is independently selected from the group consisting of:

wherein k is an integer from 1 to 20; X¹⁰¹ to X¹⁰⁸ is C (including CH) or N; Z¹⁰¹ is NAr¹, O, or S; Ar¹ has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40; (Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹ and Y¹⁰² are independently selected from C, N, O, P, and S; L¹⁰¹ is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In another aspect, (Y¹⁰¹-Y¹⁰²) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc⁺/Fc couple less than about 0.6 V.

Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550, WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.

An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.

Host:

The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have the following general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴) is a bidentate ligand, Y¹⁰³ and Y¹⁰⁴ are independently selected from C, N, O, P, and S; L¹⁰¹ is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.

In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

In one aspect, the host compound contains at least one of the following groups selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, the host compound contains at least one of the following groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20. X¹⁰¹ to X¹⁰⁸ are independently selected from C (including CH) or N. Z¹⁰¹ and Z¹⁰² are independently selected from NR¹⁰¹, O, or S.

Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472, US20170263869, US20160163995, U.S. Pat. No. 9,466,803,

Additional Emitters:

One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.

Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599, U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos. 6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469, 6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228, 7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586, 8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456, WO2014112450.

HBL:

A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the HBL interface.

In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of the following groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹ is an another ligand, k′ is an integer from 1 to 3.

ETL:

Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.

In one aspect, compound used in ETL contains at least one of the following groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar¹ to Ar³ has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X¹⁰¹ to X¹⁰⁸ is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L¹⁰¹ is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.

Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,

Charge Generation Layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.

In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.

Experimental

2,3-dibromopyridine (24.00 g, 101 mmol), dibenzo[b,d]furan-3-ylboronic acid (22.55 g, 106 mmol), sodium hydroxide (12.16 g, 304 mmol), tetrakis(triphenylphosphine)palladium(0) (5.85 g, 5.07 mmol), THF (1673 ml) and water (239 ml) were added to a 5 L flask. The resulting mixture was degassed and stirred at 60° C. for 5 hrs. The reaction mixture was then cooled to room temperature and diluted with brine. The organic layer was separated, and the aqueous layer was extracted with DCM. The combined organic layers were dried over Na₂SO₄, filtered, and concentrated. The resulting residue was purified by column chromatography (DCM/heptane) to obtain 23.36 g (66% yield) of 3-bromo-2-(dibenzo[b,d]furan-3-yl)pyridine as a white solid.

A 500 mL flask was charged with dicyclohexyl(2′,4′,6′-triisopropyl-[1,1′-biphenyl]-2-yl)phosphane (1.374 g, 2.88 mmol), PdOAc₂ (0.324 g, 1.441 mmol), copper(I) iodide (0.274 g, 1.441 mmol), 3-bromo-2-(dibenzo[b,d]furan-3-yl)pyridine (23.36 g, 72.1 mmol), and triethylamine (144 mL). The reaction mixture was stirred and heated to 55° C. Ethynyltrimethylsilane (14.97 mL, 108 mmol) was then added into reaction mixture and stirred at 55° C. for about 16 hrs. The reaction mixture was cooled to room temperature, diluted with water and extracted with EtOAc. The combined organic layer was dried over Na₂SO₄, concentrated and the resulting residue was subjected to silica gel column chromatography (DCM/heptane) to afford 2-(dibenzo[b,d]furan-3-yl)-3-((trimethylsilyl)ethynyl)pyridine (24.38 g, 99% yield).

Potassium carbonate (29.60 g, 214 mmol) was added to a 2 L flask containing 2-(dibenzo[b,d]furan-3-yl)-3-((trimethylsilyl)ethynyl)pyridine (24.38 g, 71.4 mmol) in methanol (714 mL). After 3 hrs of stirring at room temperature, the reaction mixture was concentrated on the rotary evaporator. Purification of crude material via silica gel column chromatography (EtOAc/heptane) gave 2-(dibenzo[b,d]furan-3-yl)-3-ethynylpyridine (18 g, 94% yield) as an off-white solid.

1 L flask equipped with a magnetic stir bar was charged with 2-(dibenzo[b,d]furan-3-yl)-3-ethynylpyridine (16.00 g, 59.4 mmol), platinum(II) chloride (3.95 g, 14.85 mmol), and toluene (300 mL). The mixture was stirred and heated to reflux for about 16 hrs under nitrogen atmosphere. Upon completion, as evidenced by TLC analysis, the reaction mixture was cooled to room temperature and purified via silica gel column chromatography (EtOAc/heptane) which produced 6.7 g (42% yield) of desired benzo[2,3]benzofuro[5,6-h]quinoline with 99.99% purity.

A 250 mL, 4-neck round bottom flask, equipped with a condenser, stir bar and thermocouple was charged with [Ir(5-(methyl-d₃)-2-phenylpyridine(1H))₂(MeOH)₂](trifluoromethane-sulfonate) (4.1 g, 5.48 mmol, 1.0 equiv), benzo[2,3]benzofuro[5,6-h]quinoline (3.1 g, 11.31 mmol, 2.1 equiv) and ethanol (122 mL). The reaction mixture was cooled to room temperature, filtered through paper, washing the residue with methanol (100 mL). The filtrate was concentrated under reduced pressure. The crude solid was chromatographed on silica gel (150 g), eluting with a gradient of 50-100% dichloromethane in heptanes to give the inventive example Compound A as a yellow solid.

The photoluminescence spectrum of the inventive example Compound A in PMMA film was measured and the plot of the spectrum is shown in FIG. 3. The inventive compound exhibited a broad emission profile with λ_(max)=540 nm and unprecedentedly high PLQY (˜100%). The broad emission profile from 490 nm to almost 700 nm covering a significant portion of the visible region makes the inventive compound as useful emitter material in white OLEDs for lighting and display applications.

It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting. 

We claim:
 1. A compound comprising a first ligand L_(A) of Formula I

wherein X¹ to X⁸ are each independently C or N; wherein no more than two N atoms are bonded to each other; wherein at least one pair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and is joined to a structure G of Formula II

wherein A is selected from the group consisting of O, S, Se, and NR′; wherein R^(A), R^(B), R^(C), and R^(D) each independently represents mono to the maximum number of allowable substitutions, or no substitution; wherein each R^(A), R^(B), R^(C), R^(D), and R′ is independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any two substituents may be joined or fused together to form a ring; wherein L_(A) is complexed to a metal M; wherein M is optionally coordinated to other ligands; wherein the ligand L_(A) is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand.
 2. The compound of claim 1, wherein each R^(A), R^(B), R^(C), and R^(D) is independently selected from the group consisting of hydrogen, deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
 3. The compound of claim 1, wherein X¹ to X⁸ are each C.
 4. The compound of claim 1, wherein at least one of X¹ to X⁸ is N.
 5. The compound of claim 1, wherein M is selected from the group consisting of Ru, Os, Pd, Pt, Ir, Cu, and Au.
 6. The compound of claim 1, wherein Formula II is substituted or unsubstituted


7. The compound of claim 1, wherein only one pair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and is joined to the structure G.
 8. The compound of claim 1, wherein the first ligand L_(A) is selected from the group consisting of

wherein X⁹ to X¹² are each independently C or N; and wherein no more than two N atoms are bonded to each other.
 9. The compound of claim 1, wherein the first ligand L_(A) is selected from the group consisting of ligands L_(A1-O) to L_(A384-O), L_(A1-S) to L_(A384-S), and L_(A1-C) to L_(A384-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points of attachment to the corresponding points of attachment in the structure G, wherein for ligands L_(A1-O) to L_(A384-O), A in the structure G is O, wherein for ligands L_(A1-S) to L_(A384-S), A in the structure G is S, wherein for ligands L_(A1-C) to L_(A384-C), A in the structure G is C(CH₃)₂, wherein X³, R⁶, R⁸, and G are defined for A1 to A384 as shown below: X³ R⁶ R⁸ G A1 CH H H G¹ A2 CH H H G³ A3 CH H H G⁵ A4 CH H H G⁷ A5 CH H H G⁹ A6 CH H H G¹¹ A7 N H H G¹ A8 N H H G³ A9 N H H G⁵ A10 N H H G⁷ A11 N H H G⁹ A12 N H H G¹¹ A13 CR^(B1) H H G¹ A14 CR^(B3) H H G¹ A15 CR^(B5) H H G¹ A16 CR^(B7) H H G¹ A17 CR^(B9) H H G¹ A18 CR^(B11) H H G¹ A19 CR^(B13) H H G¹ A20 CR^(B15) H H G¹ A21 CR^(B17) H H G¹ A22 CR^(B19) H H G¹ A23 CR^(B21) H H G¹ A24 CR^(B23) H H G¹ A25 CR^(B25) H H G¹ A26 CR^(B27) H H G¹ A27 CR^(B29) H H G¹ A28 CR^(B31) H H G¹ A29 CR^(B33) H H G¹ A30 CR^(B35) H H G¹ A31 CR^(B37) H H G¹ A32 CR^(B39) H H G¹ A33 CR^(B41) H H G¹ A34 CR^(B43) H H G¹ A35 CR^(B45) H H G¹ A36 CR^(B47) H H G¹ A37 CR^(B49) H H G¹ A38 CR^(B51) H H G¹ A39 CR^(B53) H H G¹ A40 CR^(B55) H H G¹ A41 CR^(B57) H H G¹ A42 CR^(B59) H H G¹ A43 CR^(B1) H H G² A44 CR^(B3) H H G² A45 CR^(B5) H H G² A46 CR^(B7) H H G² A47 CR^(B9) H H G² A48 CR^(B11) H H G² A49 CR^(B13) H H G² A50 CR^(B15) H H G² A51 CR^(B17) H H G² A52 CR^(B19) H H G² A53 CR^(B21) H H G² A54 CR^(B23) H H G² A55 CR^(B25) H H G² A56 CR^(B27) H H G² A57 CR^(B29) H H G² A58 CR^(B31) H H G² A59 CR^(B33) H H G² A60 CR^(B35) H H G² A61 CR^(B37) H H G² A62 CR^(B39) H H G² A63 CR^(B41) H H G² A64 CR^(B43) H H G² A65 CR^(B45) H H G² A66 CR^(B47) H H G² A67 CR^(B49) H H G² A68 CR^(B51) H H G² A69 CR^(B53) H H G² A70 CR^(B55) H H G² A71 CR^(B57) H H G² A72 CR^(B59) H H G² A73 CR^(B1) H H G³ A74 CR^(B3) H H G³ A75 CR^(B5) H H G³ A76 CR^(B7) H H G³ A77 CR^(B9) H H G³ A78 CR^(B11) H H G³ A79 CR^(B13) H H G³ A80 CR^(B15) H H G³ A81 CR^(B17) H H G³ A82 CR^(B19) H H G³ A83 CR^(B21) H H G³ A84 CR^(B23) H H G³ A85 CR^(B25) H H G³ A86 CR^(B27) H H G³ A87 CR^(B29) H H G³ A88 CR^(B31) H H G³ A89 CR^(B33) H H G³ A90 CR^(B35) H H G³ A91 CR^(B37) H H G³ A92 CR^(B39) H H G³ A93 CR^(B41) H H G³ A94 CR^(B43) H H G³ A95 CR^(B45) H H G³ A96 CR^(B47) H H G³ A97 CR^(B49) H H G³ A98 CR^(B51) H H G³ A99 CR^(B53) H H G³ A100 CR^(B55) H H G³ A101 CR^(B57) H H G³ A102 CR^(B59) H H G³ A103 CR^(B1) H H G⁴ A104 CR^(B3) H H G⁴ A105 CR^(B5) H H G⁴ A106 CR^(B7) H H G⁴ A107 CR^(B9) H H G⁴ A108 CR^(B11) H H G⁴ A109 CR^(B13) H H G⁴ A110 CR^(B15) H H G⁴ A111 CR^(B17) H H G⁴ A112 CR^(B19) H H G⁴ A113 CR^(B21) H H G⁴ A114 CR^(B23) H H G⁴ A115 CR^(B25) H H G⁴ A116 CR^(B27) H H G⁴ A117 CR^(B29) H H G⁴ A118 CR^(B31) H H G⁴ A119 CR^(B33) H H G⁴ A120 CR^(B35) H H G⁴ A121 CR^(B37) H H G⁴ A122 CR^(B39) H H G⁴ A123 CR^(B41) H H G⁴ A124 CR^(B43) H H G⁴ A125 CR^(B45) H H G⁴ A126 CR^(B47) H H G⁴ A127 CR^(B49) H H G⁴ A128 CR^(B51) H H G⁴ A129 CH H H G² A130 CH H H G⁴ A131 CH H H G⁶ A132 CH H H G⁸ A133 CH H H G¹⁰ A134 CH H H G¹² A135 N H H G² A136 N H H G⁴ A137 N H H G⁶ A138 N H H G⁸ A139 N H H G¹⁰ A140 N H H G¹² A141 CR^(B2) H H G¹ A142 CR^(B4) H H G¹ A143 CR^(B6) H H G¹ A144 CR^(B8) H H G¹ A145 CR^(B10) H H G¹ A146 CR^(B12) H H G¹ A147 CR^(B14) H H G¹ A148 CR^(B16) H H G¹ A149 CR^(B18) H H G¹ A150 CR^(B20) H H G¹ A151 CR^(B22) H H G¹ A152 CR^(B24) H H G¹ A153 CR^(B26) H H G¹ A154 CR^(B27) H H G¹ A155 CR^(B30) H H G¹ A156 CR^(B32) H H G¹ A157 CR^(B34) H H G¹ A158 CR^(B36) H H G¹ A159 CR^(B38) H H G¹ A160 CR^(B40) H H G¹ A161 CR^(B42) H H G¹ A162 CR^(B44) H H G¹ A163 CR^(B46) H H G¹ A164 CR^(B47) H H G¹ A165 CR^(B50) H H G¹ A166 CR^(B51) H H G¹ A167 CR^(B54) H H G¹ A168 CR^(B56) H H G¹ A169 CR^(B57) H H G¹ A170 CR^(B60) H H G¹ A171 CR^(B2) H H G² A172 CR^(B4) H H G² A173 CR^(B6) H H G² A174 CR^(B8) H H G² A175 CR^(B10) H H G² A176 CR^(B12) H H G² A177 CR^(B14) H H G² A178 CR^(B16) H H G² A179 CR^(B18) H H G² A180 CR^(B20) H H G² A181 CR^(B22) H H G² A182 CR^(B24) H H G² A183 CR^(B26) H H G² A184 CR^(B27) H H G² A185 CR^(B30) H H G² A186 CR^(B32) H H G² A187 CR^(B34) H H G² A188 CR^(B36) H H G² A189 CR^(B38) H H G² A190 CR^(B40) H H G² A191 CR^(B42) H H G² A192 CR^(B44) H H G² A193 CR^(B46) H H G² A194 CR^(B47) H H G² A195 CR^(B50) H H G² A196 CR^(B51) H H G² A197 CR^(B54) H H G² A198 CR^(B56) H H G² A199 CR^(B57) H H G² A200 CR^(B60) H H G² A201 CR^(B2) H H G³ A202 CR^(B4) H H G³ A203 CR^(B6) H H G³ A204 CR^(B8) H H G³ A205 CR^(B10) H H G³ A206 CR^(B12) H H G³ A207 CR^(B14) H H G³ A208 CR^(B16) H H G³ A209 CR^(B18) H H G³ A210 CR^(B20) H H G³ A211 CR^(B22) H H G³ A212 CR^(B24) H H G³ A213 CR^(B26) H H G³ A214 CR^(B27) H H G³ A215 CR^(B30) H H G³ A216 CR^(B32) H H G³ A217 CR^(B34) H H G³ A218 CR^(B36) H H G³ A219 CR^(B38) H H G³ A220 CR^(B40) H H G³ A221 CR^(B42) H H G³ A222 CR^(B44) H H G³ A223 CR^(B46) H H G³ A224 CR^(B47) H H G³ A225 CR^(B50) H H G³ A226 CR^(B51) H H G³ A227 CR^(B54) H H G³ A228 CR^(B56) H H G³ A229 CR^(B57) H H G³ A230 CR^(B60) H H G³ A231 CR^(B2) H H G⁴ A232 CR^(B4) H H G⁴ A233 CR^(B6) H H G⁴ A234 CR^(B8) H H G⁴ A235 CR^(B10) H H G⁴ A236 CR^(B12) H H G⁴ A237 CR^(B14) H H G⁴ A238 CR^(B16) H H G⁴ A239 CR^(B18) H H G⁴ A240 CR^(B20) H H G⁴ A241 CR^(B22) H H G⁴ A242 CR^(B24) H H G⁴ A243 CR^(B26) H H G⁴ A244 CR^(B28) H H G⁴ A245 CR^(B30) H H G⁴ A246 CR^(B32) H H G⁴ A247 CR^(B34) H H G⁴ A248 CR^(B36) H H G⁴ A249 CR^(B38) H H G⁴ A250 CR^(B40) H H G⁴ A251 CR^(B42) H H G⁴ A252 CR^(B44) H H G⁴ A253 CR^(B46) H H G⁴ A254 CR^(B47) H H G⁴ A255 CR^(B50) H H G⁴ A256 CR^(B52) H H G⁴ A257 CR^(B55) H H G⁴ A258 CR^(B57) H H G⁴ A259 CR^(B59) H H G⁴ A260 CR^(B1) H H G⁵ A261 CR^(B3) H H G⁵ A262 CR^(B5) H H G⁵ A263 CR^(B7) H H G⁵ A264 CR^(B9) H H G⁵ A265 CR^(B11) H H G⁵ A266 CR^(B13) H H G⁵ A267 CR^(B15) H H G⁵ A268 CR^(B17) H H G⁵ A269 CR^(B19) H H G⁵ A270 CR^(B21) H H G⁵ A271 CR^(B23) H H G⁵ A272 CR^(B25) H H G⁵ A273 CR^(B27) H H G⁵ A274 CR^(B29) H H G⁵ A275 CR^(B31) H H G⁵ A276 CR^(B33) H H G⁵ A277 CR^(B35) H H G⁵ A278 CR^(B37) H H G⁵ A279 CR^(B39) H H G⁵ A280 CR^(B41) H H G⁵ A281 CR^(B43) H H G⁵ A282 CR^(B45) H H G⁵ A283 CR^(B47) H H G⁵ A284 CR^(B49) H H G⁵ A285 CR^(B51) H H G⁵ A286 CR^(B53) H H G⁵ A287 CR^(B55) H H G⁵ A288 CR^(B57) H H G⁵ A289 CR^(B59) H H G⁵ A290 CR^(B1) H H G⁶ A291 CR^(B3) H H G⁶ A292 CR^(B5) H H G⁶ A293 CR^(B7) H H G⁶ A294 CR^(B9) H H G⁶ A295 CR^(B11) H H G⁶ A296 CR^(B13) H H G⁶ A297 CR^(B15) H H G⁶ A298 CR^(B17) H H G⁶ A299 CR^(B19) H H G⁶ A200 CR^(B21) H H G⁶ A301 CR^(B23) H H G⁶ A302 CR^(B25) H H G⁶ A303 CR^(B27) H H G⁶ A304 CR^(B29) H H G⁶ A305 CR^(B31) H H G⁶ A306 CR^(B33) H H G⁶ A307 CR^(B35) H H G⁶ A308 CR^(B37) H H G⁶ A309 CR^(B39) H H G⁶ A310 CR^(B41) H H G⁶ A311 CR^(B43) H H G⁶ A312 CR^(B45) H H G⁶ A313 CR^(B47) H H G⁶ A314 CR^(B49) H H G⁶ A315 CR^(B51) H H G⁶ A316 CR^(B53) H H G⁶ A317 CR^(B55) H H G⁶ A318 CR^(B57) H H G⁶ A319 CR^(B59) H H G⁶ A320 CR^(B56) H H G⁴ A321 CR^(B58) H H G⁴ A322 CR^(B60) H H G⁴ A323 CR^(B2) H H G⁵ A324 CR^(B4) H H G⁵ A325 CR^(B6) H H G⁵ A326 CR^(B8) H H G⁵ A327 CR^(B10) H H G⁵ A328 CR^(B12) H H G⁵ A329 CR^(B14) H H G⁵ A330 CR^(B16) H H G⁵ A331 CR^(B18) H H G⁵ A332 CR^(B20) H H G⁵ A333 CR^(B22) H H G⁵ A334 CR^(B24) H H G⁵ A335 CR^(B26) H H G⁵ A336 CR^(B28) H H G⁵ A337 CR^(B30) H H G⁵ A338 CR^(B32) H H G⁵ A339 CR^(B34) H H G⁵ A340 CR^(B36) H H G⁵ A341 CR^(B38) H H G⁵ A342 CR^(B40) H H G⁵ A343 CR^(B42) H H G⁵ A344 CR^(B44) H H G⁵ A345 CR^(B46) H H G⁵ A346 CR^(B48) H H G⁵ A347 CR^(B50) H H G⁵ A348 CR^(B52) H H G⁵ A349 CR^(B54) H H G⁵ A350 CR^(B56) H H G⁵ A351 CR^(B58) H H G⁵ A352 CR^(B60) H H G⁵ A353 CR^(B1) H H G⁶ A354 CR^(B4) H H G⁶ A355 CR^(B7) H H G⁶ A356 CR^(B10) H H G⁶ A357 CR^(B13) H H G⁶ A358 CR^(B16) H H G⁶ A359 CR^(B19) H H G⁶ A360 CR^(B22) H H G⁶ A361 CR^(B25) H H G⁶ A362 CR^(B28) H H G⁶ A363 CR^(B31) H H G⁶ A364 CR^(B34) H H G⁶ A365 CR^(B37) H H G⁶ A366 CR^(B40) H H G⁶ A367 CR^(B43) H H G⁶ A368 CR^(B46) H H G⁶ A369 CR^(B49) H H G⁶ A370 CR^(B52) H H G⁶ A371 CR^(B55) H H G⁶ A372 CR^(B58) H H G⁶ A373 CR^(B61) H H G⁶ A374 CR^(B64) H H G⁶ A375 CR^(B67) H H G⁶ A376 CR^(B70) H H G⁶ A377 CR^(B73) H H G⁶ A378 CR^(B76) H H G⁶ A379 CR^(B79) H H G⁶ A380 CR^(B82) H H G⁶ A381 CR^(B85) H H G⁶ A382 CR^(B88) H H G⁶ A383 CR^(B53) H H G⁴ A384 CR^(B54) H H G⁴

ligands L_(A385-O) to L_(A420-O), L_(A385-S) to L_(A420-S), and L_(A385-C) to L_(A420-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points of attachment to the corresponding points of attachment in the structure G, wherein for ligands L_(A385-O) to L_(A420-O), A in the structure G is O, wherein for ligands L_(A385-S) to L_(A420-S), A in the structure G is S, wherein for ligands L_(A385-C) to L_(A420-C), A in the structure G is C(CH₃)₂, wherein R⁶, R⁸, and G are defined for A385 to A420 as shown below: R⁶ R⁸ G A385 H H G¹³ A386 H H G¹⁵ A387 H H G¹⁷ A388 H H G¹⁹ A389 H H G²¹ A390 H H G²³ A391 CH₃ CH₃ G¹³ A392 CH₃ CH₃ G¹⁵ A393 CH₃ CH₃ G¹⁷ A394 CH₃ CH₃ G¹⁹ A395 CH₃ CH₃ G²¹ A396 CH₃ CH₃ G²³ A397 CH₃ CH₃ G¹³ A398 CH₃ CH₃ G¹⁵ A399 CH₃ CH₃ G¹⁷ A400 CH₃ CH₃ G¹⁹ A401 CH₃ CH₃ G²¹ A402 CH₃ CH₃ G²³ A403 H H G¹⁴ A404 H H G¹⁶ A405 H H G¹⁸ A406 H H G²⁰ A407 H H G²² A408 H H G²⁴ A409 CH₃ CH₃ G¹⁴ A410 CH₃ CH₃ G¹⁶ A411 CH₃ CH₃ G¹⁸ A412 CH₃ CH₃ G²⁰ A413 CH₃ CH₃ G²² A414 CH₃ CH₃ G²⁴ A415 CH₃ CH₃ G¹⁴ A416 CH₃ CH₃ G¹⁶ A417 CH₃ CH₃ G¹⁸ A418 CH₃ CH₃ G²⁰ A419 CH₃ CH₃ G²² A420 CH₃ CH₃ G²⁴

ligands L_(A421-O) to L_(A1152-O), L_(A421-S) to L_(A1152-S), and L_(A421-C) to L_(A1152-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points of attachment to the corresponding points of attachment in the structure G, wherein for ligands L_(A421-O) to L_(A1152-O), A in the structure G is O, wherein for ligands L_(A421-S) to L_(A1152-S), A in the structure G is S, and wherein for ligands L_(A421-C) to L_(A1152-C), A in the structure G is C(CH₃)₂, wherein R², R³, and G are defined for A421 to A1152 as shown below: R² R³ G A421 H H G³⁷ A422 H H G³⁹ A423 H H G⁴¹ A424 H H G⁴³ A425 H H G⁴⁵ A426 H H G⁴⁷ A427 CH₃ R^(B1) G³⁷ A428 CH₃ R^(B3) G³⁷ A429 CH₃ R^(B5) G³⁷ A430 CH₃ R^(B7) G³⁷ A431 CH₃ R^(B9) G³⁷ A432 CH₃ R^(B11) G³⁷ A433 CH₃ R^(B13) G³⁷ A434 CH₃ R^(B15) G³⁷ A435 CH₃ R^(B17) G³⁷ A436 CH₃ R^(B19) G³⁷ A437 CH₃ R^(B21) G³⁷ A438 CH₃ R^(B23) G³⁷ A439 CH₃ R^(B25) G³⁷ A440 CH₃ R^(B27) G³⁷ A441 CH₃ R^(B29) G³⁷ A442 CH₃ R^(B31) G³⁷ A443 CH₃ R^(B33) G³⁷ A444 CH₃ R^(B35) G³⁷ A445 CH₃ R^(B37) G³⁷ A446 CH₃ R^(B39) G³⁷ A447 CH₃ R^(B41) G³⁷ A448 CH₃ R^(B43) G³⁷ A449 CH₃ R^(B45) G³⁷ A450 CH₃ R^(B47) G³⁷ A451 CH₃ R^(B49) G³⁷ A452 CH₃ R^(B51) G³⁷ A453 CH₃ R^(B53) G³⁷ A454 CH₃ R^(B55) G³⁷ A455 CH₃ R^(B57) G³⁷ A456 CH₃ R^(B59) G³⁷ A457 R^(B1) CH₃ G³⁷ A458 R^(B3) CH₃ G³⁷ A459 R^(B5) CH₃ G³⁷ A460 R^(B7) CH₃ G³⁷ A461 R^(B9) CH₃ G³⁷ A462 R^(B11) CH₃ G³⁷ A463 R^(B13) CH₃ G³⁷ A464 R^(B15) CH₃ G³⁷ A465 R^(B17) CH₃ G³⁷ A466 R^(B19) CH₃ G³⁷ A467 R^(B21) CH₃ G³⁷ A468 R^(B23) CH₃ G³⁷ A469 R^(B25) CH₃ G³⁷ A470 R^(B27) CH₃ G³⁷ A471 R^(B29) CH₃ G³⁷ A472 R^(B31) CH₃ G³⁷ A473 R^(B33) CH₃ G³⁷ A474 R^(B35) CH₃ G³⁷ A475 R^(B37) CH₃ G³⁷ A476 R^(B39) CH₃ G³⁷ A477 R^(B41) CH₃ G³⁷ A478 R^(B43) CH₃ G³⁷ A479 R^(B45) CH₃ G³⁷ A480 R^(B47) CH₃ G³⁷ A481 R^(B49) CH₃ G³⁷ A482 R^(B51) CH₃ G³⁷ A483 R^(B53) CH₃ G³⁷ A484 R^(B55) CH₃ G³⁷ A485 R^(B57) CH₃ G³⁷ A486 R^(B59) CH₃ G³⁷ A487 CH₃ R^(B1) G³⁸ A488 CH₃ R^(B3) G³⁸ A489 CH₃ R^(B5) G³⁸ A490 CH₃ R^(B7) G³⁸ A491 CH₃ R^(B9) G³⁸ A492 CH₃ R^(B11) G³⁸ A493 CH₃ R^(B13) G³⁸ A494 CH₃ R^(B15) G³⁸ A495 CH₃ R^(B17) G³⁸ A496 CH₃ R^(B19) G³⁸ A497 CH₃ R^(B21) G³⁸ A498 CH₃ R^(B23) G³⁸ A499 CH₃ R^(B25) G³⁸ A500 CH₃ R^(B27) G³⁸ A501 CH₃ R^(B29) G³⁸ A502 CH₃ R^(B31) G³⁸ A503 CH₃ R^(B33) G³⁸ A504 CH₃ R^(B35) G³⁸ A505 CH₃ R^(B37) G³⁸ A506 CH₃ R^(B39) G³⁸ A507 CH₃ R^(B41) G³⁸ A508 CH₃ R^(B43) G³⁸ A509 CH₃ R^(B45) G³⁸ A510 CH₃ R^(B47) G³⁸ A511 CH₃ R^(B49) G³⁸ A512 CH₃ R^(B51) G³⁸ A513 CH₃ R^(B53) G³⁸ A514 CH₃ R^(B55) G³⁸ A515 CH₃ R^(B57) G³⁸ A516 CH₃ R^(B59) G³⁸ A517 R^(B1) CH₃ G³⁸ A518 R^(B3) CH₃ G³⁸ A519 R^(B5) CH₃ G³⁸ A520 R^(B7) CH₃ G³⁸ A521 R^(B9) CH₃ G³⁸ A522 R^(B11) CH₃ G³⁸ A523 R^(B13) CH₃ G³⁸ A524 R^(B15) CH₃ G³⁸ A525 R^(B17) CH₃ G³⁸ A526 R^(B19) CH₃ G³⁸ A527 R^(B21) CH₃ G³⁸ A528 R^(B23) CH₃ G³⁸ A529 R^(B25) CH₃ G³⁸ A530 R^(B27) CH₃ G³⁸ A531 R^(B29) CH₃ G³⁸ A532 R^(B31) CH₃ G³⁸ A533 R^(B33) CH₃ G³⁸ A534 R^(B35) CH₃ G³⁸ A535 R^(B37) CH₃ G³⁸ A536 R^(B39) CH₃ G³⁸ A537 R^(B41) CH₃ G³⁸ A538 R^(B43) CH₃ G³⁸ A539 R^(B45) CH₃ G³⁸ A540 R^(B47) CH₃ G³⁸ A541 R^(B49) CH₃ G³⁸ A542 R^(B51) CH₃ G³⁸ A543 R^(B53) CH₃ G³⁸ A544 R^(B55) CH₃ G³⁸ A545 R^(B57) CH₃ G³⁸ A546 R^(B59) CH₃ G³⁸ A547 CH₃ R^(B1) G³⁹ A548 CH₃ R^(B3) G³⁹ A549 CH₃ R^(B5) G³⁹ A550 CH₃ R^(B7) G³⁹ A551 CH₃ R^(B9) G³⁹ A552 CH₃ R^(B11) G³⁹ A553 CH₃ R^(B13) G³⁹ A554 CH₃ R^(B15) G³⁹ A555 CH₃ R^(B17) G³⁹ A556 CH₃ R^(B19) G³⁹ A557 CH₃ R^(B21) G³⁹ A558 CH₃ R^(B23) G³⁹ A559 CH₃ R^(B25) G³⁹ A560 CH₃ R^(B27) G³⁹ A561 CH₃ R^(B29) G³⁹ A562 CH₃ R^(B31) G³⁹ A563 CH₃ R^(B33) G³⁹ A564 CH₃ R^(B35) G³⁹ A565 CH₃ R^(B37) G³⁹ A566 CH₃ R^(B39) G³⁹ A567 CH₃ R^(B41) G³⁹ A568 CH₃ R^(B43) G³⁹ A569 CH₃ R^(B45) G³⁹ A570 CH₃ R^(B47) G³⁹ A571 CH₃ R^(B49) G³⁹ A572 CH₃ R^(B51) G³⁹ A573 CH₃ R^(B53) G³⁹ A574 CH₃ R^(B55) G³⁹ A575 CH₃ R^(B57) G³⁹ A576 CH₃ R^(B59) G³⁹ A577 R^(B1) CH₃ G³⁹ A578 R^(B3) CH₃ G³⁹ A579 R^(B5) CH₃ G³⁹ A580 R^(B7) CH₃ G³⁹ A581 R^(B9) CH₃ G³⁹ A582 R^(B11) CH₃ G³⁹ A583 R^(B13) CH₃ G³⁹ A584 R^(B15) CH₃ G³⁹ A585 R^(B17) CH₃ G³⁹ A586 R^(B19) CH₃ G³⁹ A587 R^(B21) CH₃ G³⁹ A588 R^(B23) CH₃ G³⁹ A589 R^(B25) CH₃ G³⁹ A590 R^(B27) CH₃ G³⁹ A591 R^(B29) CH₃ G³⁹ A592 R^(B31) CH₃ G³⁹ A593 R^(B33) CH₃ G³⁹ A594 R^(B35) CH₃ G³⁹ A595 R^(B37) CH₃ G³⁹ A596 R^(B39) CH₃ G³⁹ A597 R^(B41) CH₃ G³⁹ A598 R^(B43) CH₃ G³⁹ A599 R^(B45) CH₃ G³⁹ A600 R^(B47) CH₃ G³⁹ A601 R^(B49) CH₃ G³⁹ A602 R^(B51) CH₃ G³⁹ A603 R^(B53) CH₃ G³⁹ A604 R^(B55) CH₃ G³⁹ A605 R^(B57) CH₃ G³⁹ A606 R^(B59) CH₃ G³⁹ A607 CH₃ R^(B1) G⁴⁰ A608 CH₃ R^(B3) G⁴⁰ A609 CH₃ R^(B5) G⁴⁰ A610 CH₃ R^(B7) G⁴⁰ A611 CH₃ R^(B9) G⁴⁰ A612 CH₃ R^(B11) G⁴⁰ A613 CH₃ R^(B13) G⁴⁰ A614 CH₃ R^(B15) G⁴⁰ A615 CH₃ R^(B17) G⁴⁰ A616 CH₃ R^(B19) G⁴⁰ A617 CH₃ R^(B21) G⁴⁰ A618 CH₃ R^(B23) G⁴⁰ A619 CH₃ R^(B25) G⁴⁰ A620 CH₃ R^(B27) G⁴⁰ A621 CH₃ R^(B29) G⁴⁰ A622 CH₃ R^(B31) G⁴⁰ A623 CH₃ R^(B33) G⁴⁰ A624 CH₃ R^(B35) G⁴⁰ A625 CH₃ R^(B37) G⁴⁰ A626 CH₃ R^(B39) G⁴⁰ A627 CH₃ R^(B41) G⁴⁰ A628 CH₃ R^(B43) G⁴⁰ A629 CH₃ R^(B45) G⁴⁰ A630 CH₃ R^(B47) G⁴⁰ A631 CH₃ R^(B49) G⁴⁰ A632 CH₃ R^(B51) G⁴⁰ A633 CH₃ R^(B53) G⁴⁰ A634 CH₃ R^(B55) G⁴⁰ A635 CH₃ R^(B57) G⁴⁰ A636 CH₃ R^(B59) G⁴⁰ A637 R^(B1) CH₃ G⁴⁰ A638 R^(B3) CH₃ G⁴⁰ A639 R^(B5) CH₃ G⁴⁰ A640 R^(B7) CH₃ G⁴⁰ A641 R^(B9) CH₃ G⁴⁰ A642 R^(B11) CH₃ G⁴⁰ A643 R^(B13) CH₃ G⁴⁰ A644 R^(B15) CH₃ G⁴⁰ A645 R^(B17) CH₃ G⁴⁰ A646 R^(B19) CH₃ G⁴⁰ A647 R^(B21) CH₃ G⁴⁰ A648 R^(B23) CH₃ G⁴⁰ A649 R^(B25) CH₃ G⁴⁰ A650 R^(B27) CH₃ G⁴⁰ A651 R^(B29) CH₃ G⁴⁰ A652 R^(B31) CH₃ G⁴⁰ A653 R^(B33) CH₃ G⁴⁰ A654 R^(B35) CH₃ G⁴⁰ A655 R^(B37) CH₃ G⁴⁰ A656 R^(B39) CH₃ G⁴⁰ A657 R^(B41) CH₃ G⁴⁰ A658 R^(B43) CH₃ G⁴⁰ A659 R^(B45) CH₃ G⁴⁰ A660 R^(B47) CH₃ G⁴⁰ A661 R^(B49) CH₃ G⁴⁰ A662 R^(B51) CH₃ G⁴⁰ A663 R^(B53) CH₃ G⁴⁰ A664 R^(B55) CH₃ G⁴⁰ A665 H H G³⁸ A666 H H G⁴⁰ A667 H H G⁴² A668 H H G⁴⁴ A669 H H G⁴⁶ A670 H H G⁴⁸ A671 CH₃ R^(B2) G³⁷ A672 CH₃ R^(B4) G³⁷ A673 CH₃ R^(B6) G³⁷ A674 CH₃ R^(B8) G³⁷ A675 CH₃ R^(B10) G³⁷ A676 CH₃ R^(B12) G³⁷ A677 CH₃ R^(B14) G³⁷ A678 CH₃ R^(B16) G³⁷ A679 CH₃ R^(B18) G³⁷ A680 CH₃ R^(B20) G³⁷ A681 CH₃ R^(B22) G³⁷ A682 CH₃ R^(B24) G³⁷ A683 CH₃ R^(B26) G³⁷ A684 CH₃ R^(B28) G³⁷ A685 CH₃ R^(B30) G³⁷ A686 CH₃ R^(B32) G³⁷ A687 CH₃ R^(B34) G³⁷ A688 CH₃ R^(B36) G³⁷ A689 CH₃ R^(B38) G³⁷ A690 CH₃ R^(B40) G³⁷ A691 CH₃ R^(B42) G³⁷ A692 CH₃ R^(B44) G³⁷ A693 CH₃ R^(B46) G³⁷ A694 CH₃ R^(B48) G³⁷ A695 CH₃ R^(B50) G³⁷ A696 CH₃ R^(B52) G³⁷ A697 CH₃ R^(B54) G³⁷ A698 CH₃ R^(B56) G³⁷ A699 CH₃ R^(B58) G³⁷ A700 CH₃ R^(B60) G³⁷ A701 R^(B2) CH₃ G³⁷ A702 R^(B4) CH₃ G³⁷ A703 R^(B6) CH₃ G³⁷ A704 R^(B8) CH₃ G³⁷ A705 R^(B10) CH₃ G³⁷ A706 R^(B12) CH₃ G³⁷ A707 R^(B14) CH₃ G³⁷ A708 R^(B16) CH₃ G³⁷ A709 R^(B18) CH₃ G³⁷ A710 R^(B20) CH₃ G³⁷ A711 R^(B22) CH₃ G³⁷ A712 R^(B24) CH₃ G³⁷ A713 R^(B26) CH₃ G³⁷ A714 R^(B28) CH₃ G³⁷ A715 R^(B30) CH₃ G³⁷ A716 R^(B32) CH₃ G³⁷ A717 R^(B34) CH₃ G³⁷ A718 R^(B36) CH₃ G³⁷ A719 R^(B38) CH₃ G³⁷ A720 R^(B40) CH₃ G³⁷ A721 R^(B42) CH₃ G³⁷ A722 R^(B44) CH₃ G³⁷ A723 R^(B46) CH₃ G³⁷ A724 R^(B48) CH₃ G³⁷ A725 R^(B50) CH₃ G³⁷ A726 R^(B52) CH₃ G³⁷ A727 R^(B54) CH₃ G³⁷ A728 R^(B56) CH₃ G³⁷ A729 R^(B58) CH₃ G³⁷ A730 R^(B60) CH₃ G³⁷ A731 CH₃ R^(B2) G³⁸ A732 CH₃ R^(B4) G³⁸ A733 CH₃ R^(B6) G³⁸ A734 CH₃ R^(B8) G³⁸ A735 CH₃ R^(B10) G³⁸ A736 CH₃ R^(B12) G³⁸ A737 CH₃ R^(B14) G³⁸ A738 CH₃ R^(B16) G³⁸ A739 CH₃ R^(B18) G³⁸ A740 CH₃ R^(B20) G³⁸ A741 CH₃ R^(B22) G³⁸ A742 CH₃ R^(B24) G³⁸ A743 CH₃ R^(B26) G³⁸ A744 CH₃ R^(B28) G³⁸ A745 CH₃ R^(B30) G³⁸ A746 CH₃ R^(B32) G³⁸ A747 CH₃ R^(B34) G³⁸ A748 CH₃ R^(B36) G³⁸ A749 CH₃ R^(B38) G³⁸ A750 CH₃ R^(B40) G³⁸ A751 CH₃ R^(B42) G³⁸ A752 CH₃ R^(B44) G³⁸ A753 CH₃ R^(B46) G³⁸ A754 CH₃ R^(B48) G³⁸ A755 CH₃ R^(B50) G³⁸ A756 CH₃ R^(B52) G³⁸ A757 CH₃ R^(B54) G³⁸ A758 CH₃ R^(B56) G³⁸ A759 CH₃ R^(B58) G³⁸ A760 CH₃ R^(B60) G³⁸ A761 R^(B2) CH₃ G³⁸ A762 R^(B4) CH₃ G³⁸ A763 R^(B6) CH₃ G³⁸ A764 R^(B8) CH₃ G³⁸ A765 R^(B10) CH₃ G³⁸ A766 R^(B12) CH₃ G³⁸ A767 R^(B14) CH₃ G³⁸ A768 R^(B16) CH₃ G³⁸ A769 R^(B18) CH₃ G³⁸ A770 R^(B20) CH₃ G³⁸ A771 R^(B22) CH₃ G³⁸ A772 R^(B24) CH₃ G³⁸ A773 R^(B26) CH₃ G³⁸ A774 R^(B28) CH₃ G³⁸ A775 R^(B30) CH₃ G³⁸ A776 R^(B32) CH₃ G³⁸ A777 R^(B34) CH₃ G³⁸ A778 R^(B36) CH₃ G³⁸ A779 R^(B38) CH₃ G³⁸ A780 R^(B40) CH₃ G³⁸ A781 R^(B42) CH₃ G³⁸ A782 R^(B44) CH₃ G³⁸ A783 R^(B46) CH₃ G³⁸ A784 R^(B48) CH₃ G³⁸ A785 R^(B50) CH₃ G³⁸ A786 R^(B52) CH₃ G³⁸ A787 R^(B54) CH₃ G³⁸ A788 R^(B56) CH₃ G³⁸ A789 R^(B58) CH₃ G³⁸ A790 R^(B60) CH₃ G³⁸ A791 CH₃ R^(B2) G³⁹ A792 CH₃ R^(B4) G³⁹ A793 CH₃ R^(B6) G³⁹ A794 CH₃ R^(B8) G³⁹ A795 CH₃ R^(B10) G³⁹ A796 CH₃ R^(B12) G³⁹ A797 CH₃ R^(B14) G³⁹ A798 CH₃ R^(B16) G³⁹ A799 CH₃ R^(B18) G³⁹ A800 CH₃ R^(B20) G³⁹ A801 CH₃ R^(B22) G³⁹ A802 CH₃ R^(B24) G³⁹ A803 CH₃ R^(B26) G³⁹ A804 CH₃ R^(B28) G³⁹ A805 CH₃ R^(B30) G³⁹ A806 CH₃ R^(B32) G³⁹ A807 CH₃ R^(B34) G³⁹ A808 CH₃ R^(B36) G³⁹ A809 CH₃ R^(B38) G³⁹ A810 CH₃ R^(B40) G³⁹ A811 CH₃ R^(B42) G³⁹ A812 CH₃ R^(B44) G³⁹ A813 CH₃ R^(B46) G³⁹ A814 CH₃ R^(B48) G³⁹ A815 CH₃ R^(B50) G³⁹ A816 CH₃ R^(B52) G³⁹ A817 CH₃ R^(B54) G³⁹ A818 CH₃ R^(B56) G³⁹ A819 CH₃ R^(B58) G³⁹ A820 CH₃ R^(B60) G³⁹ A821 R^(B2) CH₃ G³⁹ A822 R^(B4) CH₃ G³⁹ A823 R^(B6) CH₃ G³⁹ A824 R^(B8) CH₃ G³⁹ A825 R^(B10) CH₃ G³⁹ A826 R^(B12) CH₃ G³⁹ A827 R^(B14) CH₃ G³⁹ A828 R^(B16) CH₃ G³⁹ A829 R^(B18) CH₃ G³⁹ A830 R^(B20) CH₃ G³⁹ A831 R^(B22) CH₃ G³⁹ A832 R^(B24) CH₃ G³⁹ A833 R^(B26) CH₃ G³⁹ A834 R^(B28) CH₃ G³⁹ A835 R^(B30) CH₃ G³⁹ A836 R^(B32) CH₃ G³⁹ A837 R^(B34) CH₃ G³⁹ A838 R^(B36) CH₃ G³⁹ A839 R^(B38) CH₃ G³⁹ A840 R^(B40) CH₃ G³⁹ A841 R^(B42) CH₃ G³⁹ A842 R^(B44) CH₃ G³⁹ A843 R^(B46) CH₃ G³⁹ A844 R^(B48) CH₃ G³⁹ A845 R^(B50) CH₃ G³⁹ A846 R^(B52) CH₃ G³⁹ A847 R^(B54) CH₃ G³⁹ A848 R^(B56) CH₃ G³⁹ A849 R^(B58) CH₃ G³⁹ A850 R^(B60) CH₃ G³⁹ A851 CH₃ R^(B2) G⁴⁰ A852 CH₃ R^(B4) G⁴⁰ A853 CH₃ R^(B6) G⁴⁰ A854 CH₃ R^(B8) G⁴⁰ A855 CH₃ R^(B10) G⁴⁰ A856 CH₃ R^(B12) G⁴⁰ A857 CH₃ R^(B14) G⁴⁰ A858 CH₃ R^(B16) G⁴⁰ A859 CH₃ R^(B18) G⁴⁰ A860 CH₃ R^(B20) G⁴⁰ A861 CH₃ R^(B22) G⁴⁰ A862 CH₃ R^(B24) G⁴⁰ A863 CH₃ R^(B26) G⁴⁰ A864 CH₃ R^(B28) G⁴⁰ A865 CH₃ R^(B30) G⁴⁰ A866 CH₃ R^(B32) G⁴⁰ A867 CH₃ R^(B34) G⁴⁰ A868 CH₃ R^(B36) G⁴⁰ A869 CH₃ R^(B38) G⁴⁰ A870 CH₃ R^(B40) G⁴⁰ A871 CH₃ R^(B42) G⁴⁰ A872 CH₃ R^(B44) G⁴⁰ A873 CH₃ R^(B46) G⁴⁰ A874 CH₃ R^(B48) G⁴⁰ A875 CH₃ R^(B50) G⁴⁰ A876 CH₃ R^(B52) G⁴⁰ A877 CH₃ R^(B54) G⁴⁰ A878 CH₃ R^(B56) G⁴⁰ A879 CH₃ R^(B58) G⁴⁰ A880 CH₃ R^(B60) G⁴⁰ A881 R^(B2) CH₃ G⁴⁰ A882 R^(B4) CH₃ G⁴⁰ A883 R^(B6) CH₃ G⁴⁰ A884 R^(B8) CH₃ G⁴⁰ A885 R^(B10) CH₃ G⁴⁰ A886 R^(B12) CH₃ G⁴⁰ A887 R^(B14) CH₃ G⁴⁰ A888 R^(B16) CH₃ G⁴⁰ A889 R^(B18) CH₃ G⁴⁰ A890 R^(B20) CH₃ G⁴⁰ A891 R^(B22) CH₃ G⁴⁰ A892 R^(B24) CH₃ G⁴⁰ A893 R^(B26) CH₃ G⁴⁰ A894 R^(B28) CH₃ G⁴⁰ A895 R^(B30) CH₃ G⁴⁰ A896 R^(B32) CH₃ G⁴⁰ A897 R^(B34) CH₃ G⁴⁰ A898 R^(B36) CH₃ G⁴⁰ A899 R^(B38) CH₃ G⁴⁰ A900 R^(B40) CH₃ G⁴⁰ A901 R^(B42) CH₃ G⁴⁰ A902 R^(B44) CH₃ G⁴⁰ A903 R^(B46) CH₃ G⁴⁰ A904 R^(B48) CH₃ G⁴⁰ A905 R^(B50) CH₃ G⁴⁰ A906 R^(B52) CH₃ G⁴⁰ A907 R^(B54) CH₃ G⁴⁰ A908 R^(B56) CH₃ G⁴⁰ A909 R^(B57) CH₃ G⁴⁰ A910 R^(B59) CH₃ G⁴⁰ A911 CH₃ R^(B1) G⁴¹ A912 CH₃ R^(B3) G⁴¹ A913 CH₃ R^(B5) G⁴¹ A914 CH₃ R^(B7) G⁴¹ A915 CH₃ R^(B9) G⁴¹ A916 CH₃ R^(B11) G⁴¹ A917 CH₃ R^(B13) G⁴¹ A918 CH₃ R^(B15) G⁴¹ A919 CH₃ R^(B17) G⁴¹ A920 CH₃ R^(B19) G⁴¹ A921 CH₃ R^(B21) G⁴¹ A922 CH₃ R^(B23) G⁴¹ A923 CH₃ R^(B25) G⁴¹ A924 CH₃ R^(B27) G⁴¹ A925 CH₃ R^(B29) G⁴¹ A926 CH₃ R^(B31) G⁴¹ A927 CH₃ R^(B33) G⁴¹ A928 CH₃ R^(B35) G⁴¹ A929 CH₃ R^(B37) G⁴¹ A930 CH₃ R^(B39) G⁴¹ A931 CH₃ R^(B41) G⁴¹ A932 CH₃ R^(B43) G⁴¹ A933 CH₃ R^(B45) G⁴¹ A934 CH₃ R^(B47) G⁴¹ A935 CH₃ R^(B49) G⁴¹ A936 CH₃ R^(B51) G⁴¹ A937 CH₃ R^(B53) G⁴¹ A938 CH₃ R^(B55) G⁴¹ A939 CH₃ R^(B57) G⁴¹ A940 CH₃ R^(B59) G⁴¹ A941 R^(B1) CH₃ G⁴¹ A942 R^(B3) CH₃ G⁴¹ A943 R^(B5) CH₃ G⁴¹ A944 R^(B7) CH₃ G⁴¹ A945 R^(B9) CH₃ G⁴¹ A946 R^(B11) CH₃ G⁴¹ A947 R^(B13) CH₃ G⁴¹ A948 R^(B15) CH₃ G⁴¹ A949 R^(B17) CH₃ G⁴¹ A950 R^(B19) CH₃ G⁴¹ A951 R^(B21) CH₃ G⁴¹ A952 R^(B23) CH₃ G⁴¹ A953 R^(B25) CH₃ G⁴¹ A954 R^(B27) CH₃ G⁴¹ A955 R^(B29) CH₃ G⁴¹ A956 R^(B31) CH₃ G⁴¹ A957 R^(B33) CH₃ G⁴¹ A958 R^(B35) CH₃ G⁴¹ A959 R^(B37) CH₃ G⁴¹ A960 R^(B39) CH₃ G⁴¹ A961 R^(B41) CH₃ G⁴¹ A962 R^(B43) CH₃ G⁴¹ A963 R^(B45) CH₃ G⁴¹ A964 R^(B47) CH₃ G⁴¹ A965 R^(B49) CH₃ G⁴¹ A966 R^(B51) CH₃ G⁴¹ A967 R^(B53) CH₃ G⁴¹ A968 R^(B55) CH₃ G⁴¹ A969 R^(B57) CH₃ G⁴¹ A970 R^(B59) CH₃ G⁴¹ A971 CH₃ R^(B1) G⁴² A972 CH₃ R^(B3) G⁴² A973 CH₃ R^(B5) G⁴² A974 CH₃ R^(B7) G⁴² A975 CH₃ R^(B9) G⁴² A976 CH₃ R^(B11) G⁴² A977 CH₃ R^(B13) G⁴² A978 CH₃ R^(B15) G⁴² A979 CH₃ R^(B17) G⁴² A980 CH₃ R^(B19) G⁴² A981 CH₃ R^(B21) G⁴² A982 CH₃ R^(B23) G⁴² A983 CH₃ R^(B25) G⁴² A984 CH₃ R^(B27) G⁴² A985 CH₃ R^(B29) G⁴² A986 CH₃ R^(B31) G⁴² A987 CH₃ R^(B33) G⁴² A988 CH₃ R^(B35) G⁴² A989 CH₃ R^(B37) G⁴² A990 CH₃ R^(B39) G⁴² A991 CH₃ R^(B41) G⁴² A992 CH₃ R^(B43) G⁴² A993 CH₃ R^(B45) G⁴² A994 CH₃ R^(B47) G⁴² A995 CH₃ R^(B49) G⁴² A996 CH₃ R^(B51) G⁴² A997 CH₃ R^(B53) G⁴² A998 CH₃ R^(B55) G⁴² A999 CH₃ R^(B57) G⁴² A1000 CH₃ R^(B59) G⁴² A1001 R^(B1) CH₃ G⁴² A1002 R^(B3) CH₃ G⁴² A1003 R^(B5) CH₃ G⁴² A1004 R^(B7) CH₃ G⁴² A1005 R^(B9) CH₃ G⁴² A1006 R^(B11) CH₃ G⁴² A1007 R^(B13) CH₃ G⁴² A1008 R^(B15) CH₃ G⁴² A1009 R^(B17) CH₃ G⁴² A1010 R^(B19) CH₃ G⁴² A1011 R^(B21) CH₃ G⁴² A1012 R^(B23) CH₃ G⁴² A1013 R^(B25) CH₃ G⁴² A1014 R^(B27) CH₃ G⁴² A1015 R^(B29) CH₃ G⁴² A1016 R^(B31) CH₃ G⁴² A1017 R^(B33) CH₃ G⁴² A1018 R^(B35) CH₃ G⁴² A1019 R^(B37) CH₃ G⁴² A1020 R^(B39) CH₃ G⁴² A1021 R^(B41) CH₃ G⁴² A1022 R^(B43) CH₃ G⁴² A1023 R^(B45) CH₃ G⁴² A1024 R^(B47) CH₃ G⁴² A1025 R^(B49) CH₃ G⁴² A1026 R^(B51) CH₃ G⁴² A1027 R^(B53) CH₃ G⁴² A1028 R^(B55) CH₃ G⁴² A1029 R^(B57) CH₃ G⁴² A1030 R^(B59) CH₃ G⁴² A1031 R^(B58) CH₃ G⁴⁰ A1032 R^(B60) CH₃ G⁴⁰ A1033 CH₃ R^(B2) G⁴¹ A1034 CH₃ R^(B4) G⁴¹ A1035 CH₃ R^(B6) G⁴¹ A1036 CH₃ R^(B8) G⁴¹ A1037 CH₃ R^(B10) G⁴¹ A1038 CH₃ R^(B12) G⁴¹ A1039 CH₃ R^(B14) G⁴¹ A1040 CH₃ R^(B16) G⁴¹ A1041 CH₃ R^(B18) G⁴¹ A1042 CH₃ R^(B20) G⁴¹ A1043 CH₃ R^(B22) G⁴¹ A1044 CH₃ R^(B24) G⁴¹ A1045 CH₃ R^(B26) G⁴¹ A1046 CH₃ R^(B28) G⁴¹ A1047 CH₃ R^(B30) G⁴¹ A1048 CH₃ R^(B32) G⁴¹ A1049 CH₃ R^(B34) G⁴¹ A1050 CH₃ R^(B36) G⁴¹ A1051 CH₃ R^(B38) G⁴¹ A1052 CH₃ R^(B40) G⁴¹ A1053 CH₃ R^(B42) G⁴¹ A1054 CH₃ R^(B44) G⁴¹ A1055 CH₃ R^(B46) G⁴¹ A1056 CH₃ R^(B48) G⁴¹ A1057 CH₃ R^(B50) G⁴¹ A1058 CH₃ R^(B52) G⁴¹ A1059 CH₃ R^(B54) G⁴¹ A1060 CH₃ R^(B56) G⁴¹ A1061 CH₃ R^(B58) G⁴¹ A1062 CH₃ R^(B60) G⁴¹ A1063 R^(B2) CH₃ G⁴¹ A1064 R^(B4) CH₃ G⁴¹ A1065 R^(B6) CH₃ G⁴¹ A1066 R^(B8) CH₃ G⁴¹ A1067 R^(B10) CH₃ G⁴¹ A1068 R^(B12) CH₃ G⁴¹ A1069 R^(B14) CH₃ G⁴¹ A1070 R^(B16) CH₃ G⁴¹ A1071 R^(B18) CH₃ G⁴¹ A1072 R^(B20) CH₃ G⁴¹ A1073 R^(B22) CH₃ G⁴¹ A1074 R^(B24) CH₃ G⁴¹ A1075 R^(B26) CH₃ G⁴¹ A1076 R^(B28) CH₃ G⁴¹ A1077 R^(B30) CH₃ G⁴¹ A1078 R^(B32) CH₃ G⁴¹ A1079 R^(B34) CH₃ G⁴¹ A1080 R^(B36) CH₃ G⁴¹ A1081 R^(B38) CH₃ G⁴¹ A1082 R^(B40) CH₃ G⁴¹ A1083 R^(B42) CH₃ G⁴¹ A1084 R^(B44) CH₃ G⁴¹ A1085 R^(B46) CH₃ G⁴¹ A1086 R^(B48) CH₃ G⁴¹ A1087 R^(B50) CH₃ G⁴¹ A1088 R^(B52) CH₃ G⁴¹ A1089 R^(B54) CH₃ G⁴¹ A1090 R^(B56) CH₃ G⁴¹ A1091 R^(B58) CH₃ G⁴¹ A1092 R^(B60) CH₃ G⁴¹ A1093 CH₃ R^(B2) G⁴² A1094 CH₃ R^(B4) G⁴² A1095 CH₃ R^(B6) G⁴² A1096 CH₃ R^(B8) G⁴² A1097 CH₃ R^(B10) G⁴² A1098 CH₃ R^(B12) G⁴² A1099 CH₃ R^(B14) G⁴² A1100 CH₃ R^(B16) G⁴² A1101 CH₃ R^(B18) G⁴² A1102 CH₃ R^(B20) G⁴² A1103 CH₃ R^(B22) G⁴² A1104 CH₃ R^(B24) G⁴² A1105 CH₃ R^(B26) G⁴² A1106 CH₃ R^(B28) G⁴² A1107 CH₃ R^(B30) G⁴² A1108 CH₃ R^(B32) G⁴² A1109 CH₃ R^(B34) G⁴² A1110 CH₃ R^(B36) G⁴² A1111 CH₃ R^(B38) G⁴² A1112 CH₃ R^(B40) G⁴² A1113 CH₃ R^(B42) G⁴² A1114 CH₃ R^(B44) G⁴² A1115 CH₃ R^(B46) G⁴² A1116 CH₃ R^(B48) G⁴² A1117 CH₃ R^(B50) G⁴² A1118 CH₃ R^(B52) G⁴² A1119 CH₃ R^(B54) G⁴² A1120 CH₃ R^(B56) G⁴² A1121 CH₃ R^(B58) G⁴² A1122 CH₃ R^(B60) G⁴² A1123 R^(B2) CH₃ G⁴² A1124 R^(B4) CH₃ G⁴² A1125 R^(B6) CH₃ G⁴² A1126 R^(B8) CH₃ G⁴² A1127 R^(B10) CH₃ G⁴² A1128 R^(B12) CH₃ G⁴² A1129 R^(B14) CH₃ G⁴² A1130 R^(B16) CH₃ G⁴² A1131 R^(B18) CH₃ G⁴² A1132 R^(B20) CH₃ G⁴² A1133 R^(B22) CH₃ G⁴² A1134 R^(B24) CH₃ G⁴² A1135 R^(B26) CH₃ G⁴² A1136 R^(B28) CH₃ G⁴² A1137 R^(B30) CH₃ G⁴² A1138 R^(B32) CH₃ G⁴² A1139 R^(B34) CH₃ G⁴² A1140 R^(B36) CH₃ G⁴² A1141 R^(B38) CH₃ G⁴² A1142 R^(B40) CH₃ G⁴² A1143 R^(B42) CH₃ G⁴² A1144 R^(B44) CH₃ G⁴² A1145 R^(B46) CH₃ G⁴² A1146 R^(B48) CH₃ G⁴² A1147 R^(B50) CH₃ G⁴² A1148 R^(B52) CH₃ G⁴² A1149 R^(B54) CH₃ G⁴² A1150 R^(B56) CH₃ G⁴² A1151 R^(B58) CH₃ G⁴² A1152 R^(B60) CH₃ G⁴²

ligands L_(A1153-O) to L_(A1764-O), L_(A1153-S) to L_(A1764-S), L_(A1153-C) to L_(A1764-C) that are based on the structure

wherein the asterisks with an Arabic numeral indicate the points of attachment to the corresponding points of attachment in the structure G, wherein for ligands L_(A1153-O) to L_(A1764-O), A in the structure G is O, wherein for ligands L_(A1153-S) to L_(A1764-S), A in the structure G is S, and wherein for ligands L_(A1153-C) to L_(A1764-C), A in the structure G is C(CH₃)₂, wherein R², R³, and G are defined for A1153 to A1764 as shown below: R² R³ G A1153 H H G³⁷ A1154 H H G³⁹ A1155 H H G⁴¹ A1156 H H G⁴³ A1157 H H G⁴⁵ A1158 H H G⁴⁷ A1159 CH₃ R^(B1) G³⁷ A1160 CH₃ R^(B3) G³⁷ A1161 CH₃ R^(B5) G³⁷ A1162 CH₃ R^(B7) G³⁷ A1163 CH₃ R^(B9) G³⁷ A1164 CH₃ R^(B11) G³⁷ A1165 CH₃ R^(B13) G³⁷ A1166 CH₃ R^(B15) G³⁷ A1167 CH₃ R^(B17) G³⁷ A1168 CH₃ R^(B19) G³⁷ A1169 CH₃ R^(B21) G³⁷ A1170 CH₃ R^(B23) G³⁷ A1171 CH₃ R^(B25) G³⁷ A1172 CH₃ R^(B27) G³⁷ A1173 CH₃ R^(B29) G³⁷ A1174 CH₃ R^(B31) G³⁷ A1175 CH₃ R^(B33) G³⁷ A1176 CH₃ R^(B35) G³⁷ A1177 CH₃ R^(B37) G³⁷ A1178 CH₃ R^(B39) G³⁷ A1179 CH₃ R^(B41) G³⁷ A1180 CH₃ R^(B43) G³⁷ A1181 CH₃ R^(B45) G³⁷ A1182 CH₃ R^(B47) G³⁷ A1183 CH₃ R^(B49) G³⁷ A1184 CH₃ R^(B51) G³⁷ A1185 CH₃ R^(B53) G³⁷ A1186 CH₃ R^(B55) G³⁷ A1187 CH₃ R^(B57) G³⁷ A1188 CH₃ R^(B59) G³⁷ A1189 R^(B1) CH₃ G³⁷ A1190 R^(B3) CH₃ G³⁷ A1191 R^(B5) CH₃ G³⁷ A1192 R^(B7) CH₃ G³⁷ A1193 R^(B9) CH₃ G³⁷ A1194 R^(B11) CH₃ G³⁷ A1195 R^(B13) CH₃ G³⁷ A1196 R^(B15) CH₃ G³⁷ A1197 R^(B17) CH₃ G³⁷ A1198 R^(B19) CH₃ G³⁷ A1199 R^(B21) CH₃ G³⁷ A1200 R^(B23) CH₃ G³⁷ A1201 R^(B25) CH₃ G³⁷ A1202 R^(B27) CH₃ G³⁷ A1203 R^(B29) CH₃ G³⁷ A1204 R^(B31) CH₃ G³⁷ A1205 R^(B33) CH₃ G³⁷ A1206 R^(B35) CH₃ G³⁷ A1207 R^(B37) CH₃ G³⁷ A1208 R^(B39) CH₃ G³⁷ A1209 R^(B41) CH₃ G³⁷ A1210 R^(B43) CH₃ G³⁷ A1211 R^(B45) CH₃ G³⁷ A1212 R^(B47) CH₃ G³⁷ A1213 R^(B49) CH₃ G³⁷ A1214 R^(B51) CH₃ G³⁷ A1215 R^(B53) CH₃ G³⁷ A1216 R^(B55) CH₃ G³⁷ A1217 R^(B57) CH₃ G³⁷ A1218 R^(B59) CH₃ G³⁷ A1219 CH₃ R^(B1) G³⁹ A1220 CH₃ R^(B3) G³⁹ A1221 CH₃ R^(B5) G³⁹ A1222 CH₃ R^(B7) G³⁹ A1223 CH₃ R^(B9) G³⁹ A1224 CH₃ R^(B11) G³⁹ A1225 CH₃ R^(B13) G³⁹ A1226 CH₃ R^(B15) G³⁹ A1227 CH₃ R^(B17) G³⁹ A1228 CH₃ R^(B19) G³⁹ A1229 CH₃ R^(B21) G³⁹ A1230 CH₃ R^(B23) G³⁹ A1231 CH₃ R^(B25) G³⁹ A1232 CH₃ R^(B27) G³⁹ A1233 CH₃ R^(B29) G³⁹ A1234 CH₃ R^(B31) G³⁹ A1235 CH₃ R^(B33) G³⁹ A1236 CH₃ R^(B35) G³⁹ A1237 CH₃ R^(B37) G³⁹ A1238 CH₃ R^(B39) G³⁹ A1239 CH₃ R^(B41) G³⁹ A1240 CH₃ R^(B43) G³⁹ A1241 CH₃ R^(B45) G³⁹ A1242 CH₃ R^(B47) G³⁹ A1243 CH₃ R^(B49) G³⁹ A1244 CH₃ R^(B51) G³⁹ A1245 CH₃ R^(B53) G³⁹ A1246 CH₃ R^(B55) G³⁹ A1247 CH₃ R^(B57) G³⁹ A1248 CH₃ R^(B59) G³⁹ A1249 R^(B1) CH₃ G³⁹ A1250 R^(B3) CH₃ G³⁹ A1251 R^(B5) CH₃ G³⁹ A1252 R^(B7) CH₃ G³⁹ A1253 R^(B9) CH₃ G³⁹ A1254 R^(B11) CH₃ G³⁹ A1255 R^(B13) CH₃ G³⁹ A1256 R^(B15) CH₃ G³⁹ A1257 R^(B17) CH₃ G³⁹ A1258 R^(B19) CH₃ G³⁹ A1259 R^(B21) CH₃ G³⁹ A1260 R^(B23) CH₃ G³⁹ A1261 R^(B25) CH₃ G³⁹ A1262 R^(B27) CH₃ G³⁹ A1263 R^(B29) CH₃ G³⁹ A1264 R^(B31) CH₃ G³⁹ A1265 R^(B33) CH₃ G³⁹ A1266 R^(B35) CH₃ G³⁹ A1267 R^(B37) CH₃ G³⁹ A1268 R^(B39) CH₃ G³⁹ A1269 R^(B41) CH₃ G³⁹ A1270 R^(B43) CH₃ G³⁹ A1271 R^(B45) CH₃ G³⁹ A1272 R^(B47) CH₃ G³⁹ A1273 R^(B49) CH₃ G³⁹ A1274 R^(B51) CH₃ G³⁹ A1275 R^(B53) CH₃ G³⁹ A1276 R^(B55) CH₃ G³⁹ A1277 R^(B57) CH₃ G³⁹ A1278 R^(B59) CH₃ G³⁹ A1279 CH₃ R^(B1) G⁴⁰ A1280 CH₃ R^(B3) G⁴⁰ A1281 CH₃ R^(B5) G⁴⁰ A1282 CH₃ R^(B7) G⁴⁰ A1283 CH₃ R^(B9) G⁴⁰ A1284 CH₃ R^(B11) G⁴⁰ A1285 CH₃ R^(B13) G⁴⁰ A1286 CH₃ R^(B15) G⁴⁰ A1287 CH₃ R^(B17) G⁴⁰ A1288 CH₃ R^(B19) G⁴⁰ A1289 CH₃ R^(B21) G⁴⁰ A1290 CH₃ R^(B23) G⁴⁰ A1291 CH₃ R^(B25) G⁴⁰ A1292 CH₃ R^(B27) G⁴⁰ A1293 CH₃ R^(B29) G⁴⁰ A1294 CH₃ R^(B31) G⁴⁰ A1295 CH₃ R^(B33) G⁴⁰ A1296 CH₃ R^(B35) G⁴⁰ A1297 CH₃ R^(B37) G⁴⁰ A1298 CH₃ R^(B39) G⁴⁰ A1299 CH₃ R^(B41) G⁴⁰ A1300 CH₃ R^(B43) G⁴⁰ A1301 CH₃ R^(B45) G⁴⁰ A1302 CH₃ R^(B47) G⁴⁰ A1303 CH₃ R^(B49) G⁴⁰ A1304 CH₃ R^(B51) G⁴⁰ A1305 CH₃ R^(B53) G⁴⁰ A1306 CH₃ R^(B55) G⁴⁰ A1307 CH₃ R^(B57) G⁴⁰ A1308 CH₃ R^(B59) G⁴⁰ A1309 R^(B1) CH₃ G⁴⁰ A1310 R^(B3) CH₃ G⁴⁰ A1311 R^(B5) CH₃ G⁴⁰ A1312 R^(B7) CH₃ G⁴⁰ A1313 R^(B9) CH₃ G⁴⁰ A1314 R^(B11) CH₃ G⁴⁰ A1315 R^(B13) CH₃ G⁴⁰ A1316 R^(B15) CH₃ G⁴⁰ A1317 R^(B17) CH₃ G⁴⁰ A1318 R^(B19) CH₃ G⁴⁰ A1319 R^(B21) CH₃ G⁴⁰ A1320 R^(B23) CH₃ G⁴⁰ A1321 R^(B25) CH₃ G⁴⁰ A1322 R^(B27) CH₃ G⁴⁰ A1323 R^(B29) CH₃ G⁴⁰ A1324 R^(B31) CH₃ G⁴⁰ A1325 R^(B33) CH₃ G⁴⁰ A1326 R^(B35) CH₃ G⁴⁰ A1327 R^(B37) CH₃ G⁴⁰ A1328 R^(B39) CH₃ G⁴⁰ A1329 R^(B41) CH₃ G⁴⁰ A1330 R^(B43) CH₃ G⁴⁰ A1331 R^(B45) CH₃ G⁴⁰ A1332 R^(B47) CH₃ G⁴⁰ A1333 R^(B49) CH₃ G⁴⁰ A1334 R^(B51) CH₃ G⁴⁰ A1335 R^(B53) CH₃ G⁴⁰ A1336 R^(B55) CH₃ G⁴⁰ A1337 R^(B57) CH₃ G⁴⁰ A1338 R^(B59) CH₃ G⁴⁰ A1339 CH₃ R^(B1) G⁴¹ A1340 CH₃ R^(B3) G⁴¹ A1341 CH₃ R^(B5) G⁴¹ A1342 CH₃ R^(B7) G⁴¹ A1343 CH₃ R^(B9) G⁴¹ A1344 CH₃ R^(B11) G⁴¹ A1345 CH₃ R^(B13) G⁴¹ A1346 CH₃ R^(B15) G⁴¹ A1347 CH₃ R^(B17) G⁴¹ A1348 CH₃ R^(B19) G⁴¹ A1349 CH₃ R^(B21) G⁴¹ A1350 CH₃ R^(B23) G⁴¹ A1351 CH₃ R^(B25) G⁴¹ A1352 CH₃ R^(B27) G⁴¹ A1353 CH₃ R^(B29) G⁴¹ A1354 CH₃ R^(B31) G⁴¹ A1355 CH₃ R^(B33) G⁴¹ A1356 CH₃ R^(B35) G⁴¹ A1357 H H G³⁸ A1358 H H G⁴⁰ A1359 H H G⁴² A1360 H H G⁴⁴ A1361 H H G⁴⁶ A1362 H H G⁴⁸ A1363 CH₃ R^(B2) G³⁷ A1364 CH₃ R^(B4) G³⁷ A1365 CH₃ R^(B6) G³⁷ A1366 CH₃ R^(B8) G³⁷ A1367 CH₃ R^(B10) G³⁷ A1368 CH₃ R^(B12) G³⁷ A1369 CH₃ R^(B14) G³⁷ A1370 CH₃ R^(B16) G³⁷ A1371 CH₃ R^(B18) G³⁷ A1372 CH₃ R^(B20) G³⁷ A1373 CH₃ R^(B22) G³⁷ A1374 CH₃ R^(B24) G³⁷ A1375 CH₃ R^(B26) G³⁷ A1376 CH₃ R^(B28) G³⁷ A1377 CH₃ R^(B30) G³⁷ A1378 CH₃ R^(B32) G³⁷ A1379 CH₃ R^(B34) G³⁷ A1380 CH₃ R^(B36) G³⁷ A1381 CH₃ R^(B38) G³⁷ A1382 CH₃ R^(B40) G³⁷ A1383 CH₃ R^(B42) G³⁷ A1384 CH₃ R^(B44) G³⁷ A1385 CH₃ R^(B46) G³⁷ A1386 CH₃ R^(B48) G³⁷ A1387 CH₃ R^(B50) G³⁷ A1388 CH₃ R^(B52) G³⁷ A1389 CH₃ R^(B54) G³⁷ A1390 CH₃ R^(B56) G³⁷ A1391 CH₃ R^(B58) G³⁷ A1392 CH₃ R^(B60) G³⁷ A1393 R^(B2) CH₃ G³⁷ A1394 R^(B4) CH₃ G³⁷ A1395 R^(B6) CH₃ G³⁷ A1396 R^(B8) CH₃ G³⁷ A1397 R^(B10) CH₃ G³⁷ A1398 R^(B12) CH₃ G³⁷ A1399 R^(B14) CH₃ G³⁷ A1400 R^(B16) CH₃ G³⁷ A1401 R^(B18) CH₃ G³⁷ A1402 R^(B20) CH₃ G³⁷ A1403 R^(B22) CH₃ G³⁷ A1404 R^(B24) CH₃ G³⁷ A1405 R^(B26) CH₃ G³⁷ A1406 R^(B28) CH₃ G³⁷ A1407 R^(B30) CH₃ G³⁷ A1408 R^(B32) CH₃ G³⁷ A1409 R^(B34) CH₃ G³⁷ A1410 R^(B36) CH₃ G³⁷ A1411 R^(B38) CH₃ G³⁷ A1412 R^(B40) CH₃ G³⁷ A1413 R^(B42) CH₃ G³⁷ A1414 R^(B44) CH₃ G³⁷ A1415 R^(B46) CH₃ G³⁷ A1416 R^(B48) CH₃ G³⁷ A1417 R^(B50) CH₃ G³⁷ A1418 R^(B52) CH₃ G³⁷ A1419 R^(B54) CH₃ G³⁷ A1420 R^(B56) CH₃ G³⁷ A1421 R^(B58) CH₃ G³⁷ A1422 R^(B60) CH₃ G³⁷ A1423 CH₃ R^(B2) G³⁹ A1424 CH₃ R^(B4) G³⁹ A1425 CH₃ R^(B6) G³⁹ A1426 CH₃ R^(B8) G³⁹ A1427 CH₃ R^(B10) G³⁹ A1428 CH₃ R^(B12) G³⁹ A1429 CH₃ R^(B14) G³⁹ A1430 CH₃ R^(B16) G³⁹ A1431 CH₃ R^(B18) G³⁹ A1432 CH₃ R^(B20) G³⁹ A1433 CH₃ R^(B22) G³⁹ A1434 CH₃ R^(B24) G³⁹ A1435 CH₃ R^(B26) G³⁹ A1436 CH₃ R^(B28) G³⁹ A1437 CH₃ R^(B30) G³⁹ A1438 CH₃ R^(B32) G³⁹ A1439 CH₃ R^(B34) G³⁹ A1440 CH₃ R^(B36) G³⁹ A1441 CH₃ R^(B38) G³⁹ A1442 CH₃ R^(B40) G³⁹ A1443 CH₃ R^(B42) G³⁹ A1444 CH₃ R^(B44) G³⁹ A1445 CH₃ R^(B46) G³⁹ A1446 CH₃ R^(B48) G³⁹ A1447 CH₃ R^(B50) G³⁹ A1448 CH₃ R^(B52) G³⁹ A1449 CH₃ R^(B54) G³⁹ A1450 CH₃ R^(B56) G³⁹ A1451 CH₃ R^(B58) G³⁹ A1452 CH₃ R^(B60) G³⁹ A1453 R^(B2) CH₃ G³⁹ A1454 R^(B4) CH₃ G³⁹ A1455 R^(B6) CH₃ G³⁹ A1456 R^(B8) CH₃ G³⁹ A1457 R^(B10) CH₃ G³⁹ A1458 R^(B12) CH₃ G³⁹ A1459 R^(B14) CH₃ G³⁹ A1460 R^(B16) CH₃ G³⁹ A1461 R^(B18) CH₃ G³⁹ A1462 R^(B20) CH₃ G³⁹ A1463 R^(B22) CH₃ G³⁹ A1464 R^(B24) CH₃ G³⁹ A1465 R^(B26) CH₃ G³⁹ A1466 R^(B28) CH₃ G³⁹ A1467 R^(B30) CH₃ G³⁹ A1468 R^(B32) CH₃ G³⁹ A1469 R^(B34) CH₃ G³⁹ A1470 R^(B36) CH₃ G³⁹ A1471 R^(B38) CH₃ G³⁹ A1472 R^(B40) CH₃ G³⁹ A1473 R^(B42) CH₃ G³⁹ A1474 R^(B44) CH₃ G³⁹ A1475 R^(B46) CH₃ G³⁹ A1476 R^(B48) CH₃ G³⁹ A1477 R^(B50) CH₃ G³⁹ A1478 R^(B52) CH₃ G³⁹ A1479 R^(B54) CH₃ G³⁹ A1480 R^(B56) CH₃ G³⁹ A1481 R^(B58) CH₃ G³⁹ A1482 R^(B60) CH₃ G³⁹ A1483 CH₃ R^(B2) G⁴⁰ A1484 CH₃ R^(B4) G⁴⁰ A1485 CH₃ R^(B6) G⁴⁰ A1486 CH₃ R^(B8) G⁴⁰ A1487 CH₃ R^(B10) G⁴⁰ A1488 CH₃ R^(B12) G⁴⁰ A1489 CH₃ R^(B14) G⁴⁰ A1490 CH₃ R^(B16) G⁴⁰ A1491 CH₃ R^(B18) G⁴⁰ A1492 CH₃ R^(B20) G⁴⁰ A1493 CH₃ R^(B22) G⁴⁰ A1494 CH₃ R^(B24) G⁴⁰ A1495 CH₃ R^(B26) G⁴⁰ A1496 CH₃ R^(B28) G⁴⁰ A1497 CH₃ R^(B30) G⁴⁰ A1498 CH₃ R^(B32) G⁴⁰ A1499 CH₃ R^(B34) G⁴⁰ A1500 CH₃ R^(B36) G⁴⁰ A1501 CH₃ R^(B38) G⁴⁰ A1502 CH₃ R^(B40) G⁴⁰ A1503 CH₃ R^(B42) G⁴⁰ A1504 CH₃ R^(B44) G⁴⁰ A1505 CH₃ R^(B46) G⁴⁰ A1506 CH₃ R^(B48) G⁴⁰ A1507 CH₃ R^(B50) G⁴⁰ A1508 CH₃ R^(B52) G⁴⁰ A1509 CH₃ R^(B54) G⁴⁰ A1510 CH₃ R^(B56) G⁴⁰ A1511 CH₃ R^(B58) G⁴⁰ A1512 CH₃ R^(B60) G⁴⁰ A1513 R^(B2) CH₃ G⁴⁰ A1514 R^(B4) CH₃ G⁴⁰ A1515 R^(B6) CH₃ G⁴⁰ A1516 R^(B8) CH₃ G⁴⁰ A1517 R^(B10) CH₃ G⁴⁰ A1518 R^(B12) CH₃ G⁴⁰ A1519 R^(B14) CH₃ G⁴⁰ A1520 R^(B16) CH₃ G⁴⁰ A1521 R^(B18) CH₃ G⁴⁰ A1522 R^(B20) CH₃ G⁴⁰ A1523 R^(B22) CH₃ G⁴⁰ A1524 R^(B24) CH₃ G⁴⁰ A1525 R^(B26) CH₃ G⁴⁰ A1526 R^(B28) CH₃ G⁴⁰ A1527 R^(B30) CH₃ G⁴⁰ A1528 R^(B32) CH₃ G⁴⁰ A1529 R^(B34) CH₃ G⁴⁰ A1530 R^(B36) CH₃ G⁴⁰ A1531 R^(B38) CH₃ G⁴⁰ A1532 R^(B40) CH₃ G⁴⁰ A1533 R^(B42) CH₃ G⁴⁰ A1534 R^(B44) CH₃ G⁴⁰ A1535 R^(B46) CH₃ G⁴⁰ A1536 R^(B48) CH₃ G⁴⁰ A1537 R^(B50) CH₃ G⁴⁰ A1538 R^(B52) CH₃ G⁴⁰ A1539 R^(B54) CH₃ G⁴⁰ A1540 R^(B56) CH₃ G⁴⁰ A1541 R^(B58) CH₃ G⁴⁰ A1542 R^(B60) CH₃ G⁴⁰ A1543 CH₃ R^(B2) G⁴¹ A1544 CH₃ R^(B4) G⁴¹ A1545 CH₃ R^(B6) G⁴¹ A1546 CH₃ R^(B8) G⁴¹ A1547 CH₃ R^(B10) G⁴¹ A1548 CH₃ R^(B12) G⁴¹ A1549 CH₃ R^(B14) G⁴¹ A1550 CH₃ R^(B16) G⁴¹ A1551 CH₃ R^(B18) G⁴¹ A1552 CH₃ R^(B20) G⁴¹ A1553 CH₃ R^(B22) G⁴¹ A1554 CH₃ R^(B24) G⁴¹ A1555 CH₃ R^(B26) G⁴¹ A1556 CH₃ R^(B28) G⁴¹ A1557 CH₃ R^(B30) G⁴¹ A1558 CH₃ R^(B32) G⁴¹ A1559 CH₃ R^(B34) G⁴¹ A1560 CH₃ R^(B36) G⁴¹ A1561 CH₃ R^(B37) G⁴¹ A1562 CH₃ R^(B39) G⁴¹ A1563 CH₃ R^(B41) G⁴¹ A1564 CH₃ R^(B43) G⁴¹ A1565 CH₃ R^(B45) G⁴¹ A1566 CH₃ R^(B47) G⁴¹ A1567 CH₃ R^(B49) G⁴¹ A1568 CH₃ R^(B51) G⁴¹ A1569 CH₃ R^(B53) G⁴¹ A1570 CH₃ R^(B55) G⁴¹ A1571 CH₃ R^(B57) G⁴¹ A1572 CH₃ R^(B59) G⁴¹ A1573 R^(B1) CH₃ G⁴¹ A1574 R^(B3) CH₃ G⁴¹ A1575 R^(B5) CH₃ G⁴¹ A1576 R^(B7) CH₃ G⁴¹ A1577 R^(B9) CH₃ G⁴¹ A1578 R^(B11) CH₃ G⁴¹ A1579 R^(B13) CH₃ G⁴¹ A1580 R^(B15) CH₃ G⁴¹ A1581 R^(B17) CH₃ G⁴¹ A1582 R^(B19) CH₃ G⁴¹ A1583 R^(B21) CH₃ G⁴¹ A1584 R^(B23) CH₃ G⁴¹ A1585 R^(B25) CH₃ G⁴¹ A1586 R^(B27) CH₃ G⁴¹ A1587 R^(B29) CH₃ G⁴¹ A1588 R^(B31) CH₃ G⁴¹ A1589 R^(B33) CH₃ G⁴¹ A1590 R^(B35) CH₃ G⁴¹ A1591 R^(B37) CH₃ G⁴¹ A1592 R^(B39) CH₃ G⁴¹ A1593 R^(B41) CH₃ G⁴¹ A1594 R^(B43) CH₃ G⁴¹ A1595 R^(B45) CH₃ G⁴¹ A1596 R^(B47) CH₃ G⁴¹ A1597 R^(B49) CH₃ G⁴¹ A1598 R^(B51) CH₃ G⁴¹ A1599 R^(B53) CH₃ G⁴¹ A1600 R^(B55) CH₃ G⁴¹ A1601 R^(B57) CH₃ G⁴¹ A1602 R^(B59) CH₃ G⁴¹ A1603 CH₃ R^(B1) G⁴² A1604 CH₃ R^(B3) G⁴² A1605 CH₃ R^(B5) G⁴² A1606 CH₃ R^(B7) G⁴² A1607 CH₃ R^(B9) G⁴² A1608 CH₃ R^(B11) G⁴² A1609 CH₃ R^(B13) G⁴² A1610 CH₃ R^(B15) G⁴² A1611 CH₃ R^(B17) G⁴² A1612 CH₃ R^(B19) G⁴² A1613 CH₃ R^(B21) G⁴² A1614 CH₃ R^(B23) G⁴² A1615 CH₃ R^(B25) G⁴² A1616 CH₃ R^(B27) G⁴² A1617 CH₃ R^(B29) G⁴² A1618 CH₃ R^(B31) G⁴² A1619 CH₃ R^(B33) G⁴² A1620 CH₃ R^(B35) G⁴² A1621 CH₃ R^(B37) G⁴² A1622 CH₃ R^(B39) G⁴² A1623 CH₃ R^(B41) G⁴² A1624 CH₃ R^(B43) G⁴² A1625 CH₃ R^(B45) G⁴² A1626 CH₃ R^(B47) G⁴² A1627 CH₃ R^(B49) G⁴² A1628 CH₃ R^(B51) G⁴² A1629 CH₃ R^(B53) G⁴² A1630 CH₃ R^(B55) G⁴² A1631 CH₃ R^(B57) G⁴² A1632 CH₃ R^(B59) G⁴² A1633 R^(B1) CH₃ G⁴² A1634 R^(B3) CH₃ G⁴² A1635 R^(B5) CH₃ G⁴² A1636 R^(B7) CH₃ G⁴² A1637 R^(B9) CH₃ G⁴² A1638 R^(B11) CH₃ G⁴² A1639 R^(B13) CH₃ G⁴² A1640 R^(B15) CH₃ G⁴² A1641 R^(B17) CH₃ G⁴² A1642 R^(B19) CH₃ G⁴² A1643 R^(B21) CH₃ G⁴² A1644 R^(B23) CH₃ G⁴² A1645 R^(B25) CH₃ G⁴² A1646 R^(B27) CH₃ G⁴² A1647 R^(B29) CH₃ G⁴² A1648 R^(B31) CH₃ G⁴² A1649 R^(B33) CH₃ G⁴² A1650 R^(B35) CH₃ G⁴² A1651 R^(B37) CH₃ G⁴² A1652 R^(B39) CH₃ G⁴² A1653 R^(B41) CH₃ G⁴² A1654 R^(B43) CH₃ G⁴² A1655 R^(B45) CH₃ G⁴² A1656 R^(B47) CH₃ G⁴² A1657 R^(B49) CH₃ G⁴² A1658 R^(B51) CH₃ G⁴² A1659 R^(B53) CH₃ G⁴² A1660 R^(B55) CH₃ G⁴² A1661 R^(B57) CH₃ G⁴² A1662 R^(B59) CH₃ G⁴² A1663 CH₃ R^(B38) G⁴¹ A1664 CH₃ R^(B40) G⁴¹ A1665 CH₃ R^(B42) G⁴¹ A1666 CH₃ R^(B44) G⁴¹ A1667 CH₃ R^(B46) G⁴¹ A1668 CH₃ R^(B48) G⁴¹ A1669 CH₃ R^(B50) G⁴¹ A1670 CH₃ R^(B52) G⁴¹ A1671 CH₃ R^(B54) G⁴¹ A1672 CH₃ R^(B56) G⁴¹ A1673 CH₃ R^(B58) G⁴¹ A1674 CH₃ R^(B60) G⁴¹ A1675 R^(B2) CH₃ G⁴¹ A1676 R^(B4) CH₃ G⁴¹ A1677 R^(B6) CH₃ G⁴¹ A1678 R^(B8) CH₃ G⁴¹ A1679 R^(B10) CH₃ G⁴¹ A1680 R^(B12) CH₃ G⁴¹ A1681 R^(B14) CH₃ G⁴¹ A1682 R^(B16) CH₃ G⁴¹ A1683 R^(B18) CH₃ G⁴¹ A1684 R^(B20) CH₃ G⁴¹ A1685 R^(B22) CH₃ G⁴¹ A1686 R^(B24) CH₃ G⁴¹ A1687 R^(B26) CH₃ G⁴¹ A1688 R^(B28) CH₃ G⁴¹ A1689 R^(B30) CH₃ G⁴¹ A1690 R^(B32) CH₃ G⁴¹ A1691 R^(B34) CH₃ G⁴¹ A1692 R^(B36) CH₃ G⁴¹ A1693 R^(B38) CH₃ G⁴¹ A1694 R^(B40) CH₃ G⁴¹ A1695 R^(B42) CH₃ G⁴¹ A1696 R^(B44) CH₃ G⁴¹ A1697 R^(B46) CH₃ G⁴¹ A1698 R^(B48) CH₃ G⁴¹ A1699 R^(B50) CH₃ G⁴¹ A1700 R^(B52) CH₃ G⁴¹ A1701 R^(B54) CH₃ G⁴¹ A1702 R^(B56) CH₃ G⁴¹ A1703 R^(B58) CH₃ G⁴¹ A1704 R^(B60) CH₃ G⁴¹ A1705 CH₃ R^(B2) G⁴² A1706 CH₃ R^(B4) G⁴² A1707 CH₃ R^(B6) G⁴² A1708 CH₃ R^(B8) G⁴² A1709 CH₃ R^(B10) G⁴² A1710 CH₃ R^(B12) G⁴² A1711 CH₃ R^(B14) G⁴² A1712 CH₃ R^(B16) G⁴² A1713 CH₃ R^(B18) G⁴² A1714 CH₃ R^(B20) G⁴² A1715 CH₃ R^(B22) G⁴² A1716 CH₃ R^(B24) G⁴² A1717 CH₃ R^(B26) G⁴² A1718 CH₃ R^(B28) G⁴² A1719 CH₃ R^(B30) G⁴² A1720 CH₃ R^(B32) G⁴² A1721 CH₃ R^(B34) G⁴² A1722 CH₃ R^(B36) G⁴² A1723 CH₃ R^(B38) G⁴² A1724 CH₃ R^(B40) G⁴² A1725 CH₃ R^(B42) G⁴² A1726 CH₃ R^(B44) G⁴² A1727 CH₃ R^(B46) G⁴² A1728 CH₃ R^(B48) G⁴² A1729 CH₃ R^(B50) G⁴² A1730 CH₃ R^(B52) G⁴² A1731 CH₃ R^(B54) G⁴² A1732 CH₃ R^(B56) G⁴² A1733 CH₃ R^(B58) G⁴² A1734 CH₃ R^(B60) G⁴² A1735 R^(B2) CH₃ G⁴² A1736 R^(B4) CH₃ G⁴² A1737 R^(B6) CH₃ G⁴² A1738 R^(B8) CH₃ G⁴² A1739 R^(B10) CH₃ G⁴² A1740 R^(B12) CH₃ G⁴² A1741 R^(B14) CH₃ G⁴² A1742 R^(B16) CH₃ G⁴² A1743 R^(B18) CH₃ G⁴² A1744 R^(B20) CH₃ G⁴² A1745 R^(B22) CH₃ G⁴² A1746 R^(B24) CH₃ G⁴² A1747 R^(B26) CH₃ G⁴² A1748 R^(B28) CH₃ G⁴² A1749 R^(B30) CH₃ G⁴² A1750 R^(B32) CH₃ G⁴² A1751 R^(B34) CH₃ G⁴² A1752 R^(B36) CH₃ G⁴² A1753 R^(B38) CH₃ G⁴² A1754 R^(B40) CH₃ G⁴² A1755 R^(B42) CH₃ G⁴² A1756 R^(B44) CH₃ G⁴² A1757 R^(B46) CH₃ G⁴² A1758 R^(B48) CH₃ G⁴² A1759 R^(B50) CH₃ G⁴² A1760 R^(B52) CH₃ G⁴² A1761 R^(B54) CH₃ G⁴² A1762 R^(B56) CH₃ G⁴² A1763 R^(B58) CH₃ G⁴² A1764 R^(B60) CH₃ G⁴²

wherein R^(B1) to R^(B60) have the following structures:

wherein G¹ to G⁴⁸ have the following structures:

wherein the Arabic Numerals indicate the points of attachment to the corresponding points of attachment in ligand L_(A).
 10. The compound of claim 1, wherein the compound has a formula of M(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) wherein L_(B) and L_(C) are each a bidentate ligand; and wherein x is 1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2; and x+y+z is the oxidation state of the metal M.
 11. The compound of claim 10, wherein L_(B) and L_(C) are each independently selected from the group consisting of:

wherein each Y¹ to Y¹³ are independently selected from the group consisting of carbon and nitrogen; wherein Y′ is selected from the group consisting of BR_(e), NR_(e), PR_(e), O, S, Se, C═O, S═O, SO₂, CR_(e)R_(f), SiR_(e)R_(f), and GeR_(e)R_(f); wherein R_(e) and R_(f) are optionally fused or joined to form a ring; wherein each R_(e) and R_(f) is independently selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein each R_(a), R_(b), R_(e), and R_(d) may independently represent from mono substitution to the maximum possible number of substitution, or no substitution; wherein each R_(a), R_(b), R_(e), and R_(d) is independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein any two adjacent substituents of R_(a), R_(b), R_(e), and R_(d) are optionally fused or joined to form a ring or form a multidentate ligand.
 12. The compound of claim 9, wherein the compound is Compound Ai-F having the formula Ir(L_(Ai-F))₃, Compound By-F having the formula Ir(L_(Ai-F))(L_(Bk))₂, or Compound Cz-F having the formula Ir(L_(Ai-F))₂(L_(Cj)); wherein i is an integer from 1 to 1764, and k is an integer from 1 to 490, j is an integer from 1 to 1260, y=490i+k−4908, and z=1764i+j−1764; and wherein F is O, S, or C; wherein L_(Bk) is selected from the group consisting of the following structures:

wherein L_(C1) through L_(C1260) are based on a structure of Formula X

 in which R¹, R², and R³ are defined as: Ligand R¹ R² R³ L_(C1) R^(D1) R^(D1) H L_(C2) R^(D2) R^(D2) H L_(C3) R^(D3) R^(D3) H L_(C4) R^(D4) R^(D4) H L_(C5) R^(D5) R^(D5) H L_(C6) R^(D6) R^(D6) H L_(C7) R^(D7) R^(D7) H L_(C8) R^(D8) R^(D8) H L_(C9) R^(D9) R^(D9) H L_(C10) R^(D10) R^(D10) H L_(C11) R^(D11) R^(D11) H L_(C12) R^(D12) R^(D12) H L_(C13) R^(D13) R^(D13) H L_(C14) R^(D14) R^(D14) H L_(C15) R^(D15) R^(D15) H L_(C16) R^(D16) R^(D16) H L_(C17) R^(D17) R^(D17) H L_(C18) R^(D18) R^(D18) H L_(C19) R^(D19) R^(D19) H L_(C20) R^(D20) R^(D20) H L_(C21) R^(D21) R^(D21) H L_(C22) R^(D22) R^(D22) H L_(C23) R^(D23) R^(D23) H L_(C24) R^(D24) R^(D24) H L_(C25) R^(D25) R^(D25) H L_(C26) R^(D26) R^(D26) H L_(C27) R^(D27) R^(D27) H L_(C28) R^(D28) R^(D28) H L_(C29) R^(D29) R^(D29) H L_(C30) R^(D30) R^(D30) H L_(C31) R^(D31) R^(D31) H L_(C32) R^(D32) R^(D32) H L_(C33) R^(D33) R^(D33) H L_(C34) R^(D34) R^(D34) H L_(C35) R^(D35) R^(D35) H L_(C36) R^(D40) R^(D40) H L_(C37) R^(D41) R^(D41) H L_(C38) R^(D42) R^(D42) H L_(C39) R^(D64) R^(D64) H L_(C40) R^(D66) R^(D66) H L_(C41) R^(D68) R^(D68) H L_(C42) R^(D76) R^(D76) H L_(C43) R^(D1) R^(D2) H L_(C44) R^(D1) R^(D3) H L_(C45) R^(D1) R^(D4) H L_(C46) R^(D1) R^(D5) H L_(C47) R^(D1) R^(D6) H L_(C48) R^(D1) R^(D7) H L_(C49) R^(D1) R^(D8) H L_(C50) R^(D1) R^(D9) H L_(C51) R^(D1) R^(D10) H L_(C52) R^(D1) R^(D11) H L_(C53) R^(D1) R^(D12) H L_(C54) R^(D1) R^(D13) H L_(C55) R^(D1) R^(D14) H L_(C56) R^(D1) R^(D15) H L_(C57) R^(D1) R^(D16) H L_(C58) R^(D1) R^(D17) H L_(C59) R^(D1) R^(D18) H L_(C60) R^(D1) R^(D19) H L_(C61) R^(D1) R^(D20) H L_(C62) R^(D1) R^(D21) H L_(C63) R^(D1) R^(D22) H L_(C64) R^(D1) R^(D23) H L_(C65) R^(D1) R^(D24) H L_(C66) R^(D1) R^(D25) H L_(C67) R^(D1) R^(D26) H L_(C68) R^(D1) R^(D27) H L_(C69) R^(D1) R^(D28) H L_(C70) R^(D1) R^(D29) H L_(C71) R^(D1) R^(D30) H L_(C72) R^(D1) R^(D31) H L_(C73) R^(D1) R^(D32) H L_(C74) R^(D1) R^(D33) H L_(C75) R^(D1) R^(D34) H L_(C76) R^(D1) R^(D35) H L_(C77) R^(D1) R^(D40) H L_(C78) R^(D1) R^(D41) H L_(C79) R^(D1) R^(D42) H L_(C80) R^(D1) R^(D64) H L_(C81) R^(D1) R^(D66) H L_(C82) R^(D1) R^(D68) H L_(C83) R^(D1) R^(D76) H L_(C84) R^(D2) R^(D1) H L_(C85) R^(D2) R^(D3) H L_(C86) R^(D2) R^(D4) H L_(C87) R^(D2) R^(D5) H L_(C88) R^(D2) R^(D6) H L_(C89) R^(D2) R^(D7) H L_(C90) R^(D2) R^(D8) H L_(C91) R^(D2) R^(D9) H L_(C92) R^(D2) R^(D10) H L_(C93) R^(D2) R^(D11) H L_(C94) R^(D2) R^(D12) H L_(C95) R^(D2) R^(D13) H L_(C96) R^(D2) R^(D14) H L_(C97) R^(D2) R^(D15) H L_(C98) R^(D2) R^(D16) H L_(C99) R^(D2) R^(D17) H L_(C100) R^(D2) R^(D18) H L_(C101) R^(D2) R^(D19) H L_(C102) R^(D2) R^(D20) H L_(C103) R^(D2) R^(D21) H L_(C104) R^(D2) R^(D22) H L_(C105) R^(D2) R^(D23) H L_(C106) R^(D2) R^(D24) H L_(C107) R^(D2) R^(D25) H L_(C108) R^(D2) R^(D26) H L_(C109) R^(D2) R^(D27) H L_(C110) R^(D2) R^(D28) H L_(C111) R^(D2) R^(D29) H L_(C112) R^(D2) R^(D30) H L_(C113) R^(D2) R^(D31) H L_(C114) R^(D2) R^(D32) H L_(C115) R^(D2) R^(D33) H L_(C116) R^(D2) R^(D34) H L_(C117) R^(D2) R^(D35) H L_(C118) R^(D2) R^(D40) H L_(C119) R^(D2) R^(D41) H L_(C120) R^(D2) R^(D42) H L_(C121) R^(D2) R^(D64) H L_(C122) R^(D2) R^(D66) H L_(C123) R^(D2) R^(D68) H L_(C124) R^(D2) R^(D76) H L_(C125) R^(D3) R^(D4) H L_(C126) R^(D3) R^(D5) H L_(C127) R^(D3) R^(D6) H L_(C128) R^(D3) R^(D7) H L_(C129) R^(D3) R^(D8) H L_(C130) R^(D3) R^(D9) H L_(C131) R^(D3) R^(D10) H L_(C132) R^(D3) R^(D11) H L_(C133) R^(D3) R^(D12) H L_(C134) R^(D3) R^(D13) H L_(C135) R^(D3) R^(D14) H L_(C136) R^(D3) R^(D15) H L_(C137) R^(D3) R^(D16) H L_(C138) R^(D3) R^(D17) H L_(C139) R^(D3) R^(D18) H L_(C140) R^(D3) R^(D19) H L_(C141) R^(D3) R^(D20) H L_(C142) R^(D3) R^(D21) H L_(C143) R^(D3) R^(D22) H L_(C144) R^(D3) R^(D23) H L_(C145) R^(D3) R^(D24) H L_(C146) R^(D3) R^(D25) H L_(C147) R^(D3) R^(D26) H L_(C148) R^(D3) R^(D27) H L_(C149) R^(D3) R^(D28) H L_(C150) R^(D3) R^(D29) H L_(C151) R^(D3) R^(D30) H L_(C152) R^(D3) R^(D31) H L_(C153) R^(D3) R^(D32) H L_(C154) R^(D3) R^(D33) H L_(C155) R^(D3) R^(D34) H L_(C156) R^(D3) R^(D35) H L_(C157) R^(D3) R^(D40) H L_(C158) R^(D3) R^(D41) H L_(C159) R^(D3) R^(D42) H L_(C160) R^(D3) R^(D64) H L_(C161) R^(D3) R^(D66) H L_(C162) R^(D3) R^(D68) H L_(C163) R^(D3) R^(D76) H L_(C164) R^(D4) R^(D5) H L_(C165) R^(D4) R^(D6) H L_(C166) R^(D4) R^(D7) H L_(C167) R^(D4) R^(D8) H L_(C168) R^(D4) R^(D9) H L_(C169) R^(D4) R^(D10) H L_(C170) R^(D4) R^(D11) H L_(C171) R^(D4) R^(D12) H L_(C172) R^(D4) R^(D13) H L_(C173) R^(D4) R^(D14) H L_(C174) R^(D4) R^(D15) H L_(C175) R^(D4) R^(D16) H L_(C176) R^(D4) R^(D17) H L_(C177) R^(D4) R^(D18) H L_(C178) R^(D4) R^(D19) H L_(C179) R^(D4) R^(D20) H L_(C180) R^(D4) R^(D21) H L_(C181) R^(D4) R^(D22) H L_(C182) R^(D4) R^(D23) H L_(C183) R^(D4) R^(D24) H L_(C184) R^(D4) R^(D25) H L_(C185) R^(D4) R^(D26) H L_(C186) R^(D4) R^(D27) H L_(C187) R^(D4) R^(D28) H L_(C188) R^(D4) R^(D29) H L_(C189) R^(D4) R^(D30) H L_(C190) R^(D4) R^(D31) H L_(C191) R^(D4) R^(D32) H L_(C192) R^(D4) R^(D33) H L_(C193) R^(D4) R^(D34) H L_(C194) R^(D4) R^(D35) H L_(C195) R^(D4) R^(D40) H L_(C196) R^(D4) R^(D41) H L_(C197) R^(D4) R^(D42) H L_(C198) R^(D4) R^(D64) H L_(C199) R^(D4) R^(D66) H L_(C200) R^(D4) R^(D68) H L_(C201) R^(D4) R^(D76) H L_(C202) R^(D4) R^(D1) H L_(C203) R^(D7) R^(D5) H L_(C204) R^(D7) R^(D6) H L_(C205) R^(D7) R^(D8) H L_(C206) R^(D7) R^(D9) H L_(C207) R^(D7) R^(D10) H L_(C208) R^(D7) R^(D11) H L_(C209) R^(D7) R^(D12) H L_(C210) R^(D7) R^(D13) H L_(C211) R^(D7) R^(D14) H L_(C212) R^(D7) R^(D15) H L_(C213) R^(D7) R^(D16) H L_(C214) R^(D7) R^(D17) H L_(C215) R^(D7) R^(D18) H L_(C216) R^(D7) R^(D19) H L_(C217) R^(D7) R^(D20) H L_(C218) R^(D7) R^(D21) H L_(C219) R^(D7) R^(D22) H L_(C220) R^(D7) R^(D23) H L_(C221) R^(D7) R^(D24) H L_(C222) R^(D7) R^(D25) H L_(C223) R^(D7) R^(D26) H L_(C224) R^(D7) R^(D27) H L_(C225) R^(D7) R^(D28) H L_(C226) R^(D7) R^(D29) H L_(C227) R^(D7) R^(D30) H L_(C228) R^(D7) R^(D31) H L_(C229) R^(D7) R^(D32) H L_(C230) R^(D7) R^(D33) H L_(C231) R^(D7) R^(D34) H L_(C232) R^(D7) R^(D35) H L_(C233) R^(D7) R^(D40) H L_(C234) R^(D7) R^(D41) H L_(C235) R^(D7) R^(D42) H L_(C236) R^(D7) R^(D64) H L_(C237) R^(D7) R^(D66) H L_(C238) R^(D7) R^(D68) H L_(C239) R^(D7) R^(D76) H L_(C240) R^(D8) R^(D5) H L_(C241) R^(D8) R^(D6) H L_(C242) R^(D8) R^(D9) H L_(C243) R^(D8) R^(D10) H L_(C244) R^(D8) R^(D11) H L_(C245) R^(D8) R^(D12) H L_(C246) R^(D8) R^(D13) H L_(C247) R^(D8) R^(D14) H L_(C248) R^(D8) R^(D15) H L_(C249) R^(D8) R^(D16) H L_(C250) R^(D8) R^(D17) H L_(C251) R^(D8) R^(D18) H L_(C252) R^(D8) R^(D19) H L_(C253) R^(D8) R^(D20) H L_(C254) R^(D8) R^(D21) H L_(C255) R^(D8) R^(D22) H L_(C256) R^(D8) R^(D23) H L_(C257) R^(D8) R^(D24) H L_(C258) R^(D8) R^(D25) H L_(C259) R^(D8) R^(D26) H L_(C260) R^(D8) R^(D27) H L_(C261) R^(D8) R^(D28) H L_(C262) R^(D8) R^(D29) H L_(C263) R^(D8) R^(D30) H L_(C264) R^(D8) R^(D31) H L_(C265) R^(D8) R^(D32) H L_(C266) R^(D8) R^(D33) H L_(C267) R^(D8) R^(D34) H L_(C268) R^(D8) R^(D35) H L_(C269) R^(D8) R^(D40) H L_(C270) R^(D8) R^(D41) H L_(C271) R^(D8) R^(D42) H L_(C272) R^(D8) R^(D64) H L_(C273) R^(D8) R^(D66) H L_(C274) R^(D8) R^(D68) H L_(C275) R^(D8) R^(D76) H L_(C276) R^(D11) R^(D5) H L_(C277) R^(D11) R^(D6) H L_(C278) R^(D11) R^(D9) H L_(C279) R^(D11) R^(D10) H L_(C280) R^(D11) R^(D12) H L_(C281) R^(D11) R^(D13) H L_(C282) R^(D11) R^(D14) H L_(C283) R^(D11) R^(D15) H L_(C284) R^(D11) R^(D16) H L_(C285) R^(D11) R^(D17) H L_(C286) R^(D11) R^(D18) H L_(C287) R^(D11) R^(D19) H L_(C288) R^(D11) R^(D20) H L_(C289) R^(D11) R^(D21) H L_(C290) R^(D11) R^(D22) H L_(C291) R^(D11) R^(D23) H L_(C292) R^(D11) R^(D24) H L_(C293) R^(D11) R^(D25) H L_(C294) R^(D11) R^(D26) H L_(C295) R^(D11) R^(D27) H L_(C296) R^(D11) R^(D28) H L_(C297) R^(D11) R^(D29) H L_(C298) R^(D11) R^(D30) H L_(C299) R^(D11) R^(D31) H L_(C300) R^(D11) R^(D32) H L_(C301) R^(D11) R^(D33) H L_(C302) R^(D11) R^(D34) H L_(C303) R^(D11) R^(D35) H L_(C304) R^(D11) R^(D40) H L_(C305) R^(D11) R^(D41) H L_(C306) R^(D11) R^(D42) H L_(C307) R^(D11) R^(D64) H L_(C308) R^(D11) R^(D66) H L_(C309) R^(D11) R^(D68) H L_(C310) R^(D11) R^(D76) H L_(C311) R^(D13) R^(D5) H L_(C312) R^(D13) R^(D6) H L_(C313) R^(D13) R^(D9) H L_(C314) R^(D13) R^(D10) H L_(C315) R^(D13) R^(D12) H L_(C316) R^(D13) R^(D14) H L_(C317) R^(D13) R^(D15) H L_(C318) R^(D13) R^(D16) H L_(C319) R^(D13) R^(D17) H L_(C320) R^(D13) R^(D18) H L_(C321) R^(D13) R^(D19) H L_(C322) R^(D13) R^(D20) H L_(C323) R^(D13) R^(D21) H L_(C324) R^(D13) R^(D22) H L_(C325) R^(D13) R^(D23) H L_(C326) R^(D13) R^(D24) H L_(C327) R^(D13) R^(D25) H L_(C328) R^(D13) R^(D26) H L_(C329) R^(D13) R^(D27) H L_(C330) R^(D13) R^(D28) H L_(C331) R^(D13) R^(D29) H L_(C332) R^(D13) R^(D30) H L_(C333) R^(D13) R^(D31) H L_(C334) R^(D13) R^(D32) H L_(C335) R^(D13) R^(D33) H L_(C336) R^(D13) R^(D34) H L_(C337) R^(D13) R^(D35) H L_(C338) R^(D13) R^(D40) H L_(C339) R^(D13) R^(D41) H L_(C340) R^(D13) R^(D42) H L_(C341) R^(D13) R^(D64) H L_(C342) R^(D13) R^(D66) H L_(C343) R^(D13) R^(D68) H L_(C344) R^(D13) R^(D76) H L_(C345) R^(D14) R^(D5) H L_(C346) R^(D14) R^(D6) H L_(C347) R^(D14) R^(D9) H L_(C348) R^(D14) R^(D10) H L_(C349) R^(D14) R^(D12) H L_(C350) R^(D14) R^(D15) H L_(C351) R^(D14) R^(D16) H L_(C352) R^(D14) R^(D17) H L_(C353) R^(D14) R^(D18) H L_(C354) R^(D14) R^(D19) H L_(C355) R^(D14) R^(D20) H L_(C356) R^(D14) R^(D21) H L_(C357) R^(D14) R^(D22) H L_(C358) R^(D14) R^(D23) H L_(C359) R^(D14) R^(D24) H L_(C360) R^(D14) R^(D25) H L_(C361) R^(D14) R^(D26) H L_(C362) R^(D14) R^(D27) H L_(C363) R^(D14) R^(D28) H L_(C364) R^(D14) R^(D29) H L_(C365) R^(D14) R^(D30) H L_(C366) R^(D14) R^(D31) H L_(C367) R^(D14) R^(D32) H L_(C368) R^(D14) R^(D33) H L_(C369) R^(D14) R^(D34) H L_(C370) R^(D14) R^(D35) H L_(C371) R^(D14) R^(D40) H L_(C372) R^(D14) R^(D41) H L_(C373) R^(D14) R^(D42) H L_(C374) R^(D14) R^(D64) H L_(C375) R^(D14) R^(D66) H L_(C376) R^(D14) R^(D68) H L_(C377) R^(D14) R^(D76) H L_(C378) R^(D22) R^(D5) H L_(C379) R^(D22) R^(D6) H L_(C380) R^(D22) R^(D9) H L_(C381) R^(D22) R^(D10) H L_(C382) R^(D22) R^(D12) H L_(C383) R^(D22) R^(D15) H L_(C384) R^(D22) R^(D16) H L_(C385) R^(D22) R^(D17) H L_(C386) R^(D22) R^(D18) H L_(C387) R^(D22) R^(D19) H L_(C388) R^(D22) R^(D20) H L_(C389) R^(D22) R^(D21) H L_(C390) R^(D22) R^(D23) H L_(C391) R^(D22) R^(D24) H L_(C392) R^(D22) R^(D25) H L_(C393) R^(D22) R^(D26) H L_(C394) R^(D22) R^(D27) H L_(C395) R^(D22) R^(D28) H L_(C396) R^(D22) R^(D29) H L_(C397) R^(D22) R^(D30) H L_(C398) R^(D22) R^(D31) H L_(C399) R^(D22) R^(D32) H L_(C400) R^(D22) R^(D33) H L_(C401) R^(D22) R^(D34) H L_(C402) R^(D22) R^(D35) H L_(C403) R^(D22) R^(D40) H L_(C404) R^(D22) R^(D41) H L_(C405) R^(D22) R^(D42) H L_(C406) R^(D22) R^(D64) H L_(C407) R^(D22) R^(D66) H L_(C408) R^(D22) R^(D68) H L_(C409) R^(D22) R^(D76) H L_(C410) R^(D26) R^(D5) H L_(C411) R^(D26) R^(D6) H L_(C412) R^(D26) R^(D9) H L_(C413) R^(D26) R^(D10) H L_(C414) R^(D26) R^(D12) H L_(C415) R^(D26) R^(D15) H L_(C416) R^(D26) R^(D16) H L_(C417) R^(D26) R^(D17) H L_(C418) R^(D26) R^(D18) H L_(C419) R^(D26) R^(D19) H L_(C420) R^(D26) R^(D20) H L_(C421) R^(D26) R^(D21) H L_(C422) R^(D26) R^(D23) H L_(C423) R^(D26) R^(D24) H L_(C424) R^(D26) R^(D25) H L_(C425) R^(D26) R^(D27) H L_(C426) R^(D26) R^(D28) H L_(C427) R^(D26) R^(D29) H L_(C428) R^(D26) R^(D30) H L_(C429) R^(D26) R^(D31) H L_(C430) R^(D26) R^(D32) H L_(C431) R^(D26) R^(D33) H L_(C432) R^(D26) R^(D34) H L_(C433) R^(D26) R^(D35) H L_(C434) R^(D26) R^(D40) H L_(C435) R^(D26) R^(D41) H L_(C436) R^(D26) R^(D42) H L_(C437) R^(D26) R^(D64) H L_(C438) R^(D26) R^(D66) H L_(C439) R^(D26) R^(D68) H L_(C440) R^(D26) R^(D76) H L_(C441) R^(D35) R^(D5) H L_(C442) R^(D35) R^(D6) H L_(C443) R^(D35) R^(D9) H L_(C444) R^(D35) R^(D10) H L_(C445) R^(D35) R^(D12) H L_(C446) R^(D35) R^(D15) H L_(C447) R^(D35) R^(D16) H L_(C448) R^(D35) R^(D17) H L_(C449) R^(D35) R^(D18) H L_(C450) R^(D35) R^(D19) H L_(C451) R^(D35) R^(D20) H L_(C452) R^(D35) R^(D21) H L_(C453) R^(D35) R^(D23) H L_(C454) R^(D35) R^(D24) H L_(C455) R^(D35) R^(D25) H L_(C456) R^(D35) R^(D27) H L_(C457) R^(D35) R^(D28) H L_(C458) R^(D35) R^(D29) H L_(C459) R^(D35) R^(D30) H L_(C460) R^(D35) R^(D31) H L_(C461) R^(D35) R^(D32) H L_(C462) R^(D35) R^(D33) H L_(C463) R^(D35) R^(D34) H L_(C464) R^(D35) R^(D40) H L_(C465) R^(D35) R^(D41) H L_(C466) R^(D35) R^(D42) H L_(C467) R^(D35) R^(D64) H L_(C468) R^(D35) R^(D66) H L_(C469) R^(D35) R^(D68) H L_(C470) R^(D35) R^(D76) H L_(C471) R^(D40) R^(D5) H L_(C472) R^(D40) R^(D6) H L_(C473) R^(D40) R^(D9) H L_(C474) R^(D40) R^(D10) H L_(C475) R^(D40) R^(D12) H L_(C476) R^(D40) R^(D15) H L_(C477) R^(D40) R^(D16) H L_(C478) R^(D40) R^(D17) H L_(C479) R^(D40) R^(D18) H L_(C480) R^(D40) R^(D19) H L_(C481) R^(D40) R^(D20) H L_(C482) R^(D40) R^(D21) H L_(C483) R^(D40) R^(D23) H L_(C484) R^(D40) R^(D24) H L_(C485) R^(D40) R^(D25) H L_(C486) R^(D40) R^(D27) H L_(C487) R^(D40) R^(D28) H L_(C488) R^(D40) R^(D29) H L_(C489) R^(D40) R^(D30) H L_(C490) R^(D40) R^(D31) H L_(C491) R^(D40) R^(D32) H L_(C492) R^(D40) R^(D33) H L_(C493) R^(D40) R^(D34) H L_(C494) R^(D40) R^(D41) H L_(C495) R^(D40) R^(D42) H L_(C496) R^(D40) R^(D64) H L_(C497) R^(D40) R^(D66) H L_(C498) R^(D40) R^(D68) H L_(C499) R^(D40) R^(D76) H L_(C500) R^(D41) R^(D5) H L_(C501) R^(D41) R^(D6) H L_(C502) R^(D41) R^(D9) H L_(C503) R^(D41) R^(D10) H L_(C504) R^(D41) R^(D12) H L_(C505) R^(D41) R^(D15) H L_(C506) R^(D41) R^(D16) H L_(C507) R^(D41) R^(D17) H L_(C508) R^(D41) R^(D18) H L_(C509) R^(D41) R^(D19) H L_(C510) R^(D41) R^(D20) H L_(C511) R^(D41) R^(D21) H L_(C512) R^(D41) R^(D23) H L_(C513) R^(D41) R^(D24) H L_(C514) R^(D41) R^(D25) H L_(C515) R^(D41) R^(D27) H L_(C516) R^(D41) R^(D28) H L_(C517) R^(D41) R^(D29) H L_(C518) R^(D41) R^(D30) H L_(C519) R^(D41) R^(D31) H L_(C520) R^(D41) R^(D32) H L_(C521) R^(D41) R^(D33) H L_(C522) R^(D41) R^(D34) H L_(C523) R^(D41) R^(D42) H L_(C524) R^(D41) R^(D64) H L_(C525) R^(D41) R^(D66) H L_(C526) R^(D41) R^(D68) H L_(C527) R^(D41) R^(D76) H L_(C528) R^(D64) R^(D5) H L_(C529) R^(D64) R^(D6) H L_(C530) R^(D64) R^(D9) H L_(C531) R^(D64) R^(D10) H L_(C532) R^(D64) R^(D12) H L_(C533) R^(D64) R^(D15) H L_(C534) R^(D64) R^(D16) H L_(C535) R^(D64) R^(D17) H L_(C536) R^(D64) R^(D18) H L_(C537) R^(D64) R^(D19) H L_(C538) R^(D64) R^(D20) H L_(C539) R^(D64) R^(D21) H L_(C540) R^(D64) R^(D23) H L_(C541) R^(D64) R^(D24) H L_(C542) R^(D64) R^(D25) H L_(C543) R^(D64) R^(D27) H L_(C544) R^(D64) R^(D28) H L_(C545) R^(D64) R^(D29) H L_(C546) R^(D64) R^(D30) H L_(C547) R^(D64) R^(D31) H L_(C548) R^(D64) R^(D32) H L_(C549) R^(D64) R^(D33) H L_(C550) R^(D64) R^(D34) H L_(C551) R^(D64) R^(D42) H L_(C552) R^(D64) R^(D64) H L_(C553) R^(D64) R^(D66) H L_(C554) R^(D64) R^(D68) H L_(C555) R^(D64) R^(D76) H L_(C556) R^(D66) R^(D5) H L_(C557) R^(D66) R^(D6) H L_(C558) R^(D66) R^(D9) H L_(C559) R^(D66) R^(D10) H L_(C560) R^(D66) R^(D12) H L_(C561) R^(D66) R^(D15) H L_(C562) R^(D66) R^(D16) H L_(C563) R^(D66) R^(D17) H L_(C564) R^(D66) R^(D18) H L_(C565) R^(D66) R^(D19) H L_(C566) R^(D66) R^(D20) H L_(C567) R^(D66) R^(D21) H L_(C568) R^(D66) R^(D23) H L_(C569) R^(D66) R^(D24) H L_(C570) R^(D66) R^(D25) H L_(C571) R^(D66) R^(D27) H L_(C572) R^(D66) R^(D28) H L_(C573) R^(D66) R^(D29) H L_(C574) R^(D66) R^(D30) H L_(C575) R^(D66) R^(D31) H L_(C576) R^(D66) R^(D32) H L_(C577) R^(D66) R^(D33) H L_(C578) R^(D66) R^(D34) H L_(C579) R^(D66) R^(D42) H L_(C580) R^(D66) R^(D68) H L_(C581) R^(D66) R^(D76) H L_(C582) R^(D68) R^(D5) H L_(C583) R^(D68) R^(D6) H L_(C584) R^(D68) R^(D9) H L_(C585) R^(D68) R^(D10) H L_(C586) R^(D68) R^(D12) H L_(C587) R^(D68) R^(D15) H L_(C588) R^(D68) R^(D16) H L_(C589) R^(D68) R^(D17) H L_(C590) R^(D68) R^(D18) H L_(C591) R^(D68) R^(D19) H L_(C592) R^(D68) R^(D20) H L_(C593) R^(D68) R^(D21) H L_(C594) R^(D68) R^(D23) H L_(C595) R^(D68) R^(D24) H L_(C596) R^(D68) R^(D25) H L_(C597) R^(D68) R^(D27) H L_(C598) R^(D68) R^(D28) H L_(C599) R^(D68) R^(D29) H L_(C600) R^(D68) R^(D30) H L_(C601) R^(D68) R^(D31) H L_(C602) R^(D68) R^(D32) H L_(C603) R^(D68) R^(D33) H L_(C604) R^(D68) R^(D34) H L_(C605) R^(D68) R^(D42) H L_(C606) R^(D68) R^(D76) H L_(C607) R^(D76) R^(D5) H L_(C608) R^(D76) R^(D6) H L_(C609) R^(D76) R^(D9) H L_(C610) R^(D76) R^(D10) H L_(C611) R^(D76) R^(D12) H L_(C612) R^(D76) R^(D15) H L_(C613) R^(D76) R^(D16) H L_(C614) R^(D76) R^(D17) H L_(C615) R^(D76) R^(D18) H L_(C616) R^(D76) R^(D19) H L_(C617) R^(D76) R^(D20) H L_(C618) R^(D76) R^(D21) H L_(C619) R^(D76) R^(D23) H L_(C620) R^(D76) R^(D24) H L_(C621) R^(D76) R^(D25) H L_(C622) R^(D76) R^(D27) H L_(C623) R^(D76) R^(D28) H L_(C624) R^(D76) R^(D29) H L_(C625) R^(D76) R^(D30) H L_(C626) R^(D76) R^(D31) H L_(C627) R^(D76) R^(D32) H L_(C628) R^(D76) R^(D33) H L_(C629) R^(D76) R^(D34) H L_(C630) R^(D76) R^(D42) H L_(C631) R^(D1) R^(D1) R^(D1) L_(C632) R^(D2) R^(D2) R^(D1) L_(C633) R^(D3) R^(D3) R^(D1) L_(C634) R^(D4) R^(D4) R^(D1) L_(C635) R^(D5) R^(D5) R^(D1) L_(C636) R^(D6) R^(D6) R^(D1) L_(C637) R^(D7) R^(D7) R^(D1) L_(C638) R^(D8) R^(D8) R^(D1) L_(C639) R^(D9) R^(D9) R^(D1) L_(C640) R^(D10) R^(D10) R^(D1) L_(C641) R^(D11) R^(D11) R^(D1) L_(C642) R^(D12) R^(D12) R^(D1) L_(C643) R^(D13) R^(D13) R^(D1) L_(C644) R^(D14) R^(D14) R^(D1) L_(C645) R^(D15) R^(D15) R^(D1) L_(C646) R^(D16) R^(D16) R^(D1) L_(C647) R^(D17) R^(D17) R^(D1) L_(C648) R^(D18) R^(D18) R^(D1) L_(C649) R^(D19) R^(D19) R^(D1) L_(C650) R^(D20) R^(D20) R^(D1) L_(C651) R^(D21) R^(D21) R^(D1) L_(C652) R^(D22) R^(D22) R^(D1) L_(C653) R^(D23) R^(D23) R^(D1) L_(C654) R^(D24) R^(D24) R^(D1) L_(C655) R^(D25) R^(D25) R^(D1) L_(C656) R^(D26) R^(D26) R^(D1) L_(C657) R^(D27) R^(D27) R^(D1) L_(C658) R^(D28) R^(D28) R^(D1) L_(C659) R^(D29) R^(D29) R^(D1) L_(C660) R^(D30) R^(D30) R^(D1) L_(C661) R^(D31) R^(D31) R^(D1) L_(C662) R^(D32) R^(D32) R^(D1) L_(C663) R^(D33) R^(D33) R^(D1) L_(C664) R^(D34) R^(D34) R^(D1) L_(C665) R^(D35) R^(D35) R^(D1) L_(C666) R^(D40) R^(D40) R^(D1) L_(C667) R^(D41) R^(D41) R^(D1) L_(C668) R^(D42) R^(D42) R^(D1) L_(C669) R^(D64) R^(D64) R^(D1) L_(C670) R^(D66) R^(D66) R^(D1) L_(C671) R^(D68) R^(D68) R^(D1) L_(C672) R^(D76) R^(D76) R^(D1) L_(C673) R^(D1) R^(D2) R^(D1) L_(C674) R^(D1) R^(D3) R^(D1) L_(C675) R^(D1) R^(D4) R^(D1) L_(C676) R^(D1) R^(D5) R^(D1) L_(C677) R^(D1) R^(D6) R^(D1) L_(C678) R^(D1) R^(D7) R^(D1) L_(C679) R^(D1) R^(D8) R^(D1) L_(C680) R^(D1) R^(D9) R^(D1) L_(C681) R^(D1) R^(D10) R^(D1) L_(C682) R^(D1) R^(D11) R^(D1) L_(C683) R^(D1) R^(D12) R^(D1) L_(C684) R^(D1) R^(D13) R^(D1) L_(C685) R^(D1) R^(D14) R^(D1) L_(C686) R^(D1) R^(D15) R^(D1) L_(C687) R^(D1) R^(D16) R^(D1) L_(C688) R^(D1) R^(D17) R^(D1) L_(C689) R^(D1) R^(D18) R^(D1) L_(C690) R^(D1) R^(D19) R^(D1) L_(C691) R^(D1) R^(D20) R^(D1) L_(C692) R^(D1) R^(D21) R^(D1) L_(C693) R^(D1) R^(D22) R^(D1) L_(C694) R^(D1) R^(D23) R^(D1) L_(C695) R^(D1) R^(D24) R^(D1) L_(C696) R^(D1) R^(D25) R^(D1) L_(C697) R^(D1) R^(D26) R^(D1) L_(C698) R^(D1) R^(D27) R^(D1) L_(C699) R^(D1) R^(D28) R^(D1) L_(C700) R^(D1) R^(D29) R^(D1) L_(C701) R^(D1) R^(D30) R^(D1) L_(C702) R^(D1) R^(D31) R^(D1) L_(C703) R^(D1) R^(D32) R^(D1) L_(C704) R^(D1) R^(D33) R^(D1) L_(C705) R^(D1) R^(D34) R^(D1) L_(C706) R^(D1) R^(D35) R^(D1) L_(C707) R^(D1) R^(D40) R^(D1) L_(C708) R^(D1) R^(D41) R^(D1) L_(C709) R^(D1) R^(D42) R^(D1) L_(C710) R^(D1) R^(D64) R^(D1) L_(C711) R^(D1) R^(D66) R^(D1) L_(C712) R^(D1) R^(D68) R^(D1) L_(C713) R^(D1) R^(D76) R^(D1) L_(C714) R^(D2) R^(D1) R^(D1) L_(C715) R^(D2) R^(D3) R^(D1) L_(C716) R^(D2) R^(D4) R^(D1) L_(C717) R^(D2) R^(D5) R^(D1) L_(C718) R^(D2) R^(D6) R^(D1) L_(C719) R^(D2) R^(D7) R^(D1) L_(C720) R^(D2) R^(D8) R^(D1) L_(C721) R^(D2) R^(D9) R^(D1) L_(C722) R^(D2) R^(D10) R^(D1) L_(C723) R^(D2) R^(D11) R^(D1) L_(C724) R^(D2) R^(D12) R^(D1) L_(C725) R^(D2) R^(D13) R^(D1) L_(C726) R^(D2) R^(D14) R^(D1) L_(C727) R^(D2) R^(D15) R^(D1) L_(C728) R^(D2) R^(D16) R^(D1) L_(C729) R^(D2) R^(D17) R^(D1) L_(C730) R^(D2) R^(D18) R^(D1) L_(C731) R^(D2) R^(D19) R^(D1) L_(C732) R^(D2) R^(D20) R^(D1) L_(C733) R^(D2) R^(D21) R^(D1) L_(C734) R^(D2) R^(D22) R^(D1) L_(C735) R^(D2) R^(D23) R^(D1) L_(C736) R^(D2) R^(D24) R^(D1) L_(C737) R^(D2) R^(D25) R^(D1) L_(C738) R^(D2) R^(D26) R^(D1) L_(C739) R^(D2) R^(D27) R^(D1) L_(C740) R^(D2) R^(D28) R^(D1) L_(C741) R^(D2) R^(D29) R^(D1) L_(C742) R^(D2) R^(D30) R^(D1) L_(C743) R^(D2) R^(D31) R^(D1) L_(C744) R^(D2) R^(D32) R^(D1) L_(C745) R^(D2) R^(D33) R^(D1) L_(C746) R^(D2) R^(D34) R^(D1) L_(C747) R^(D2) R^(D35) R^(D1) L_(C748) R^(D2) R^(D40) R^(D1) L_(C749) R^(D2) R^(D41) R^(D1) L_(C750) R^(D2) R^(D42) R^(D1) L_(C751) R^(D2) R^(D64) R^(D1) L_(C752) R^(D2) R^(D66) R^(D1) L_(C753) R^(D2) R^(D68) R^(D1) L_(C754) R^(D2) R^(D76) R^(D1) L_(C755) R^(D3) R^(D4) R^(D1) L_(C756) R^(D3) R^(D5) R^(D1) L_(C757) R^(D3) R^(D6) R^(D1) L_(C758) R^(D3) R^(D7) R^(D1) L_(C759) R^(D3) R^(D8) R^(D1) L_(C760) R^(D3) R^(D9) R^(D1) L_(C761) R^(D3) R^(D10) R^(D1) L_(C762) R^(D3) R^(D11) R^(D1) L_(C763) R^(D3) R^(D12) R^(D1) L_(C764) R^(D3) R^(D13) R^(D1) L_(C765) R^(D3) R^(D14) R^(D1) L_(C766) R^(D3) R^(D15) R^(D1) L_(C767) R^(D3) R^(D16) R^(D1) L_(C768) R^(D3) R^(D17) R^(D1) L_(C769) R^(D3) R^(D18) R^(D1) L_(C770) R^(D3) R^(D19) R^(D1) L_(C771) R^(D3) R^(D20) R^(D1) L_(C772) R^(D3) R^(D21) R^(D1) L_(C773) R^(D3) R^(D22) R^(D1) L_(C774) R^(D3) R^(D23) R^(D1) L_(C775) R^(D3) R^(D24) R^(D1) L_(C776) R^(D3) R^(D25) R^(D1) L_(C777) R^(D3) R^(D26) R^(D1) L_(C778) R^(D3) R^(D27) R^(D1) L_(C779) R^(D3) R^(D28) R^(D1) L_(C780) R^(D3) R^(D29) R^(D1) L_(C781) R^(D3) R^(D30) R^(D1) L_(C782) R^(D3) R^(D31) R^(D1) L_(C783) R^(D3) R^(D32) R^(D1) L_(C784) R^(D3) R^(D33) R^(D1) L_(C785) R^(D3) R^(D34) R^(D1) L_(C786) R^(D3) R^(D35) R^(D1) L_(C787) R^(D3) R^(D40) R^(D1) L_(C788) R^(D3) R^(D41) R^(D1) L_(C789) R^(D3) R^(D42) R^(D1) L_(C790) R^(D3) R^(D64) R^(D1) L_(C791) R^(D3) R^(D66) R^(D1) L_(C792) R^(D3) R^(D68) R^(D1) L_(C793) R^(D3) R^(D76) R^(D1) L_(C794) R^(D4) R^(D5) R^(D1) L_(C795) R^(D4) R^(D6) R^(D1) L_(C796) R^(D4) R^(D7) R^(D1) L_(C797) R^(D4) R^(D8) R^(D1) L_(C798) R^(D4) R^(D9) R^(D1) L_(C799) R^(D4) R^(D10) R^(D1) L_(C800) R^(D4) R^(D11) R^(D1) L_(C801) R^(D4) R^(D12) R^(D1) L_(C802) R^(D4) R^(D13) R^(D1) L_(C803) R^(D4) R^(D14) R^(D1) L_(C804) R^(D4) R^(D15) R^(D1) L_(C805) R^(D4) R^(D16) R^(D1) L_(C806) R^(D4) R^(D17) R^(D1) L_(C807) R^(D4) R^(D18) R^(D1) L_(C808) R^(D4) R^(D19) R^(D1) L_(C809) R^(D4) R^(D20) R^(D1) L_(C810) R^(D4) R^(D21) R^(D1) L_(C811) R^(D4) R^(D22) R^(D1) L_(C812) R^(D4) R^(D23) R^(D1) L_(C813) R^(D4) R^(D24) R^(D1) L_(C814) R^(D4) R^(D25) R^(D1) L_(C815) R^(D4) R^(D26) R^(D1) L_(C816) R^(D4) R^(D27) R^(D1) L_(C817) R^(D4) R^(D28) R^(D1) L_(C818) R^(D4) R^(D29) R^(D1) L_(C819) R^(D4) R^(D30) R^(D1) L_(C820) R^(D4) R^(D31) R^(D1) L_(C821) R^(D4) R^(D32) R^(D1) L_(C822) R^(D4) R^(D33) R^(D1) L_(C823) R^(D4) R^(D34) R^(D1) L_(C824) R^(D4) R^(D35) R^(D1) L_(C825) R^(D4) R^(D40) R^(D1) L_(C826) R^(D4) R^(D41) R^(D1) L_(C827) R^(D4) R^(D42) R^(D1) L_(C828) R^(D4) R^(D64) R^(D1) L_(C829) R^(D4) R^(D66) R^(D1) L_(C830) R^(D4) R^(D68) R^(D1) L_(C831) R^(D4) R^(D76) R^(D1) L_(C832) R^(D4) R^(D1) R^(D1) L_(C833) R^(D7) R^(D5) R^(D1) L_(C834) R^(D7) R^(D6) R^(D1) L_(C835) R^(D7) R^(D8) R^(D1) L_(C836) R^(D7) R^(D9) R^(D1) L_(C837) R^(D7) R^(D10) R^(D1) L_(C838) R^(D7) R^(D11) R^(D1) L_(C839) R^(D7) R^(D12) R^(D1) L_(C840) R^(D7) R^(D13) R^(D1) L_(C841) R^(D7) R^(D14) R^(D1) L_(C842) R^(D7) R^(D15) R^(D1) L_(C843) R^(D7) R^(D16) R^(D1) L_(C844) R^(D7) R^(D17) R^(D1) L_(C845) R^(D7) R^(D18) R^(D1) L_(C846) R^(D7) R^(D19) R^(D1) L_(C847) R^(D7) R^(D20) R^(D1) L_(C848) R^(D7) R^(D21) R^(D1) L_(C849) R^(D7) R^(D22) R^(D1) L_(C850) R^(D7) R^(D23) R^(D1) L_(C851) R^(D7) R^(D24) R^(D1) L_(C852) R^(D7) R^(D25) R^(D1) L_(C853) R^(D7) R^(D26) R^(D1) L_(C854) R^(D7) R^(D27) R^(D1) L_(C855) R^(D7) R^(D28) R^(D1) L_(C856) R^(D7) R^(D29) R^(D1) L_(C857) R^(D7) R^(D30) R^(D1) L_(C858) R^(D7) R^(D31) R^(D1) L_(C859) R^(D7) R^(D32) R^(D1) L_(C860) R^(D7) R^(D33) R^(D1) L_(C861) R^(D7) R^(D34) R^(D1) L_(C862) R^(D7) R^(D35) R^(D1) L_(C863) R^(D7) R^(D40) R^(D1) L_(C864) R^(D7) R^(D41) R^(D1) L_(C865) R^(D7) R^(D42) R^(D1) L_(C866) R^(D7) R^(D64) R^(D1) L_(C867) R^(D7) R^(D66) R^(D1) L_(C868) R^(D7) R^(D68) R^(D1) L_(C869) R^(D7) R^(D76) R^(D1) L_(C870) R^(D8) R^(D5) R^(D1) L_(C871) R^(D8) R^(D6) R^(D1) L_(C872) R^(D8) R^(D9) R^(D1) L_(C873) R^(D8) R^(D10) R^(D1) L_(C874) R^(D8) R^(D11) R^(D1) L_(C875) R^(D8) R^(D12) R^(D1) L_(C876) R^(D8) R^(D13) R^(D1) L_(C877) R^(D8) R^(D14) R^(D1) L_(C878) R^(D8) R^(D15) R^(D1) L_(C879) R^(D8) R^(D16) R^(D1) L_(C880) R^(D8) R^(D17) R^(D1) L_(C881) R^(D8) R^(D18) R^(D1) L_(C882) R^(D8) R^(D19) R^(D1) L_(C883) R^(D8) R^(D20) R^(D1) L_(C884) R^(D8) R^(D21) R^(D1) L_(C885) R^(D8) R^(D22) R^(D1) L_(C886) R^(D8) R^(D23) R^(D1) L_(C887) R^(D8) R^(D24) R^(D1) L_(C888) R^(D8) R^(D25) R^(D1) L_(C889) R^(D8) R^(D26) R^(D1) L_(C890) R^(D8) R^(D27) R^(D1) L_(C891) R^(D8) R^(D28) R^(D1) L_(C892) R^(D8) R^(D29) R^(D1) L_(C893) R^(D8) R^(D30) R^(D1) L_(C894) R^(D8) R^(D31) R^(D1) L_(C895) R^(D8) R^(D32) R^(D1) L_(C896) R^(D8) R^(D33) R^(D1) L_(C897) R^(D8) R^(D34) R^(D1) L_(C898) R^(D8) R^(D35) R^(D1) L_(C899) R^(D8) R^(D40) R^(D1) L_(C900) R^(D8) R^(D41) R^(D1) L_(C901) R^(D8) R^(D42) R^(D1) L_(C902) R^(D8) R^(D64) R^(D1) L_(C903) R^(D8) R^(D66) R^(D1) L_(C904) R^(D8) R^(D68) R^(D1) L_(C905) R^(D8) R^(D76) R^(D1) L_(C906) R^(D11) R^(D5) R^(D1) L_(C907) R^(D11) R^(D6) R^(D1) L_(C908) R^(D11) R^(D9) R^(D1) L_(C909) R^(D11) R^(D10) R^(D1) L_(C910) R^(D11) R^(D12) R^(D1) L_(C911) R^(D11) R^(D13) R^(D1) L_(C912) R^(D11) R^(D14) R^(D1) L_(C913) R^(D11) R^(D15) R^(D1) L_(C914) R^(D11) R^(D16) R^(D1) L_(C915) R^(D11) R^(D17) R^(D1) L_(C916) R^(D11) R^(D18) R^(D1) L_(C917) R^(D11) R^(D19) R^(D1) L_(C918) R^(D11) R^(D20) R^(D1) L_(C919) R^(D11) R^(D21) R^(D1) L_(C920) R^(D11) R^(D22) R^(D1) L_(C921) R^(D11) R^(D23) R^(D1) L_(C922) R^(D11) R^(D24) R^(D1) L_(C923) R^(D11) R^(D25) R^(D1) L_(C924) R^(D11) R^(D26) R^(D1) L_(C925) R^(D11) R^(D27) R^(D1) L_(C926) R^(D11) R^(D28) R^(D1) L_(C927) R^(D11) R^(D29) R^(D1) L_(C928) R^(D11) R^(D30) R^(D1) L_(C929) R^(D11) R^(D31) R^(D1) L_(C930) R^(D11) R^(D32) R^(D1) L_(C931) R^(D11) R^(D33) R^(D1) L_(C932) R^(D11) R^(D34) R^(D1) L_(C933) R^(D11) R^(D35) R^(D1) L_(C934) R^(D11) R^(D40) R^(D1) L_(C935) R^(D11) R^(D41) R^(D1) L_(C936) R^(D11) R^(D42) R^(D1) L_(C937) R^(D11) R^(D64) R^(D1) L_(C938) R^(D11) R^(D66) R^(D1) L_(C939) R^(D11) R^(D68) R^(D1) L_(C940) R^(D11) R^(D76) R^(D1) L_(C941) R^(D13) R^(D5) R^(D1) L_(C942) R^(D13) R^(D6) R^(D1) L_(C943) R^(D13) R^(D9) R^(D1) L_(C944) R^(D13) R^(D10) R^(D1) L_(C945) R^(D13) R^(D12) R^(D1) L_(C946) R^(D13) R^(D14) R^(D1) L_(C947) R^(D13) R^(D15) R^(D1) L_(C948) R^(D13) R^(D16) R^(D1) L_(C949) R^(D13) R^(D17) R^(D1) L_(C950) R^(D13) R^(D18) R^(D1) L_(C951) R^(D13) R^(D19) R^(D1) L_(C952) R^(D13) R^(D20) R^(D1) L_(C953) R^(D13) R^(D21) R^(D1) L_(C954) R^(D13) R^(D22) R^(D1) L_(C955) R^(D13) R^(D23) R^(D1) L_(C956) R^(D13) R^(D24) R^(D1) L_(C957) R^(D13) R^(D25) R^(D1) L_(C958) R^(D13) R^(D26) R^(D1) L_(C959) R^(D13) R^(D27) R^(D1) L_(C960) R^(D13) R^(D28) R^(D1) L_(C961) R^(D13) R^(D29) R^(D1) L_(C962) R^(D13) R^(D30) R^(D1) L_(C963) R^(D13) R^(D31) R^(D1) L_(C964) R^(D13) R^(D32) R^(D1) L_(C965) R^(D13) R^(D33) R^(D1) L_(C966) R^(D13) R^(D34) R^(D1) L_(C967) R^(D13) R^(D35) R^(D1) L_(C968) R^(D13) R^(D40) R^(D1) L_(C969) R^(D13) R^(D41) R^(D1) L_(C970) R^(D13) R^(D42) R^(D1) L_(C971) R^(D13) R^(D64) R^(D1) L_(C972) R^(D13) R^(D66) R^(D1) L_(C973) R^(D13) R^(D68) R^(D1) L_(C974) R^(D13) R^(D76) R^(D1) L_(C975) R^(D14) R^(D5) R^(D1) L_(C976) R^(D14) R^(D6) R^(D1) L_(C977) R^(D14) R^(D9) R^(D1) L_(C978) R^(D14) R^(D10) R^(D1) L_(C979) R^(D14) R^(D12) R^(D1) L_(C980) R^(D14) R^(D15) R^(D1) L_(C981) R^(D14) R^(D16) R^(D1) L_(C982) R^(D14) R^(D17) R^(D1) L_(C983) R^(D14) R^(D18) R^(D1) L_(C984) R^(D14) R^(D19) R^(D1) L_(C985) R^(D14) R^(D20) R^(D1) L_(C986) R^(D14) R^(D21) R^(D1) L_(C987) R^(D14) R^(D22) R^(D1) L_(C988) R^(D14) R^(D23) R^(D1) L_(C989) R^(D14) R^(D24) R^(D1) L_(C990) R^(D14) R^(D25) R^(D1) L_(C991) R^(D14) R^(D26) R^(D1) L_(C992) R^(D14) R^(D27) R^(D1) L_(C993) R^(D14) R^(D28) R^(D1) L_(C994) R^(D14) R^(D29) R^(D1) L_(C995) R^(D14) R^(D30) R^(D1) L_(C996) R^(D14) R^(D31) R^(D1) L_(C997) R^(D14) R^(D32) R^(D1) L_(C998) R^(D14) R^(D33) R^(D1) L_(C999) R^(D14) R^(D34) R^(D1) L_(C1000) R^(D14) R^(D35) R^(D1) L_(C1001) R^(D14) R^(D40) R^(D1) L_(C1002) R^(D14) R^(D41) R^(D1) L_(C1003) R^(D14) R^(D42) R^(D1) L_(C1004) R^(D14) R^(D64) R^(D1) L_(C1005) R^(D14) R^(D66) R^(D1) L_(C1006) R^(D14) R^(D68) R^(D1) L_(C1007) R^(D14) R^(D76) R^(D1) L_(C1008) R^(D22) R^(D5) R^(D1) L_(C1009) R^(D22) R^(D6) R^(D1) L_(C1010) R^(D22) R^(D9) R^(D1) L_(C1011) R^(D22) R^(D10) R^(D1) L_(C1012) R^(D22) R^(D12) R^(D1) L_(C1013) R^(D22) R^(D15) R^(D1) L_(C1014) R^(D22) R^(D16) R^(D1) L_(C1015) R^(D22) R^(D17) R^(D1) L_(C1016) R^(D22) R^(D18) R^(D1) L_(C1017) R^(D22) R^(D19) R^(D1) L_(C1018) R^(D22) R^(D20) R^(D1) L_(C1019) R^(D22) R^(D21) R^(D1) L_(C1020) R^(D22) R^(D23) R^(D1) L_(C1021) R^(D22) R^(D24) R^(D1) L_(C1022) R^(D22) R^(D25) R^(D1) L_(C1023) R^(D22) R^(D26) R^(D1) L_(C1024) R^(D22) R^(D27) R^(D1) L_(C1025) R^(D22) R^(D28) R^(D1) L_(C1026) R^(D22) R^(D29) R^(D1) L_(C1027) R^(D22) R^(D30) R^(D1) L_(C1028) R^(D22) R^(D31) R^(D1) L_(C1029) R^(D22) R^(D32) R^(D1) L_(C1030) R^(D22) R^(D33) R^(D1) L_(C1031) R^(D22) R^(D34) R^(D1) L_(C1032) R^(D22) R^(D35) R^(D1) L_(C1033) R^(D22) R^(D40) R^(D1) L_(C1034) R^(D22) R^(D41) R^(D1) L_(C1035) R^(D22) R^(D42) R^(D1) L_(C1036) R^(D22) R^(D64) R^(D1) L_(C1037) R^(D22) R^(D66) R^(D1) L_(C1038) R^(D22) R^(D68) R^(D1) L_(C1039) R^(D22) R^(D76) R^(D1) L_(C1040) R^(D26) R^(D5) R^(D1) L_(C1041) R^(D26) R^(D6) R^(D1) L_(C1042) R^(D26) R^(D9) R^(D1) L_(C1043) R^(D26) R^(D10) R^(D1) L_(C1044) R^(D26) R^(D12) R^(D1) L_(C1045) R^(D26) R^(D15) R^(D1) L_(C1046) R^(D26) R^(D16) R^(D1) L_(C1047) R^(D26) R^(D17) R^(D1) L_(C1048) R^(D26) R^(D18) R^(D1) L_(C1049) R^(D26) R^(D19) R^(D1) L_(C1050) R^(D26) R^(D20) R^(D1) L_(C1051) R^(D26) R^(D21) R^(D1) L_(C1052) R^(D26) R^(D23) R^(D1) L_(C1053) R^(D26) R^(D24) R^(D1) L_(C1054) R^(D26) R^(D25) R^(D1) L_(C1055) R^(D26) R^(D27) R^(D1) L_(C1056) R^(D26) R^(D28) R^(D1) L_(C1057) R^(D26) R^(D29) R^(D1) L_(C1058) R^(D26) R^(D30) R^(D1) L_(C1059) R^(D26) R^(D31) R^(D1) L_(C1060) R^(D26) R^(D32) R^(D1) L_(C1061) R^(D26) R^(D33) R^(D1) L_(C1062) R^(D26) R^(D34) R^(D1) L_(C1063) R^(D26) R^(D35) R^(D1) L_(C1064) R^(D26) R^(D40) R^(D1) L_(C1065) R^(D26) R^(D41) R^(D1) L_(C1066) R^(D26) R^(D42) R^(D1) L_(C1067) R^(D26) R^(D64) R^(D1) L_(C1068) R^(D26) R^(D66) R^(D1) L_(C1069) R^(D26) R^(D68) R^(D1) L_(C1070) R^(D26) R^(D76) R^(D1) L_(C1071) R^(D35) R^(D5) R^(D1) L_(C1072) R^(D35) R^(D6) R^(D1) L_(C1073) R^(D35) R^(D9) R^(D1) L_(C1074) R^(D35) R^(D10) R^(D1) L_(C1075) R^(D35) R^(D12) R^(D1) L_(C1076) R^(D35) R^(D15) R^(D1) L_(C1077) R^(D35) R^(D16) R^(D1) L_(C1078) R^(D35) R^(D17) R^(D1) L_(C1079) R^(D35) R^(D18) R^(D1) L_(C1080) R^(D35) R^(D19) R^(D1) L_(C1081) R^(D35) R^(D20) R^(D1) L_(C1082) R^(D35) R^(D21) R^(D1) L_(C1083) R^(D35) R^(D23) R^(D1) L_(C1084) R^(D35) R^(D24) R^(D1) L_(C1085) R^(D35) R^(D25) R^(D1) L_(C1086) R^(D35) R^(D27) R^(D1) L_(C1087) R^(D35) R^(D28) R^(D1) L_(C1088) R^(D35) R^(D29) R^(D1) L_(C1089) R^(D35) R^(D30) R^(D1) L_(C1090) R^(D35) R^(D31) R^(D1) L_(C1091) R^(D35) R^(D32) R^(D1) L_(C1092) R^(D35) R^(D33) R^(D1) L_(C1093) R^(D35) R^(D34) R^(D1) L_(C1094) R^(D35) R^(D40) R^(D1) L_(C1095) R^(D35) R^(D41) R^(D1) L_(C1096) R^(D35) R^(D42) R^(D1) L_(C1097) R^(D35) R^(D64) R^(D1) L_(C1098) R^(D35) R^(D66) R^(D1) L_(C1099) R^(D35) R^(D68) R^(D1) L_(C1100) R^(D35) R^(D76) R^(D1) L_(C1101) R^(D40) R^(D5) R^(D1) L_(C1102) R^(D40) R^(D6) R^(D1) L_(C1103) R^(D40) R^(D9) R^(D1) L_(C1104) R^(D40) R^(D10) R^(D1) L_(C1105) R^(D40) R^(D12) R^(D1) L_(C1106) R^(D40) R^(D15) R^(D1) L_(C1107) R^(D40) R^(D16) R^(D1) L_(C1108) R^(D40) R^(D17) R^(D1) L_(C1109) R^(D40) R^(D18) R^(D1) L_(C1110) R^(D40) R^(D19) R^(D1) L_(C1111) R^(D40) R^(D20) R^(D1) L_(C1102) R^(D40) R^(D21) R^(D1) L_(C1103) R^(D40) R^(D23) R^(D1) L_(C1104) R^(D40) R^(D24) R^(D1) L_(C1105) R^(D40) R^(D25) R^(D1) L_(C1106) R^(D40) R^(D27) R^(D1) L_(C1107) R^(D40) R^(D28) R^(D1) L_(C1118) R^(D40) R^(D29) R^(D1) L_(C1119) R^(D40) R^(D30) R^(D1) L_(C1120) R^(D40) R^(D31) R^(D1) L_(C1121) R^(D40) R^(D32) R^(D1) L_(C1122) R^(D40) R^(D33) R^(D1) L_(C1123) R^(D40) R^(D34) R^(D1) L_(C1124) R^(D40) R^(D41) R^(D1) L_(C1125) R^(D40) R^(D42) R^(D1) L_(C1126) R^(D40) R^(D64) R^(D1) L_(C1127) R^(D40) R^(D66) R^(D1) L_(C1128) R^(D40) R^(D68) R^(D1) L_(C1129) R^(D40) R^(D76) R^(D1) L_(C1130) R^(D41) R^(D5) R^(D1) L_(C1131) R^(D41) R^(D6) R^(D1) L_(C1132) R^(D41) R^(D9) R^(D1) L_(C1133) R^(D41) R^(D10) R^(D1) L_(C1134) R^(D41) R^(D12) R^(D1) L_(C1135) R^(D41) R^(D15) R^(D1) L_(C1136) R^(D41) R^(D16) R^(D1) L_(C1137) R^(D41) R^(D17) R^(D1) L_(C1138) R^(D41) R^(D18) R^(D1) L_(C1139) R^(D41) R^(D19) R^(D1) L_(C1140) R^(D41) R^(D20) R^(D1) L_(C1141) R^(D41) R^(D21) R^(D1) L_(C1142) R^(D41) R^(D23) R^(D1) L_(C1143) R^(D41) R^(D24) R^(D1) L_(C1144) R^(D41) R^(D25) R^(D1) L_(C1145) R^(D41) R^(D27) R^(D1) L_(C1146) R^(D41) R^(D28) R^(D1) L_(C1147) R^(D41) R^(D29) R^(D1) L_(C1148) R^(D41) R^(D30) R^(D1) L_(C1149) R^(D41) R^(D31) R^(D1) L_(C1150) R^(D41) R^(D32) R^(D1) L_(C1151) R^(D41) R^(D33) R^(D1) L_(C1152) R^(D41) R^(D34) R^(D1) L_(C1153) R^(D41) R^(D42) R^(D1) L_(C1154) R^(D41) R^(D64) R^(D1) L_(C1155) R^(D41) R^(D66) R^(D1) L_(C1156) R^(D41) R^(D68) R^(D1) L_(C1157) R^(D41) R^(D76) R^(D1) L_(C1158) R^(D64) R^(D5) R^(D1) L_(C1159) R^(D64) R^(D6) R^(D1) L_(C1160) R^(D64) R^(D9) R^(D1) L_(C1161) R^(D64) R^(D10) R^(D1) L_(C1162) R^(D64) R^(D12) R^(D1) L_(C1163) R^(D64) R^(D15) R^(D1) L_(C1164) R^(D64) R^(D16) R^(D1) L_(C1165) R^(D64) R^(D17) R^(D1) L_(C1166) R^(D64) R^(D18) R^(D1) L_(C1167) R^(D64) R^(D19) R^(D1) L_(C1168) R^(D64) R^(D20) R^(D1) L_(C1169) R^(D64) R^(D21) R^(D1) L_(C1170) R^(D64) R^(D23) R^(D1) L_(C1171) R^(D64) R^(D24) R^(D1) L_(C1172) R^(D64) R^(D25) R^(D1) L_(C1173) R^(D64) R^(D27) R^(D1) L_(C1174) R^(D64) R^(D28) R^(D1) L_(C1175) R^(D64) R^(D29) R^(D1) L_(C1176) R^(D64) R^(D30) R^(D1) L_(C1177) R^(D64) R^(D31) R^(D1) L_(C1178) R^(D64) R^(D32) R^(D1) L_(C1179) R^(D64) R^(D33) R^(D1) L_(C1180) R^(D64) R^(D34) R^(D1) L_(C1181) R^(D64) R^(D42) R^(D1) L_(C1182) R^(D64) R^(D64) R^(D1) L_(C1183) R^(D64) R^(D66) R^(D1) L_(C1184) R^(D64) R^(D68) R^(D1) L_(C1185) R^(D64) R^(D76) R^(D1) L_(C1186) R^(D66) R^(D5) R^(D1) L_(C1187) R^(D66) R^(D6) R^(D1) L_(C1188) R^(D66) R^(D9) R^(D1) L_(C1189) R^(D66) R^(D10) R^(D1) L_(C1190) R^(D66) R^(D12) R^(D1) L_(C1191) R^(D66) R^(D15) R^(D1) L_(C1192) R^(D66) R^(D16) R^(D1) L_(C1193) R^(D66) R^(D17) R^(D1) L_(C1194) R^(D66) R^(D18) R^(D1) L_(C1195) R^(D66) R^(D19) R^(D1) L_(C1196) R^(D66) R^(D20) R^(D1) L_(C1197) R^(D66) R^(D21) R^(D1) L_(C1198) R^(D66) R^(D23) R^(D1) L_(C1199) R^(D66) R^(D24) R^(D1) L_(C1200) R^(D66) R^(D25) R^(D1) L_(C1201) R^(D66) R^(D27) R^(D1) L_(C1202) R^(D66) R^(D28) R^(D1) L_(C1203) R^(D66) R^(D29) R^(D1) L_(C1204) R^(D66) R^(D30) R^(D1) L_(C1205) R^(D66) R^(D31) R^(D1) L_(C1206) R^(D66) R^(D32) R^(D1) L_(C1207) R^(D66) R^(D33) R^(D1) L_(C1208) R^(D66) R^(D34) R^(D1) L_(C1209) R^(D66) R^(D42) R^(D1) L_(C1210) R^(D66) R^(D68) R^(D1) L_(C1211) R^(D66) R^(D76) R^(D1) L_(C1212) R^(D68) R^(D5) R^(D1) L_(C1213) R^(D68) R^(D6) R^(D1) L_(C1214) R^(D68) R^(D9) R^(D1) L_(C1215) R^(D68) R^(D10) R^(D1) L_(C1216) R^(D68) R^(D12) R^(D1) L_(C1217) R^(D68) R^(D15) R^(D1) L_(C1218) R^(D68) R^(D16) R^(D1) L_(C1219) R^(D68) R^(D17) R^(D1) L_(C1220) R^(D68) R^(D18) R^(D1) L_(C1221) R^(D68) R^(D19) R^(D1) L_(C1222) R^(D68) R^(D20) R^(D1) L_(C1223) R^(D68) R^(D21) R^(D1) L_(C1224) R^(D68) R^(D23) R^(D1) L_(C1225) R^(D68) R^(D24) R^(D1) L_(C1226) R^(D68) R^(D25) R^(D1) L_(C1227) R^(D68) R^(D27) R^(D1) L_(C1228) R^(D68) R^(D28) R^(D1) L_(C1229) R^(D68) R^(D29) R^(D1) L_(C1230) R^(D68) R^(D30) R^(D1) L_(C1231) R^(D68) R^(D31) R^(D1) L_(C1232) R^(D68) R^(D32) R^(D1) L_(C1233) R^(D68) R^(D33) R^(D1) L_(C1234) R^(D68) R^(D34) R^(D1) L_(C1235) R^(D68) R^(D42) R^(D1) L_(C1236) R^(D68) R^(D76) R^(D1) L_(C1237) R^(D76) R^(D5) R^(D1) L_(C1238) R^(D76) R^(D6) R^(D1) L_(C1239) R^(D76) R^(D9) R^(D1) L_(C1240) R^(D76) R^(D10) R^(D1) L_(C1241) R^(D76) R^(D12) R^(D1) L_(C1242) R^(D76) R^(D15) R^(D1) L_(C1243) R^(D76) R^(D16) R^(D1) L_(C1244) R^(D76) R^(D17) R^(D1) L_(C1245) R^(D76) R^(D18) R^(D1) L_(C1246) R^(D76) R^(D19) R^(D1) L_(C1247) R^(D76) R^(D20) R^(D1) L_(C1248) R^(D76) R^(D21) R^(D1) L_(C1249) R^(D76) R^(D23) R^(D1) L_(C1250) R^(D76) R^(D24) R^(D1) L_(C1251) R^(D76) R^(D25) R^(D1) L_(C1252) R^(D76) R^(D27) R^(D1) L_(C1253) R^(D76) R^(D28) R^(D1) L_(C1254) R^(D76) R^(D29) R^(D1) L_(C1255) R^(D76) R^(D30) R^(D1) L_(C1256) R^(D76) R^(D31) R^(D1) L_(C1257) R^(D76) R^(D32) R^(D1) L_(C1258) R^(D76) R^(D33) R^(D1) L_(C1259) R^(D76) R^(D34) R^(D1) L_(C1260) R^(D76) R^(D42) R^(D1)

wherein R^(D1) to R^(D21) have the following structures:


13. The compound of claim 1, wherein the compound has the formula:

wherein rings E and F each independently represents a 5-membered or 6-membered carbocyclic or heterocyclic ring; wherein R^(E) and R^(F) each independently represents mono to the maximum possible number of substitutions, or no substitution; wherein m₁, m₂, and m₃ are each independently an integer of 0 or 1; when m₂ is 0, both m₁ and m₃ are 1; when m₂ is 1, each m₁ and m₃ independently can be 0 or 1; wherein when m₁ is 0, L¹ is not present; when m₂ is 0, L² is not present; when m₃ is 0, L³ is not present; wherein L¹, L², and L³ are each independently selected from the group consisting of a direct bond, BR, NR, PR, O, S, Se, C═O, S═O, SO2, CRR′, SiRR′, GeRR′, alkyl, cycloalkyl, and combinations thereof; wherein R^(E) and R^(F) are each independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein R and R′ are each independently selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein any adjacent R^(E), R^(F), R, and R′ can be joined to form a ring.
 14. The compound of claim 13, wherein the compound has the formula:

wherein R^(G) is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, aryl, heteroaryl, partially or fully deuterated variants thereof, partially or fully fluorinated variants thereof, and combinations thereof.
 15. The compound of claim 13, wherein the compound has the formula selected from the group consisting of:


16. An organic light emitting device (OLED) comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound comprising a first ligand L_(A) of Formula I

wherein X¹—X⁸ are each independently C or N; wherein no more than two N atoms are bonded to each other; wherein at least one pair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and is joined to a structure G of Formula II

wherein A is selected from the group consisting of O, S, Se, and NR′; wherein R^(A), R^(B), R^(C), and R^(D) each independently represents represent mono to the maximum number of allowable substitutions, or no substitution; wherein each R^(A), R^(B), R^(C), R^(D), and R′ is independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any two substituents may be joined or fused together to form a ring; wherein L_(A) is complexed to a metal M; wherein M is optionally coordinated to other ligands; wherein the ligand L_(A) is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand.
 17. The OLED of claim 16, wherein the organic layer is an emissive layer and the compound is an emissive dopant or a non-emissive dopant.
 18. The OLED of claim 16, wherein the organic layer further comprises a host, wherein the host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
 19. The OLED of claim 18, wherein the host is selected from the group consisting of:

and combinations thereof.
 20. A consumer product comprising an organic light-emitting device comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound comprising a first ligand L_(A) of Formula I

wherein X¹—X⁸ are each independently C or N; wherein no more than two N atoms are bonded to each other; wherein at least one pair of X¹ and X², X² and X³, X⁶ and X⁷, and X⁷ and X⁸ is C—C, and is joined to a structure G of Formula II

wherein A is selected from the group consisting of O, S, Se, and NR′; wherein R^(A), R^(B), R^(C), and R^(D) each independently represents mono to the maximum number of allowable substitutions, or no substitution; wherein each R^(A), R^(B), R^(C), R^(D), and R′ is independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any two substituents may be joined or fused together to form a ring; wherein L_(A) is complexed to a metal M; wherein M is optionally coordinated to other ligands; wherein the ligand L_(A) is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate, or hexadentate ligand. 